• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2019년도 춘계 학술논문 발표대회
• /
• pp.112-113
• /
• 2019

Recently, supplementary cementitious materials such as blast-furnace slag, fly ash and silica fume have been widely used as substitutes for cementitious materials. In this study, the deformation behavior of compressive loading of C₃S paste with 50% fly ash was analyzed by X-ray scattering data and pair distribution function analysis. The obtained results were compared with 131-day-old pure C₃S paste. The Ca(OH)₂ of the C₃S-FA paste showed almost complete elastic behavior, consistent with the deformation behavior of the r-range of 20 to 40, and the C-S-H phase contributed to the range of PDF r-range of less than 20. In addition, C-S-H of C₃S-FA showed greater deformation resistance than C₃S paste.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2019년도 추계 학술논문 발표대회
• /
• pp.170-171
• /
• 2019

When the cement paste in concrete is exposed to high temperatures, the mechanical performance decreases due to a series of reactions inside the cement. In this study, we investigated the change of nanostructure of $C_3S$ when $C_3S$ was exposed to high temperature using pair distribution function (PDF) based on high energy X-ray scattering. As a result of X-ray diffraction, there was no significant difference when $C_3S$ was heated at $300^{\circ}C$, but most of $Ca(OH)_2$ was decomposed into CaO at $500^{\circ}C$. In addition, it was confirmed that CaO is dominant in the nanostructure when $C_3S$ is heated to $500^{\circ}C$.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2016년도 추계 학술논문 발표대회
• /
• pp.94-95
• /
• 2016

Calcium Silicate Hydrate (C-S-H), which takes up most of the hydration products of Portland Cement (PC), has the greatest impact on the mechanical behavior and strength development of concrete. The exact mechanism of its deformation, however, has not yet been elucidated. The present study aims to demonstrate the mechanism of nano-deformation behavior of C-S-H in tricalcium silicate paste under compressive loading, unloading and reloading by interpreting atomic pair distribution function (PDF) based on synchrotron X-ray scattering. The strain of the tricalcium silicate paste for a short-range of 0 ~ 20 Å under compressive load exhibited two stages, I) nano-packing of interlayer of C-S-H and II) micro-packing of C-S-H globules, whereas the deformation for a long-range order of 20 ~ 40 Å was similar to that of a calcium hydroxide phase measured by Bragg peak shift. Moreover, the residual strains due to the plastic deformation of C-S-H was clearly observed.

• Nuclear Engineering and Technology
• /
• 제5권4호
• /
• pp.291-309
• /
• 1973

TRIGA Mark II와 III 원자로의 여러가지 가동조건에 있어서 노벽으로 부터의 누설 ${\gamma}$선에 의한 조사선양률을 3"$\times$3"원통형 NaI(T1) 섬광계수기와 400 channel파 고분석장치로 측정하였는데 측정된 spectrum으로부터 조사선양률을 산출하는데는 실제적면에서 복잡하기 짝이 없는 response matrix 방법대신 정도가 좋으면서도 비교적 그 과정이 단순한 Moriuchi의 specturm -조사선양률 환산 이론을 적용하였다. 연구결과에 따르면 노심에서 발생된 누설 ${\gamma}$선의 기본적인 spectrum 형태는 원자로의 열출력이나 차장벽에 의한 강도의 감쇠에 별로 영향을 받지 않고 있으며 원자로 누설${\gamma}$선에 의란 전조사선양률의 공기중에서의 감쇠는 폭 넓은 energy분포에도 불구하고 지수함수적 감쇠를 하고 있음이 판명되있다. 이 전조사선양률은 원자로의 열출력에 대체로 비례하고 있으나 TRIGA Mark III과 같은 가동형노심의 경우는 측정된 spectrum이 매우 다양한바, 그로부터 산출된 전조사선양률의 크기에는 관계없이, spectrum 분해방법을 적용하여 노심에서 발생된 누설 ${\gamma}$선과 원자로가동중 발생되는 여지 ${\gamma}$선의 기여를 판별 해석하는데 성공하였다.