• Title/Summary/Keyword: 원자분포

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Recoil Effects of Neutron-Irradiated Metal Permanganates (중성자조사 금속 과망간산염의 반조효과)

  • Lee, Byung-Hun;Kim, Jung-Gwan
    • Nuclear Engineering and Technology
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    • v.20 no.2
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    • pp.105-111
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    • 1988
  • The chemical effects resulting from the capture of the thermal neutron by manganese in various crystalline permanganates, that is, potassium permanganate ammonium permangante and barium permanganate, have been investigated. The effect of pH of solvent on the distribution of radioactive manganese chemical species, that is, cationic $^{56}$ Mn, $^{56}$ MnO$_2$ and $^{56}$ MnO$_4$$^{[-10]}$ produced in the permanganates by $^{55}$ Mn(n, r) $^{56}$ Mn reaction was studied by using various adsorbents and ion-exchanger, that is, zeolite A-3, kaolinite, alumina, manganese dioxide and Dowex-50 The distribution of radioactive MnO$_4$$^{[-10]}$ in kaolinite and alumina has higher than that in other adsorbents and ion-exchanger at a representative pH value of 4, 7 and 9, respectively. The yield of radioactive MnO$_4$$^{[-10]}$ is higher at pH 4 End pH 9 than at pH 7. The thermal annealing behavior of recoil manganese atoms produced in the permanganates by $^{55}$ Mn(n, r) $^{56}$ Mn reaction was also studied. The retention of MnO$_4$$^{[-10]}$ in the thermal annealing is increased as annealing temperature increases when it was treated at 10$0^{\circ}C$ and 13$0^{\circ}C$. The recoil effect of permanganates was explained by the hot zone model.

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Subcriticality Evaluation Using the Modified Neutron Source Multiplication Method (개선된 중성자 선원 증배법을 이용한 미임계도 평가)

  • Yoon, Seok-Kyun;Naing, Win;Kim, Myung-Hyun
    • Journal of Energy Engineering
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    • v.16 no.4
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    • pp.155-163
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    • 2007
  • To insure nuclear reactor safety, the reactivity of control rods should be calculated by measuring the criticality of reactor core and it is regularly performed during the annual physics test period. Also, the core criticality should be monitored during the start-up operation to avoid reactivity induced accidents. Many research works on control rod reactivity measurement and subcriticality measurement have been accomplished throughout the world for decades and recently a new method named "Modified Neutron Source Multiplication Method (MNSM)" was proposed in Japan which is known to be improved overcoming limitations of traditional Neutron Source Multiplication Method (NSM). In this study, MNSM was tested in calculation of subcriticalities and in evaluation of application validity using the educational reactor in Kyung Hee University, AGN-201. For this study, a revised nuclear data library and a neutron transport code system TRANSX - PARTISN were established. Correction factors for various control rod positions were produced using the k-effective values and the corresponding flux distributions and adjoint flux distributions. Experimental values of the core criticality were obtained using the neutron count rates of the BF3 proportional counters. The results showed that the expected reactivity worth of control rods by MNSM agreed well with the theoretical values and the correction factors contributed much for this purpose.

A Study on Spatial Downscaling of Satellite-based Soil Moisture Data (토양수분 위성자료의 공간상세화에 관한 연구)

  • Shin, Dae Yun;Lee, Yang Won;Park, Mun Sung
    • Proceedings of the Korea Water Resources Association Conference
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    • 2017.05a
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    • pp.414-414
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    • 2017
  • 토양수분은 지면환경에서 일어나는 수문 및 에너지 순환을 이해하는 데 있어 중요한 기상인자이다. 토양수분 현장관측은 땅속에 매설된 센서에 의해 상당히 정확하게 이루어지만, 관측점 수가 충분치 않아 공간적 연속성을 확보하지 못하는 어려움이 존재한다. 이에 광역적 및 연속적 관측이 가능한 마이크로파 위성센서가 토양수분 정보 획득을 위한 보조수단으로서 그 중요성이 부각되고 있다. 마이크로파 위성센서는 구름 등 기상조건의 제약을 받지 않으며, 1978년 이래 현재까지 여러 위성에 의해 25 km 및 10 km 해상도의 전지구 토양수분자료가 생산되어 왔다. 마이크로파 센서를 이용한 토양수분자료는 동일지점에 대하여 하루 2회 정도 산출되므로 적절한 시간분해능을 가지지만, 공간해상도가 최고 10 km로서 지역규모의 수문분석에 적용하기에는 충분치 않다. 이러한 토양수분자료의 공간해상도 문제 해결을 위하여 다양한 지면환경요소를 활용한 통계적 다운스케일링이 대안으로 제시되었다. 최근의 선행연구들은 대부분 방정식을 이용한 결합모형을 통해 통계적 다운스케일링을 수행하였는데, 회귀식과 같은 선형결합뿐 아니라 신경망이나 기계학습 등의 비선형결합에서도, 불가피하게 발생할 수밖에 없는 잔차(residual)로 인하여 다운스케일링 전후의 공간분포 패턴이 달라져버리는 문제를 안고 있었다. 회귀분석에 잔차의 공간내삽을 결합시킨 회귀크리깅(regression kriging)은 잔차보정을 통해 이러한 문제를 해결함으로써 다운스케일링 전후의 공간분포 일관성을 보장하는 기법이다. 이 연구에서는 회귀크리깅을 이용하여 일자별 AMSR2(Advanced Microwave Scanning Radiometer 2) 토양수분 자료를 10 km에서 1 km 해상도로 다운스케일링하고, 다운스케일링 전후의 자료패턴 일관성을 평가한다. 지면온도(LST), 지면온도상승률(RR), 식생온도건조지수(TVDI)는 일자별로 DB를 구축하였고, 식생지수(NDVI), 수분지수(NDWI), 지면알베도(SA)는 8일 간격으로 DB를 구축하였다. 이러한 8일 간격의 자료를 일자별로 변환하기 위하여 큐빅스플라인(cubic spline)을 이용하여 시계열내삽을 수행하였다. 또한 상이한 공간해상도의 자료는 최근린법을 이용하여 다운스케일링 목표해상도인 1 km에 맞도록 변환하였다. 우선 저해상도 스케일에서 추정치를 산출하기 위해서는 저해상도 픽셀별로 이에 해당하는 복수의 고해상도 픽셀을 평균화하여 대응시켜야 하며, 이를 통해 6개의 설명변수(LST, RR, TVDI, NDVI, NDWI, SA)와 AMSR2 토양수분을 반응변수로 하는 다중회귀식을 도출하였다. 이식을 고해상도 스케일의 설명변수들에 적용하면 고해상도 토양수분 추정치가 산출되는데, 이때 추정치와 원자료의 차이에 해당하는 잔차에 대한 보정이 필요하다. 저해상도 스케일로 존재하는 잔차를 크리깅 공간내삽을 통해 고해상도로 변환한 후 이를 고해상도 추정치에 부가해주는 방식으로 잔차보정이 이루어짐으로써, 다운스케일링 전후의 자료패턴 일관성이 유지되는(r>0.95) 공간상세화된 토양수분 자료를 생산할 수 있다.

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Estimation of Spatial Distribution Using the Gaussian Mixture Model with Multivariate Geoscience Data (다변량 지구과학 데이터와 가우시안 혼합 모델을 이용한 공간 분포 추정)

  • Kim, Ho-Rim;Yu, Soonyoung;Yun, Seong-Taek;Kim, Kyoung-Ho;Lee, Goon-Taek;Lee, Jeong-Ho;Heo, Chul-Ho;Ryu, Dong-Woo
    • Economic and Environmental Geology
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    • v.55 no.4
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    • pp.353-366
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    • 2022
  • Spatial estimation of geoscience data (geo-data) is challenging due to spatial heterogeneity, data scarcity, and high dimensionality. A novel spatial estimation method is needed to consider the characteristics of geo-data. In this study, we proposed the application of Gaussian Mixture Model (GMM) among machine learning algorithms with multivariate data for robust spatial predictions. The performance of the proposed approach was tested through soil chemical concentration data from a former smelting area. The concentrations of As and Pb determined by ex-situ ICP-AES were the primary variables to be interpolated, while the other metal concentrations by ICP-AES and all data determined by in-situ portable X-ray fluorescence (PXRF) were used as auxiliary variables in GMM and ordinary cokriging (OCK). Among the multidimensional auxiliary variables, important variables were selected using a variable selection method based on the random forest. The results of GMM with important multivariate auxiliary data decreased the root mean-squared error (RMSE) down to 0.11 for As and 0.33 for Pb and increased the correlations (r) up to 0.31 for As and 0.46 for Pb compared to those from ordinary kriging and OCK using univariate or bivariate data. The use of GMM improved the performance of spatial interpretation of anthropogenic metals in soil. The multivariate spatial approach can be applied to understand complex and heterogeneous geological and geochemical features.

Dosimetry of the Low Fluence Fast Neutron Beams for Boron Neutron Capture Therapy (붕소-중성자 포획치료를 위한 미세 속중성자 선량 특성 연구)

  • Lee, Dong-Han;Ji, Young-Hoon;Lee, Dong-Hoon;Park, Hyun-Joo;Lee, Suk;Lee, Kyung-Hoo;Suh, So-Heigh;Kim, Mi-Sook;Cho, Chul-Koo;Yoo, Seong-Yul;Yu, Hyung-Jun;Gwak, Ho-Shin;Rhee, Chang-Hun
    • Radiation Oncology Journal
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    • v.19 no.1
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    • pp.66-73
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    • 2001
  • Purpose : For the research of Boron Neutron Capture Therapy (BNCT), fast neutrons generated from the MC-50 cyclotron with maximum energy of 34.4 MeV in Korea Cancer Center Hospital were moderated by 70 cm paraffin and then the dose characteristics were investigated. Using these results, we hope to establish the protocol about dose measurement of epi-thermal neutron, to make a basis of dose characteristic of epi-thermal neutron emitted from nuclear reactor, and to find feasibility about accelerator-based BNCT. Method and Materials : For measuring the absorbed dose and dose distribution of fast neutron beams, we used Unidos 10005 (PTW, Germany) electrometer and IC-17 (Far West, USA), IC-18, ElC-1 ion chambers manufactured by A-150 plastic and used IC-l7M ion chamber manufactured by magnesium for gamma dose. There chambers were flushed with tissue equivalent gas and argon gas and then the flow rate was S co per minute. Using Monte Carlo N-Particle (MCNP) code, transport program in mixed field with neutron, photon, electron, two dimensional dose and energy fluence distribution was calculated and there results were compared with measured results. Results : The absorbed dose of fast neutron beams was $6.47\times10^{-3}$ cGy per 1 MU at the 4 cm depth of the water phantom, which is assumed to be effective depth for BNCT. The magnitude of gamma contamination intermingled with fast neutron beams was $65.2{\pm}0.9\%$ at the same depth. In the dose distribution according to the depth of water, the neutron dose decreased linearly and the gamma dose decreased exponentially as the depth was deepened. The factor expressed energy level, $D_{20}/D_{10}$, of the total dose was 0.718. Conclusion : Through the direct measurement using the two ion chambers, which is made different wall materials, and computer calculation of isodose distribution using MCNP simulation method, we have found the dose characteristics of low fluence fast neutron beams. If the power supply and the target material, which generate high voltage and current, will be developed and gamma contamination was reduced by lead or bismuth, we think, it may be possible to accelerator-based BNCT.

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Elucidation of Dishes High in N-Nitrosamines Using Total Diet Study Data (총식이조사 자료를 이용한 음식별 니트로사민 함량 분포 규명)

  • Choi, Seul Ki;Lee, Youngwon;Seo, Jung-eun;Park, Jong-eun;Lee, Jee-yeon;Kwon, Hoonjeong
    • Journal of Food Hygiene and Safety
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    • v.33 no.5
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    • pp.361-368
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    • 2018
  • N-nitrosamines are probable or possible human carcinogens, which are produced by the reaction between secondary amines and nitrogen oxide in the acidic environment or by heating. Common risk assessment procedure involves the comparison between exposures expressed in the unit, mg/kg body weight/day and the Health-Based Reference dose expressed in the same unit. This procedure is suitable for the policy decision-making and is considered as inappropriate for the consumers to get information about their dietary decision-making. Therefore, the distributions of NDMA (N-nitrosodimethylamine), NDBA (N-nitrosodibutylamine), the six N-nitrosamines (NDMA, NDBA, NDEA (N-nitrosodiethylamine), NPYR (N-nitrosopyrrolidine), NPIP (N-nitrosopiperidine), and NMOR (N-nitrosomorpholine) in the menus grouped based on the presence of main ingredients and cooking methods were analyzed to generate consumer-friendly information regarding food contaminants. Recipes and intakes were taken from 2014 to 2016 KNHANES (The Korean National Health and Nutrition Examination Survey) and only the data from ages of 7 years or older were used. The contamination data were collected from the 2014~2016 Total Diet Study and all the analysis were performed using R software. Rockfish, eel, anchovy broth and pollock were mainly exposed to N-nitrosamines. In terms of cooking methods, soups and stews appeared to contain the highest amount of N-nitrosamines. Cereals, fruits, and dairy products in the ingredient categories, and rice dishes and rice combined with others in recipe categories had the lowest level exposure to N-nitrosamines. In case of N-nitrosamines, unlike other cooking related food contaminants, boiled dishes such as soups and stews and dishes mainly consisting of fishes and shellfishes had highest level of exposure, showing a large discrepancy with the previous thought of processed meat is the main source of N-nitrosamines.

Blood Lead and ZPP Concentrations of Underground Parking Lot Workers (지하주차장 근무자의 혈중 연 및 Zinc Protoporphyrin 농도)

  • Jung, Tae-Heum;Jeon, Man-Joong;Hwang, Tae-Yoon;Kim, Chang-Yoon;Chung, Jong-Hak
    • Journal of Yeungnam Medical Science
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    • v.15 no.2
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    • pp.224-236
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    • 1998
  • A study was conducted to investigate the blood lead and zinc protoporphyrin(ZPP) concentrations of the underground parking lot workers who exposed to vehicular exhaust aerosols which contained lead. The blood samples were collected from 25 study subjects of underground parking lot and from 33 controls in Taegu, from July to October, 1997. And also the related factors to the blood lead and ZPP concentrations were investigated. Blood lead concentration and ZPP concentration were measured by flameless furnace atomic absorption spectrophotometer (1L.551) and hemetofluorometer, respectively. The mean blood lead concentrations of study subjects and controls were $23.10{\pm}20.77{\mu}g/dl$ and $12.99{\pm}12.71{\mu}g/dl$, respectively(p<0.05), and the mean blood ZPP concentrations of study subjects and controls were $40.72{\pm}9.46{\mu}g/dl$ and $38.21{\pm}10.97{\mu}g/dl$, respectively. No significant correlations were observed between the blood lead concentration of the study subjects and their job duration and between blood ZPP concentration of the study subjects and their job duration. There were no statistically significant differences in the blood lead concentration and the blood ZPP concentration of smokers and nonsmokers. In multiple regression analysis on blood lead concentration of the study subjects and controls, occupation was a only significant dependent variable. In case of bood ZPP concentration, age was a only significant dependent variable in the study subjects and controls.

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THE CHANGE OF THE CONFIGURATION OF HYDROXYAPATITE CRYSTALS IN ENAMEL BY CHANGES OF PH AND DEGREE OF SATURATION OF LACTIC ACID BUFFER SOLUTION (유산 완충용액의 pH 및 포화도 변화에 따른 법랑질 내 수산화인회석 결정 형태의 변화)

  • Chon, Young-Eui;Jung, Il-Young;Roh, Bung-Duk;Lee, Chan-Young
    • Restorative Dentistry and Endodontics
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    • v.32 no.6
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    • pp.498-513
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    • 2007
  • Since it was reported that incipient enamel caries can be recovered, previous studies have quantitatively evaluated that enamel artificial caries have been, remineralized with fluoride showing simultaneously the increase of width of surface layer and the decrease of width of the body of legion. There is, however, little report which showed that remineralization could occur without fluoride. In addition, the observations on the change of hydroxyapatite crystals also have been scarcely seen. In this study, enamel caries in intact premolars or molars was induced by using lactic acidulated buffering solutions over 2 days. Then decalcified specimens were remineralized by seven groups of solutions using different degree of saturation(0.212, 0.239, 0.301, 0.355) and different pH(5.0, 5.5, 6.0) over 10 days. A qualitative comparison to changes of hydroxyapatite crystals after fracturing teeth was made under SEM(scanning electron microscopy) and AFM(atomic force microscopy). The results were as follows: 1. The size of hydroxyapatite crystals in demineralized area was smaller than the normal ones. While the space among crystals was expanded, it was observed that crystals are arranged irregularly. 2. In remineralized enamel area, the enlarged crystals with various shape were observed when the crystals were fused and new small crystals in intercrystalline spaces were deposited. 3. Group 3 and 4 with higher degree of saturation at same pH showed the formation of large clusters by aggregation of small crystals from the surface layer to the lesion body than group 1 and 2 with relatively low degree of saturation at same pH did. Especially group 4 showed complete remineralization to the body of lesions. Group 5 and 6 with lower pH at similar degree of saturation showed remineralization to the body of lesions while group 7 didn't show it. Unlike in Group 3 and 4, Group 5 and 6 showed that each particle was densely distributed with clear appearance rather than crystals form clusters together.

Atomic Absorption Spectrophotometric Analysis of Copper In the Soil s of Orchards (원자흡광법(原字吸光法)에 의(依)한 과수원(果樹園) 토양중(土壤中)의 동함량(銅含量) 분석(分析)에 관(關)한 연구(硏究))

  • Park, Seung Heui
    • Korean Journal of Agricultural Science
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    • v.7 no.1
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    • pp.52-58
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    • 1980
  • This study was conducted to detect copper which is considered in the soils of orchards, since copper fungicide has been applied to fruit trees. Soil samples taken from the fields of the chief producing districts of apple (Chungju, Yesan, Daegu), pear (Yangju, Bucheon, Seonghwan) and citrus (Seogypo in Jeju island) were analysed by an atomic absorption spectrophotometer. The results obtained were summarized as follows ; 1. In orchards of apple, the amount of copper of soils from Yesan, Chungju and Daegu were ranged 2.6-171.3ppm, 2.2-136.1ppm and 14.3-134.6ppm, respectively. Very little copper was detected from the soils in the field which has been cultivated for less than 20 years. About 100ppm and 130-170ppm of copper were detected in the field which has been cultivated for 30 years and for 50-60 years, respectively. Most of the copper was detected in the surface layer of soils (0-10cm), while very low content of copper was detected in the deeper layer of soils (10-20cm). 2. In orchards of pear, 20-30ppm of copper was detected from the surface of soils in the field which has been cultivated for more than 30 years and the highest level of copper, 36.8ppm, was detected from Yangju area. The amount of copper of soils from Yangju, Seonghwan and Bucheon were ranged 3.6-36.8ppm, 9.7-19.4ppm and 3.6-24.7ppm, respectively. 3. In orchards of citrus of Jeju island, only trace amount and 23-38ppm of copper were detected in the fields cultivated for 15 years and 20-30 years, respectively. The highest level of copper, 57ppm, was detected from the surface layer of soils in the field which has been cultivated for 35 years, but in most of the soil samples tested, only the natural background level of copper, about 20ppm, was detected. 4. The levels of copper residue in all the soil samples tested were lower than the tolerance level (125ppm of copper which is extracted in 0.1N-HCl solution), except those of copperr residue, 130-170ppm, that were detected from the orchards of apple which have been under cultivation for 50-60 years. Hence no problem for the farming could be speculated with the present concentration of copper analysed.

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Development of Forest Volume Estimation Model Using Airborne LiDAR Data - A Case Study of Mixed Forest in Aedang-ri, Chunyang-myeon, Bonghwa-gun - (항공 LiDAR 자료를 이용한 산림재적추정 모델 개발 - 봉화군 춘양면 애당리 혼효림을 대상으로 -)

  • CHO, Seung-Wan;KIM, Yong-Ku;PARK, Joo-Won
    • Journal of the Korean Association of Geographic Information Studies
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    • v.20 no.3
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    • pp.181-194
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    • 2017
  • This study aims to develop a regression model for forest volume estimation using field-collected forest inventory information and airborne LiDAR data. The response variable of the model is forest stem volume, was measured by random sampling from each individual plot of the 30 circular sample plots collected in Bonghwa-gun, Gyeong sangbuk-do, while the predictor variables for the model are Height Percentiles(HP) and Height Bin(HB), which are metrics extracted from raw LiDAR data. In order to find the most appropriate model, the candidate models are constructed from simple linear regression, quadratic polynomial regression and multiple regression analysis and the cross-validation tests were conducted for verification purposes. As a result, $R^2$ of the multiple regression models of $HB_{5-10}$, $HB_{15-20}$, $HB_{20-25}$, and $HBgt_{25}$ among the estimated models was the highest at 0.509, and the PRESS statistic of the simple linear regression model of $HP_{25}$ was the lowest at 122.352. $HB_{5-10}$, $HB_{15-20}$, $HB_{20-25}$, and $HBgt_{25}-based$ models, thus, are comparatively considered more appropriate for Korean forests with complicated vertical structures.