• Title/Summary/Keyword: 유성

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Studies on the Detergency of Oily Soils (Part 1) - Detergency of Soild Oily Soils - (유성오염의 세척성에 관한 연구(제1보) -개체유성오염의 세척성-)

  • 김영희;정두진
    • Journal of the Korean Society of Clothing and Textiles
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    • v.18 no.4
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    • pp.524-535
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    • 1994
  • The interaction and detergency between oily soil and surfactant solution were studied Samples used were tristearin, tripalmitin and their mixture as a triglyceride, myristic acid as a fatty acid and sodium dodecyl sulfate (SDS) as surfactant. The results were as follows: 1. The mixtures of model oily soils were formed of eutectic point and their melting point were lower than them of individual oily soils. 2. The formation of liquid crystalline (LC) phase was recognized in the triangle phase diagram for SDS~ water~model oily soil system. The areas of LC phase region were in the order of SHS~ water~myristir acid> SDS~ water~mixture of tristearin, tripalmitin and myristic acid (TS/TP/M)>SDS~water~mixture of tristearin and tripalmitin (TS/TP) 3. The LC phase region expanded to wide concentration range of SDS solution and high concentration range of model oily soil with increasing temperature. Particularity, the LC phase region expanded highly at $30~40^{\circ}C$ but when the temperature was elevated above $40^{\circ}C$, expanding tendency decreased. 4. In the system of myristic acid and TS/TP/M contacted with SDS solution, the LC phase was already formed at $28^{\circ}C$ and the region of the LC phase were expanded with increasing temperature. But in the system of TS/TP contacted with SDS solution, the LC phase was not formed in whole experiment temperature. 5. The detergency of myristic acid was very high ann it was recognized that the formation of the LC phase played an important role in the detergency. The detergency of TS/TP was very for low, but when TS/TF was mixed with myristic acid, the detergency of TS/TP increased. It is supposed that the LC phase was formed butween SDS solution and myristic acid promoted to penetration of SDS solution into the inner parts of TS/TP.

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Preparation and Curing Behavior of Polyurethane Coatings by Polyester/Lactone Polyol and HDI-biuret (폴리에스테르/락톤 폴리올과 HDI-Biuret에 의한 폴리우레탄 도료의 제조 및 경화거동)

  • 최용호;김대원;황규현;박홍수;김태옥
    • Polymer(Korea)
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    • v.24 no.1
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    • pp.72-81
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    • 2000
  • Benzoic acid polyester/lactone polyol were synthesized by polycaprolactone 0201 as diol, trimethylolpropane as triol, adipic acid as dibasic acid, and benzoic acid as monobasic acid. Polyisocyanate prepolymer Desmodur N-100 of HDI-biuret type was used in this study. Two-component polyurethane coatings were prepared by blending benzoic acid polyester/polycaprolactone, polyisocyanate, wetting/dispersing agent, white pigment, and flowing agent. Various properties were examined on the film coated with the prepared polyurethane. They showed excellent physical properties such as abrasion resistance, accelerated weathering resistance, and yellowness index. They also showed good physical properties such as flexibility, impact resistance, 60$^{\circ}$ specular gloss, cross hatch adhesion, hydrocarbon resistance, and lightness index difference. Hardness of coating showed a little poor character. The introduction of polycaprolactone 0201 as diol in the polyurethane coatings improved the hydrocarbon resistance, impact resistance, and flexibility of coatings. According to the drying and curing behavior with the contents of benzoic acid, they seem to have reasonable coating properties such as drying time of 2 to 4 hours and pot-life time of 20 to 37 hours.

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Effect of Processing Agent on Physical Properties of Leather (혁의 물성에 미치는 가공제 첨가 효과)

  • Lee, Jong-Seok;Seo, Gyo-Taeg;Kim, Young Chai;Moon, Sei-Ki
    • Applied Chemistry for Engineering
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    • v.10 no.6
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    • pp.934-938
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    • 1999
  • Effect of processing agents on physical properties on aniline-type leathers such as wet blue, crust leather, and finished leather has been investigated. These leathers were manufactured from pelts obtained by the chemical, the enzyme, and the bio-tech treatment. There was no difference in physical properties between crust leather and finished leather. All finished leathers with the three treatments were satisfied with the Korean Industrial Standard like a tensile strength of $1.2kg_f/mm^2$, an elongation of 30%, a tear strength of $3.0kg_f/mm$, a grain crack weight of $15kg_f$, and a $Cr_2O_3$ content of 2.5%. In peculiar, application of the bio-tech treatment gave the best leather. This improvement of physical quality could be explained by the results of SEM and image analyser.

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Genetic Analysis of Sexual Life Cycle in Heterothallic Saccharomycopsis lipolytica (Heterothallic Saccharomycopsis lipolytica의 유성생활환(有性生活環)의 유전적(遺傳的) 해석(解釋))

  • Cho, Seok-Gum;Chung, Dong-Hyo
    • Applied Biological Chemistry
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    • v.29 no.1
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    • pp.3-9
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    • 1986
  • A yeast strains, CJ 2, CJ 7 and CJ 8, isolated from soil and contaminated choose, mated with authentic strains of Saccharomycopsis lipolytica and were identified as Saccharomycopsis lipolytica with mating A, B and B, respectively. The strain CJ 7 produced large amount of isocitric acid in glucose and n-hexadecane medium as compared with another strains. All strains produced larger amount of citric acid in n-hexadecane medium as compared with glucose medium, and citric acid production of diploids was greater than that of the parental haploid strains. The specific activity of isocitrate lyase in n-hexadecane grown cells was $15{\sim}20$ times greater than that in glucose-grown cells, but the specific activity of citrate synthetase was not so influenced by carbon source. Little correlation between citric acid production and the specific acitivity of these enzymes was noticed irrespective of strains and ploidy.

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A Study on Noise Resistance and Physical Properties of NBR Rubber Materials Containing Oleamide and Aramid Chip (Oleamide 및 아라미드 칩을 첨가한 NBR 고무재료의 내소음성 및 물성 연구)

  • Kim, Hyun-Muk;Lee, Chang-Seop
    • Elastomers and Composites
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    • v.41 no.2
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    • pp.79-87
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    • 2006
  • This study are conducted for the purpose of developing rubber material with noise and crack resistance. Cure characteristics, physical properties, thermal resistance, fuel resistance, abrasion resistance, crack resistance and noise resistance of NBR compounds with the various amounts of oleamide and aramid chip were investigated. From the measurements of cure characteristics and Mooney viscosities, cure characteristics of uncured rubber showed that a torque was decreased as the amount of oleamide increased. Hardness, modulus and elongation of rubber specimens tended to be reduced gradually, however, tensile strength remained unchanged as the amount of the oleamide increased. As a testing results of heat resistance for 70 hours at $120^{\circ}C$ and oil resistance far 70 hours at $40^{\circ}C$, tensile strength and elongation were all reduced. From the TGA/DSC analysis, there was no such a change observed in thermal characteristics of rubber materials. As a result of testing basic physical properties, abrasion resistance, noise resistance and crack resistance, the optimum ratio of oleamide to NBR was found to be 3 phr, while that of aramid to NBR 227001 was 1 phr.

Structural and Functional Analysis of a Forkhead Gene, fkhF, in a Filamentous Fungus Aspergillus nidulans (사상성 진균 Aspergillus nidulans에서 forkhead 유전자인 fkhF의 구조와 기능 분석)

  • Park, Mi-Hye;Kim, Hyoun-Young;Kim, Jong-Hwa;Han, Kap-Hoon
    • Korean Journal of Microbiology
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    • v.45 no.4
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    • pp.312-317
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    • 2009
  • Genome analysis of a model filamentous fungus, Aspergillus nidulans, revealed that there are six putative forkhead genes. Among them, fkhF (AN8949.2) showed A. nidulans-specific. fkhF gene is located in chromosome VII and composed of 2,337 bp coding region for 778 amino acid. Since little is known about the involvement of the forkhead proteins in the developmental process of the filamentous fungi, including A. nidulans, we generated a deletion mutant of fkhF gene and analyzed. Deletion of fkhF resulted in less-dense conidiophore formation in a solid culture. However, the sexual developmental process or cleistothecia formation was normal. Furthermore, fkhF deletion mutant produced conidiophores and conidia under the submerged culture, suggesting that the fkhF gene is involved in repression of inappropriated induction and maturation of asexual developmental process but not in sexual development.

Effect of Vinyltriethoxysilane Content on Mechanical and Physical Properties of Precipitated Silica Reinforced Silicone Rubber (비닐트리에톡시실란 함량에 따른 습식실리카로 충전된 실리콘 고무의 기계적 및 물리적 물성)

  • Jin, Sung-Hoon;Hong, Jin-Ho;Kim, Il;Yun, Ju-Ho;Shim, Sang-Eun
    • Polymer(Korea)
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    • v.35 no.4
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    • pp.342-349
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    • 2011
  • The effect of the amount of vinyltriethoxysilane (VTEOS) in precipitated silica filled silicone rubbers was extensively investigated in terms of the change of mechanical properties, heat resistance, oil resistance, compression set, resilience, and curing characteristics. As the content of VTEOS increased from 0 to 2.0 phr, the hardness of the silicone rubber increased, however, tensile strength, elongation at break, and tear strength decreased. From heat resistance test, the change of mechanical properties was pronounced for silicone rubber treated with more VTOES. The best heat resistance was achieved at 2.0 phr VTOES. In addition, oil resistance was proportionally improved with VTEOS content. From oil resistance test. it was found that the decrease in hardness and maximum elongation was reduced for VTEOS-added systems. Finally, resilience, compression set, degree of cure and crosslink density were significantly enhanced with the amount of VTEOS.

Gas Permeation Study of Fuel Hose Composed as Inner Material of FKM Rubber (FKM 고무를 내층재료로 한 연료호스의 가스 투과성 연구)

  • Kim, Do-Hyun;Doh, Kyung-Hwan;Park, Hyun-Ho;Lee, Chang-Seop
    • Elastomers and Composites
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    • v.40 no.2
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    • pp.83-92
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    • 2005
  • To develop an automotive fuel hose suitable to the international environmental regulation, FKM rubber materials as an inner material of fuel hole were prepared with different chemical compositions. Measurement of the properties of thermal resistance, oil resistance, fuel resistance, gas permeability including fundamental properties were performed to investigate compatibility for a fuel hose material. Fundamental properties, thermal resistance, oil resistance, fuel resistance and permeability of FKM rubber materials were improved with fluorine content. When the carbon content was 20 phr, FKM compounds with fluorine contents of 66%, 09% and 71% were shown to satisfy the specification oi fuel hose. The gas permeability of NBR and FKM compounds was measured on the mixed fuel oils prepared with isooctane-toluene and gasoline-methanol. FKM rubber materials showed a small difference in penetrated amount of fuel and showed a permeability superior to NBR material. he permeability of FKM rubber materials was not influenced by the contents of fuel oil. Thermal properties of 69% FKM rubber experienced by permeability testing were not variated.

Comparison of Performance & Jet Fuel Oil Resistance of Joint Sealant Materials for Airside (공항용 조인트 충진재의 성능 및 내유저항특성 비교연구)

  • Park, Tae Soon;Lee, Keun Sik;Lee, Su Hui
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.4D
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    • pp.587-592
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    • 2006
  • The joint sealants used in the airside should resist the high temperature of the jet blast and the jet fuel oil spilled when the aircraft is maintained and filled. The material of joint sealant for the airside should be different from that for the road due to these characteristics. Three different kinds of the joint sealant materials were tested in this paper. The materials include the polysulfide, the polyurethane and the silicon. The test results show that the physical properties and the performance of the polysulfide show the high resistance to the jet blast and the jet fuel oil. When the characteristics of the airside considered, the polysulfide may apply in the both of the runway and the apron area, the polyuretane can be applied the taxiway. The use of the silicon sealant is not recommended for the airside.

Sexual Reproduction in Unicellular Green Alga Chlamydomonas (수염녹두말속(Chlamydomonas) 단세포 녹조의 유성생식)

  • Lee, Kyu Bae
    • Journal of Life Science
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    • v.27 no.1
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    • pp.100-121
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    • 2017
  • The sexual reproduction of the unicellular green alga Chlamydomonas is reviewed for a comprehensive understanding of the complex processes. The sexual life cycle of C. reinhardtii is distinguished into five main stages: gametogenesis, gamete activation, cell fusion, zygote maturation, and meiosis and germination. Gametogenesis is induced by nitrogen starvation in the environment. C. reinhardtii has two mating types: mating type plus ($mt^+$) and mating type minus ($mt^-$), controlled by a single complex mating type locus ($MT^+$ or $MT^-$) on linkage group VI. In the early gametogenesis agglutinins are synthesized. The $mt^+$ and $mt^-$ agglutinins are encoded by the autosomal genes SAG1 (Sexual AGglutination1) and SAD1 (Sexual ADhesion1), respectively. The agglutinins are responsible for the flagellar adhesion of the two mating type of gametes. The flagellar adhesion initiates a cAMP mediated signal transduction pathways and activates the flagellar tips. In response to the cAMP signal, mating structures between two flagella are activated. The $mt^+$ and $mt^-$ gamete-specific fusion proteins, Fus1 and Hap2/Gcs1, are present on the plasma membrane of the two mating structures. Contact of the two mating structures leads to develop a fertilization tubule forming a cytoplasmic bridge between the two gametes. Upon fusion of nuclei and chloroplasts of $mt^+$ and $mt^-$ cells, the zygotes become zygospores. It is notable that the young zygote shows uniparental inheritance of chloroplast DNA from the $mt^+$ parent and mitochondrial DNA from the $mt^-$ parent. Under the favorable conditions, the zygospores divide meiotically and germinate and then new haploid progenies, vegetative cells, are released.