• Title/Summary/Keyword: 유사농도분포

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Concentration Distribution of PCBs in Soil Around Industrial Complex and Relationship with PCBs Sources (공단지역 주변 토양 중 PCBs 농도분포 및 발생원 추정에 관한 연구)

  • Park, Seok-Un;Kim, Kyoung-Soo;Kim, Jong-Guk
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.5
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    • pp.521-527
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    • 2007
  • To investigate the relationship between PCB sources and concentration level in soil, PCBs concentration of 8 soil samples around Shiwa industrial complex were measured. The concentration of PCBs in soil samples were ranged from 2.43 to 274 ng/g dry (0.116 to 60.5 pg WHO-TEQ/g dry) md off-gas were ranged from 48.6 to $2872ng/m^3(0.00150\sim15.2ng\;WHO-TEQ/m^3)$; these are similar levels with results of previous study in Korea. The homologue patterns in soil samples were varied from sample to sample, but isomer patterns were very similar with each other. The two principal components were extracted by Principal Component Analysis(PCA) of 8 soil samples and cumulative factor loading was 95.7%. As the result of PCA, it could be expected that PCBs in soil samples of this study were more affected by PCB products than combustion process and mostly affected by already-known sources.

Surface Sediment and Suspended Material in Deukryang Bay (득량만의 퇴적물 및 부유물 특성)

  • 공영세;이병걸
    • 한국해양학회지
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    • v.29 no.3
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    • pp.269-277
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    • 1994
  • Process of resuspension and accumulation well explaines the characteristics of surface sediment size distribution and suspended material in Deukryang Bay. Most of the surface sediments of the bay show asymmetric unimodal size distribution, which is found also in sediments from western part of the inner shelf mud area between Keomundo and Yokchido islands. Investigation of the size curves indicates that surface sediment in Deukryang Bay is a deposit of suspended coastal sediment transported east along southern coast of Korea. The distribution pattern of coarse sit fraction content in the surface sediment is very similar to that of computed current velocity (Lee, 1994), suggesting that fine sediment on the bed may reassumed and accumulate repeatedly due to shallow depth and strong tidal current in Deukryang Bay. The process of repeated resuspension and accumulate repeatedly due to shallow depth and strong tidal current in Deukryang Bay. The process of repeated resuspension and accumulation seems to be responsible not only to the asymmetric size distribution of the surface sediment, but also to the amount of suspended material in the bay. The difference of suspended material concentration between surface and near bottom water in summer is two times as large as that the in winter. This seems to derive from the fact that stratification of water mass prevails in summer, while total water mass is vertically mixed in winter. It was found that the most important factors to decide distribution of suspended material in Deukryang Bay are the physical properties of water mass such as current velocity and stratification, and water depth, in part with the supply of suspended sediment by rivers.

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Comparison Study between Results of Ecosystem Model and Satellite Data in the Tokyo Bay (동경만의 생태계모델 결과와 위성자료의 비교연구)

  • Lee, Sung-Ae;Sugimori, Yasuhiro;Kim, Young-Seup
    • Journal of the Korean Association of Geographic Information Studies
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    • v.7 no.1
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    • pp.20-27
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    • 2004
  • The hydro-dynamical and ecological coupled model were applied in the Tokyo Bay, to evaluate the flow pattern including water quality parameters and the distribution of biomass flux, and to compare with the results obtained from the satellite data during March 2001. The flow pattern and salinity distribution obtained from the present model were nearly identical with those of the previous studies. SST from NOAA/AVHRR was $2.5^{\circ}C$ higher than model results in the mouth of bay and $0.5^{\circ}C$ lower than model results in the inner bay, respectively. It was found that the concentration of chlorophyll-a estimated from SeaWiFS was considerably higher than that of model result, regardless similar distribution pattern. This disagreement will be studied through the more elaborate investigation in the future.

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Distributions of 137Cs and 90Sr in the Soil of Uljin, South Korea (울진토양에서의 137Cs 및 90Sr 분포)

  • Song, JiYeon;Kim, Wan;Maeng, Seongjin;Lee, Sang Hoon
    • Journal of Radiation Protection and Research
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    • v.41 no.1
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    • pp.49-55
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    • 2016
  • Background: For the purpose of baseline data collection and enhancement of environmental monitoring the distribution studies of $^{137}Cs$ and $^{90}Sr$ in the soil of Uljin province was performed and the relation between surface soil activities and soil properties (pH, TOC and median of the surface soil) was analyzed. Materials and Methods: For 14 spots within 10 km from the NPP surface soil samples were collected and soils for depth profile were sampled for 3 spots in April 2011. Using ${\gamma}$-ray spectrometry with HPGe detector, the concentrations of $^{137}Cs$ were determined and the concentrations of $^{90}Sr$ were measured by counting ${\beta}$-activity of $^{90}Y$ (in equilibrium with $^{90}Sr$) in a gas flow proportional counter. Results and Discussion: The concentration ranges of $^{137}Cs$ and $^{90}Sr$ were $<0.479-39.6Bq{\cdot}(kg-dry)^{-1}$ (avg. $7.51Bq{\cdot}(kg-dry)^{-1}$) and $0.209-1.85Bq{\cdot}(kg-dry)^{-1}$ (avg. $0.74Bq{\cdot}(kg-dry)^{-1}$) which were similar to the reported values from other regions in Korea. The activity ratio of $^{137}Cs$ to $^{90}Sr$ in surface soils was around 9.67, which is much bigger than the initial value of 1.75 for worldwide fallouts because of faster downward movement of $^{90}Sr$ after fallout than that of $^{137}Cs$. For depth profile studies soils were collected down to 40 cm depth for the locations of Deokgu, Hujeong and Maehwa. The $^{137}Cs$ concentration distribution of the first two showed maximum values at top soils and decreased rapidly in exponential manner, while $^{90}Sr$ showed two local maximum values for soils near top and about 30 cm depth. Through linear fittings between the $^{137}Cs$ and $^{90}Sr$ concentrations of surface soil and pH, TOC and median of the surface soil, the only probable relationship obtained was between $^{137}Cs$ and TOC (determination coefficient $R^2=0.6$). Conclusion: The concentration ranges of $^{137}Cs$ and $^{90}Sr$ in Uljin were similar to the reported values from other regions in Korea. The only probable relationship obtained between activities and soil properties was between $^{137}Cs$ and TOC.

The Effects of Hydrologic Characteristics on Sediment Discharge in Streams with Small and Medium Size Watersheds (중소유역의 수문학적 특성이 하천유사량에 미치는 영향)

  • 김활곤;서승덕
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.38 no.3
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    • pp.127-136
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    • 1996
  • The purpose of this study is to provide with information for the water resources development and management in stream management planning, such as information on the sediment trensport, design of dam and water facilities, river improvement and flood plains management. The major results obtained from the field measurement and analysis of the watershed characteristics, hydraulic and sediment characteristics are as follows ; 1. The rating curve formulas obtained from the analysis of the hydraulic characteristics data collected are ; Q-=110.563 $(H-0.474)^2$ for 0.7m$(H-0.146)^2$ for 0.4m$Sr=aX{^2} {_1} X^{c}{_2}$, in the experimental watershed.

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Inherent optical properties of Scrippsiella trochoidea (적조생물 Scrippsiella trochoidea의 고유 광특성)

  • Lee, Nu-Ri;Moon, Jeong-Eon;Ahn, Yu-Hwan;Yang, Chan-Su;Yoon, Hong-Ju
    • Proceedings of the KSRS Conference
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    • 2007.03a
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    • pp.183-187
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    • 2007
  • 적조원격탐사의 기초연구로서 적조생물의 광학적 특성을 조사하였다. 연구에 사용된 적조생물 종은 와편모조류에 속하는 종으로 Scrippsiella trochoidea이다. 광학적 특성 조사를 위해 순수 배양된 생물종을 미세조류은행(KMCC)에서 구입하여 배양하였다. 배양된 샘플로 chlorophyll 농도, 홉광계수(absorption coefficient, a), 소산계수 (attenuation coefficient, c), 역산란계수(backscattering coefficient, $b_b$), 입자크기분포(size distribution, Fd)를 측정하였다. 본 연구의 결과는 2000년 적조 생물종 원격탐사 기술개발 보고서의 결과와 비교해 보았으며, 홉광계수 측정방법에 있어서 filter technique과 부유상태에서 측정한 결과를 비교하였다. 홉광계수에 있어서 기존연구와 본연구의 결과는 매우 유사한 홉광 스펙트럼올 나타내었으며,filter technique와 부유상태에서 측정한 홉광도는 filter technique를 이용한 것이 높은 값을 나타내었다. 이는 multiple absorption, 즉 ${\beta}-effect$에의한 것으로 보인다. 역산란 스펙트럼은 노이즈가 많이 나타났는데 이것은 농도가 충분하지 않아서 나타난 것으로 추정된다. 적조생물의 고유광특성이 해색에 영향을 미칠것이라고 보고 이들 결과는 해색을 재현하기 위한 해색모텔의 입력변수로 활용될 수 있다.

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The Method of Certificating Waterproof Effect for Consecutive Column-Wall Mass in Underground (주열식 지중연속벽체의 차수효과 확인 방안)

  • Koh, Yong-IL
    • Journal of the Korean GEO-environmental Society
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    • v.18 no.9
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    • pp.5-9
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    • 2017
  • On the flow of groundwater, the effect of consecutive column-wall in underground as a hydraulic barrier could be identified by conventional geotechnical methods ((1)visualiy identification of wall mass after underground excavating, (2)uniaxial compressive strength test for core of wall mass in underground, (3)in-situ permeability test in the hole after coring wall mass). However, for the cut off the leakage or infiltration of very high concentrated leachate from the waste landfill or the contaminated groundwater, the waterproof effect of consecutive column-wall in underground should be verified more objectively, by in-situ measuring of pH, temperature and salinity. and by evaluating of their consistency and similarity throughout analyzing the characteristics of basic components and their profiles through the series of chemical experiments. Furthermore, its waterproof effect could be verified additionally throughout deciding the similarity more simply by comparing the general distribution patterns including the difference of high and low peaks from the chromatograms using GC-MS for surrounding groundwater.

A Study on Seaweed Sea Staghorn(Codium fragile) Ethanol Extract for Antioxidant (해조류 청각(Codium fragile) 에탄올 추출물의 항산화에 관한 연구)

  • Lee, Ju-Hee;Kim, Bo-Ae
    • The Journal of the Convergence on Culture Technology
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    • v.5 no.4
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    • pp.467-472
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    • 2019
  • Seaweeds are rich in in minerals, vitamins, proteins, and fiber, and are classified as green algae, and they are distributed on the coasts of Korea, East Asia, Oceania, etc. and are used as a health function material as well as food ingredients in our countries and countries. In this study, Codium fragile was extracted from ethanol and concentrated to confirm DPPH radical scavenging activity, SOD activity, FRAP and ABTS cation radical scavenging ability. As a result, DPPH scavenging activity was 0.83, 22.83, 38.27, 40.93, 45.60% at 6.25, 12.50, 25, 50 and $100{\mu}g/mL$, SOD-like activity were 23.13, 33.63, 33.93, 44.07 and 59.07%. FRAP and ABTS showed antioxidant activity in a concentration-dependent manner, as in the previous experiment. Therefore, this study confirmed that it can be used as a cosmetic material using Codium fragile, a natural material.

Simulated Moving Bed(SMB) Chromatography Simulation for Loxoprofen Racemates Separation (록소프로펜 라세미체 분리를 위한 유사이동층 크로마토그래피의 전산모사)

  • Kim, In Ho;Song, Sung Moon
    • Korean Chemical Engineering Research
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    • v.49 no.5
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    • pp.623-627
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    • 2011
  • Simulated moving bed(SMB) chromatography was simulated for separating loxoprofen racemates. Aspen chromatography simulator was utilized with Henry's constants of loxoprofen racemates which were obtained by batch chromatography experiments. Raffinate stream concentrations as well as purities were calculated with various $m_2$ and $m_3$ values in the triangle diagram obtained from two Henry's constants 7.9 and 10.1. Purity values are high under the conditions that the $m_2-m^3$ coordinates are near the left central region in the diagram and feed flow rates are lower. Concentration profiles of raffinate and extract streams along SMB columns explain the purity change in the case of increasing the column numbers installed at SMB.

Heme과 Hemoglobin을 이용한 Pentachlorophenol 오염토양 정화

  • 강구영;정남현
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.49-53
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    • 2002
  • 워싱턴주 벤쿠버시 Bonneville 전력소 전주 보관 지역내 PCP와 creosote 오염토양 2g 당 0.020g heme에 0.108g $H_2O$$_2$을 혼합한 산화방법과 0.035g hemoglobin에 0.324g $H_2O$$_2$을 혼합한 산화방법을 비교ㆍ조사하였다. 오염토양에 $^{14}$ C-PCP을 첨가한 다음에 $^{14}$ C의 물질수지를 조사한 결과, 24시간동안 반응 후 $^{14}$ $CO_2$는 heme 과 hemoglobin반응에서는 각각 3.50g와 3.88% 생산되었다. $^{14}$ C 물질수지 분포는 heme 촉매 산화반응에서 용매 상에 43.01% 토양 상에는 46.03%이고, hemoglobin 촉매 산화반응에서는 용매 상에 39.21%와 토양 상에 51.25%로 비슷한 분포를 보였다. 실험실 규모 pan 실험에서 초기 PCP농도 273$\pm$20 mg/kg과 TPH 6379$\pm$45 mg/kg인 오염토양에서 hemoglobin 촉매 산화 반응이 초기반응을 제외하고 7일 이후 반응에서 heme 촉매 산화반응보다 빠르게 분해되었고, 35일 반응 이후 PCP는 10 mg/kg 이하의 값을 나타내었고, TPH도 유사한 결과를 보여 주었다. 그러므로 건조 hemoglobin과 과산화수소에 의한 PCP 오염토양 복원기술은 분해율이 높고 경제성을 가지고 있으므로 기존의 복원공정을 대안으로 제시될 수 있다.

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