• Proceedings of the Membrane Society of Korea Conference
• /
• 2004.05b
• /
• pp.184-187
• /
• 2004

고급산화법 중 하나인 광촉매인 TiO$_2$를 이용한 시스템은 300~400nm 파장의 UV영역에서 비교적 적은 에너지로 유기 오염 물질을 $CO_2$와 $H_2O$로 산화시킨다[1]. 따라서 폐수용액 중 오염물질을 제거한 경우에도 슬러리로 인한 2차 오염의 문제가 없다. 최근에는 난분해성 물질이나 독성을 가진 물질을 포함된 폐수처리 시설의 고도처리를 위하여 분리막을 도입하는 추세이다.(중략)

• Proceedings of the Membrane Society of Korea Conference
• /
• 1994.10a
• /
• pp.66-67
• /
• 1994

Polysulfone은 물리적, 화학적 성질이 우수하고 내열성과 내유기용매성등이 우수한 열가소성 수지로서 투과성능도 좋고 배제율도 높아 한외여과막이나 역삼투막, 기체분리막 등에 널리 이용되고 있다. 그러나 소수성 물질이기 때문에 처리과정에 있어서 fouling 발생이 큰 문제점으로 대두되고 있다. 따라서 이러한 fouling 현상을 억제하기 위해 화학적인 개질을 통하여 친수성을 높히는 방법이 필요하다. 본 실험에서는 친수성 고분자를 얻기 위하여 $-R_3N^+$기를 치환을 통하여 도입하였다. quaternary polysulfone의 치환여부를 확인하기 위하여 NMR, FT-IR를 이용하였고, 투과도와 용질배제율을 측정하여 개질의 효과를 살펴 보았다. 그리고 이온반발력을 이용하여 염료용액의 배제율을 향상시킬 수 있었다.

• Membrane Journal
• /
• v.33 no.4
• /
• pp.149-157
• /
• 2023

Covalent organic frameworks (COFs) have shown promise in various applications, including molecular separation, dye separation, gas separation, filtration, and desalination. Integrating COFs into membranes enhances permeability, selectivity, and stability, improving separation processes. Combining COFs with single-walled carbon nanotubes (SWCNT) creates nanocomposite membranes with high permeability and stability, ideal for dye separation. Incorporating COFs into polyamide (PA) membranes improves permeability and selectivity through a synthetic interfacial strategy. Three-dimensional COF fillers in mixed-matrix membranes (MMMs) enhance CO₂/CH₄ separation, making them suitable for biogas upgrading. All-nanoporous composite (ANC) membranes, which combine COFs and metal-organic framework (MOF) membranes, overcome permeance-selectivity trade-offs, significantly improving gas permeance. Computational simulations using hypothetical COFs (hypoCOFs) demonstrate superior CO₂ selectivity and working capacity relevant for CO₂ separation and H₂ purification. COFs integrated into thin-film composite (TFC) and polysulfonamide (PSA) membranes enhance rejection performance for organic contaminants, salt contaminants, and heavy metal ions, improving separation capabilities. TpPa-SO₃H/PAN covalent organic framework membranes (COFMs) exhibited superior desalination performance compared to traditional polyamide membranes by utilizing charged groups to enable efficient desalination through electrostatic repulsion, suggesting their potential for ionic and molecular separations. These findings highlight COFs' potential in membrane technology for enhanced separation processes by improving permeability, selectivity, and stability. In this review, COF applied for the separation process is discussed.

• Korean Journal of Optics and Photonics
• /
• v.8 no.1
• /
• pp.26-30
• /
• 1997

A wide dynamic range heterodyne interferometer scheme using intermode beat between a stabilized, dual frequency He-Ne laser beam has been applied for a measurement of optical thickness of an optical medium. Resolution of the optical thickness measurement is about $\pm$ 1.74 ${\mu}{\textrm}{m}$. Using this technique, we are able to determine the optical thickness of an organic dye film. We also obtain a map of the optical thickness variations over a surface of the film

• Journal of Conservation Science
• /
• v.30 no.1
• /
• pp.13-25
• /
• 2014

This study interpreted the chemicals of the pigments and the coloring techniques employed on Youngsan Ritual Ceremony Buddhist Painting through a nondestructive analysis method and a microscopic observation. Based on the interpretation, this study closely examined the chemical properties of the names of the coloring materials specified on the ceremonial writing of the Buddhist painting. It is estimated that lead white was used for the white pigments, orpiment and organic pigment for the yellow pigment, cinnabar/vermilion, minium, red ochre, and red dyes for the red pigments, malachite or atacamite for the green pigments, azurite and indigo for the blue pigments, and ink stick for the black pigments. The pigment names specified on the ceremonial writing are juhong, jungcheong, hayeop, whangdan, and whanggeum, and it was verified that juhong is cinnabar or vermilion, jungcheong is azurite, hayeop is malachite or atacamite, whangdan is minium, and whanggeum is a gold foil.

• Applied Chemistry for Engineering
• /
• v.34 no.5
• /
• pp.488-492
• /
• 2023

In this study, a carbon film derived from a polymer/lignin composite precursor was produced by a carbonization cycle with a controlled temperature profile. The feasibility of successful formation of the carbon film using the carbonization cycle was monitored. The adsorption behavior of the carbon film toward various molecules, such as nonpolar and polar organic molecules, and dyes was investigated using ultraviolet/visible (UV/Vis) spectroscopy compared with that of carbonized lignin. Cyclic voltammetry (CV) analysis proved that a robust carbon film was prepared by the carbonization cycle. It was also demonstrated that the carbonized lignin and carbon film showed adsorption capability toward all types of organic molecules, in particular organic dyes, owing to the carbonized lignin. This work provides important information for future relevant research.

• Analytical Science and Technology
• /
• v.7 no.1
• /
• pp.17-23
• /
• 1994

Through sol-gel process, inorganic/organic composite as a dye host was made. It was observed that this composite has about 90% of trnasmittance by UV/VIS spectrophotometer. The transmittance is the most important requirement to decide whether the composite could apply or not as the dye host. The transmittance was increased with decreasing HCl as a catalyst, aging time, and amount of PDMS. Also, fluorescent and transmittant charateristics of Rhodamine 6G Perchlorate that was doped into ORMOSIL were measured. The fluorescent intensity was increased and the trnasmittance was decreased with rising gelling temperature.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2013.02a
• /
• pp.676-676
• /
• 2013

무기물 양자점을 광감응 염료로 사용하는 경우 양자점의 사이즈 조절만으로 밴드갭을 조절할 수 있어 광학적 특성 조절이 용이하며, 유기 염료보다 광흡수 능력이 뛰어난 장점을 가진다. 특히 카드뮴 계열의 CdS, CdSe 양자점을 순차적으로 증착하여 사용하는 경우 가시광 전 영역을 효율적으로 흡수, 이용할 수 있어 광전기화학 셀의 광전극으로 사용 시 높은 성능을 기대할 수 있다. 하지만, 카드뮴 계열 양자점의 경우 광전기화학 셀로의 구동에 있어 안정성이 낮은 문제점이 있으며, 이는 양자점에 남아있는 정공이 관여하는 양자점 부식 반응으로 인한 것이다. 본 연구에서는 보다 안정적이면서도 고효율의 광전기화학적 수소생산 시스템을 위해, CdSe/CdS 양자점 감응형 ZnO 나노선 광전극에 IrO2 촉매물질을 증착하였다. CdSe/CdS 양자점이 가시광 전 영역을 흡수하며, ZnO 나노선 구조를 통해 생성된 광전자를 효율적으로 포집하여 높은 광전류 특성을 기대할 수 있다. 나아가 산소생산용 조촉매로 많이 사용하는 $IrO_2$ 촉매 물질의 추가증착을 통해 양자점에서 생긴 정공을 빼 줌으로서 정공이 관여하는 양자점 부식 반응을 방지할 수 있다. 실험결과 촉매물질의 증착 이후 광전류 생성 특성 및 수소생산량이 증가하였으며, 안정성 또한 상당히 향상된 것을 확인할 수 있었다.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.17 no.4
• /
• pp.74-80
• /
• 2009

Effect of dye wastewater on heavy metal removal using carboxylated alginic acid bead was performed. When carboxylated alginic acid bead was used as support, effect of dye wastewater on adsorption of $Pb^{2+}$ and $Cu^{2+}$ ions was very small. Also, when $Pb^{2+}$ was coexisted with dye wastewater, adsorption process was almost completed within 2-3 hrs and $Pb^{2+}$ ions (50 ppm) was almost removed with 0.3g of bead. This result means that carboxylated alginic acid bead has effective adsorbent for heavy metal removal in dye wastewater.

• 한국신재생에너지학회:학술대회논문집
• /
• 2009.11a
• /
• pp.350-354
• /
• 2009

In this work, polymer - inorganic composites have prepared using polymer such as polyethylene glycol (PEG)/poly (methyl methacrylate, PMMA) and inorganic nanofillers materials such as TiO2 nanotubes (TiNTs)/carbon nanotubes (CNTs). The extensive structural, morphological and ionic properties revealed that the high surface area and tubular feature of nanofillers improved the interaction and cross-linking to polymer matrix which is significantly enhanced the ionic conductivity and electrical properties of composite electrolytes. Comparably high conversion efficiency ~4.5% has been observed by using the newly prepared PEG-TiNTs composite solid electrolyte as compared with PMMA-CNTs electrolyte based DSSCs (~3%). The detailed comparative properties would be discussed in term of their structural, morphology, ionic and photovoltaic properties.