• Applied Chemistry for Engineering
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• v.33 no.2
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• pp.126-132
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• 2022

Alkaline fuel cells using liquid fuels such as hydrazine and ammonia are gaining great attention as a clean and renewable energy solution possibly owing to advantages such as excellent energy density, simple structure, compact size in fuel container, and ease of storage and transportation. However, common shortcomings including cathode flooding, fuel crossover, side yield reactions, and fuel security and toxicity are still challenging issues. Real time monitoring of fuel concentrations integrated into a fuel cell device can help improving fuel cell performance via predicting any loss of fuels used at a cathode for efficient energy production. There have been extensive research efforts made on developing real-time sensing platforms for hydrazine and ammonia. Among these, recent advancements in electrochemical sensors offering high sensitivity and selectivity, easy fabrication, and fast monitoring capability for analysis of hydrazine and ammonia concentrations will be introduced. In particular, research trend on the integration of metallic and metal oxide nanoparticles and also their hybrids with carbon-based nanomaterials into electrochemical sensing platforms for improvement in sensitivity and selectivity will be highlighted.

• Journal of Aerospace System Engineering
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• v.17 no.6
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• pp.1-8
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• 2023

Research, such as developing alternative energy in the transportation field, including aviation, is being actively conducted to solve the issue of current climate change. Interest in ammonia fuel as a carbon free energy (CFE) source is increasing due to the ease of liquefaction and transportation and similarity in energy density to that of methanol. However, explosiveness and toxicity of ammonia make it difficult to handle. Therefore, in this study, stable ammonia production was attempted using relatively easy-to-handle urea water solution (UWS). High temperature steam was used to promote the hydrolysis of ammonia. In order to determine the causes for ammonia production below the theoretical equivalent ratio, it was suggested that there were not enough collisions to promote the hydrolysis based on the kinetic theory of gases. The hydrolysis of unreacted isocyanic acid (HNCO) was tested according to the change in water supply. As a result, an increased amount of ammonia produced was confirmed. The increased amount of ammonia produced in a certain section was dependent on the steam temperature and the flow rate of water supplied.

• Proceedings of the Korea Water Resources Association Conference
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• 2005.05b
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• pp.393-398
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• 2005

Suspended fine mineral particles are deposited at the areas with low flow velocity and low transportation capacity in rivers, reservoirs and lakes. It can be contaminated by heavy metals. Examples of problem fields art dredging of sediment, water pollutants, and maintenance of navigation channels and construction works. To deal with the settling problems it is necessary to understand tile physico-chemical characteristics of cohesive sediment under varying density of particle and ion addition(NaOH, HCl, NaCl), which is dissolved in river, because fine-grained cohesive sediment can lead to flocculation with the physico-chemical influences and takes different characteristics. Experiments with fresh and saline water are followed with fine-grained sediments(alumina and quartz) in settling columns. Settling velocity of suspended fine particles in still water was measured with a pressure sensor(maximum 10 mbar). Until the initial concentration of 20,000 mg/1 of alumina and quartz the settling velocity was on the increase. Above this initial concentration was it on the decrease. In an acid condition, which causes strong flocculation, average settling velocity of quartz powder was high. In an alkaline water low average settling velocity of it was observed. However, alumina behaved exactly contrarily.

• Journal of Advanced Navigation Technology
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• v.24 no.5
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• pp.444-449
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• 2020

I proposed small ambulatory robot actuators using piezoelectric benders. In order to make the motion of the biomimetic robot legs similar to the movements of the cockroaches or similar insects, two pairs of legs in the diagonal direction in the four leg structures are required to make the same movement. And elliptical displacement is realized by taking into account horizontal and vertical displacement of multimode oscillations and driving them by electrical signals with differences step by step, for example of 90° the T-shaped robot actuator showed wide range of speed (From 2 mm/sec. up to 266 mm/sec.) and ability of transportation (up to 10 g with 50 mm/s). Locomotive performance of the robot was competitive to the preceding robots, and moreover, the modular type actuators of a segmented myriapods robot could be added and removed for different tasks or performances.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.785-788
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• 2008

This study is focused on applying heavyweight concrete to ballast used to have stability of a ship. Generally, heavyweight concrete is made from a high density aggregate like magnetite or limonite. However, these materials are hard to obtain them from relevant companies and so expensive. Therefore, this study plans to product heavyweight ballast concrete which is easy to obtain by recycled iron slag. Heavyweight ballast concrete isn't required to meet some compressive strength in use, but it is required to have high flowable and 2.7t/m3 of bulk density to fill the ballast tank densely. The designed field mix proportion of concrete based on the results of pre-experiment shows it can control the temperature crack and has superior chloride corrosion resistance after conducting chloride corrosion experiment. Also, it is prefer that before airtightness voltile corrosion inhibiter(VCI) is added in airtight space of shipyard.

• Journal of Digital Convergence
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• v.14 no.8
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• pp.479-485
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• 2016

In 2007, London Thames Gateway delivery plan was started, and it was in progress to solve climate change, population density, housing problems, green space, regional imbalances, and transportation issues from east London and Kent to Essex. The plan was carried out faithfully local autonomy enlargement of local governments. This case is evaluated as a successful case of waterfront regeneration with well balanced on development and conservation. This study concludes as follows by comparing with this case and a new Han River management foundation plan. First, Seoul's new plan needs to change to diffuse thinking on comprehensively understanding. Second, local and central government, which are adjacent to Han River, need management scheme in cooperation. Third, the countermeasures for solving traffic problems in Seoul are required through the provision of transportation method to take advantage of the waterfront.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2018.11a
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• pp.170-172
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• 2018

지구 온난화로 인해 여름철 북극해의 해빙이 점차 감소함에 따라서 북극항로를 이용한 선박의 화물운송이 점차 증가하고 있다. IMO에서는 극지해역운항선박의 안전성과 해양오염방지를 위하여 2014년에 Polar Code를 개정하였으며, 2017년 1월부터 SOLAS협약과 MARPOL73/78협약에 추가되어 시행되고 있다. 본 연구는 해양수산부 해양안전 및 해양교통시설기술개발 사업으로 1) Polar Code 강제화에 따라 '극지해역 운항선박용 항해안전지원시스템의 개발'의 필요성과 2) 북극항로에 대한 국적선의 안전 운항 확보를 위한 '북극권 국가와의 국제협력 및 공조체계 구축'과 '극지 구난, 구조 및 환경보호 관련 국내법 및 규정 제정'을 위한 기반 연구의 필요성에 의거하여 2014년 11월 10일에 시작되었으며 2018년 12월 31일에 종료될 예정이다. 연구내용은 1) 고정밀도 북극항로 빙상정보 수치예측 시스템 개발, 2) 북극항로 안전속도 예측, 평가, DB구축 및 항행 모델 개발, 3) 북극항로 안전운항을 위한 항해계획 기술 개발, 4) 북극항로 운항선박 건조 및 안전항해 가이드라인 개발이다. 본 논문에서는 개발 중인 KRISO Arctic safe Routing System (KARS)에 대한 소개와 활용 결과 및 향후 계획에 대해서 설명하고자 한다. 본 KARS는 향후 지속적인 수정보완 작업을 통해서 완성도를 높여갈 예정이며, 검증단계를 거쳐서 최적하고 안전한 항로와 운항 관련 정보를 선사와 해기사에게 제공함으로서 북극항로 중 단기 운항계획 수립과 안전 운항을 지원할 수 있을 것으로 기대된다.

• Journal of the Korean Institute of Gas
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• v.26 no.3
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• pp.38-44
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• 2022

As the supply of hydrogen charging stations for hydrogen supply accelerates due to the hydrogen economy revitalization policy, the risk of accidents is also increasing. Since most hydrogen explosion accidents lead to major accidents, it is very important to secure safety when using hydrogen energy. In order to utilize hydrogen energy, it is essential to secure the safety of hydrogen storage containers used for production, storage, and transportation of liquid hydrogen. In this paper, in order to evaluate the structural safety of a hydrogen-filled pressure vessel, the behavioral characteristics of gas pressure were analyzed by finite element analysis. SA-372 Grade J / Class 70 was used for the material of the pressure vessel, and a hexahedral mesh was applied in the analysis model considering only the 1/4 shape because the pressure vessel is axisymmetric. A finite element analysis was performed at the maximum pressure using a hydrogen gas pressure vessel, and the von Mises stress, deformation, and strain energy density of the vessel were observed.

• Journal of the Korean Institute of Gas
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• v.27 no.3
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• pp.19-26
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• 2023

Hydrogen, a clean energy source free of COx emissions, is poised to replace fossil fuels, with its usage on the rise. Despite its high energy content per unit mass, hydrogen faces limitations in storage and transportation due to its low storage density and challenges in long-term storage. In contrast, ammonia offers a high storage capacity per unit volume and is relatively easy to liquefy, making it an attractive option for storing and transporting large volumes of hydrogen. While NH₃ decomposition is an endothermic reaction, achieving excellent low-temperature catalytic activity is essential for process efficiency and cost-effectiveness. The study examined the effects of different zeolite types (5A, NaY, ZSM5) on NH₃ decomposition activity, considering differences in pore structure, cations, and Si/Al-ratio. Notably, the 5A zeolite facilitated the high dispersion of Ni across the surface, inside pores, and within the structure. Its low Si/Al ratio contributed to abundant acidity, enhancing ammonia adsorption. Additionally, the presence of Na and Ca cations in the support created medium basic sites that improved N₂ desorption rates. As a result, among the prepared catalysts, the 15 wt%Ni/5A catalyst exhibited the highest NH₃ conversion and a high H₂ formation rate of 23.5 mmol/g_cat·min (30,000 mL/g_cat·h, 600 ℃). This performance was attributed to the strong metal-support interaction and the enhancement of N₂ desorption rates through the presence of medium basic sites.

• Journal of the Korean Regional Science Association
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• v.37 no.3
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• pp.3-18
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• 2021

The fourth Industrial Revolution is transforming the industrial structure of the region, and it is necessary to develop new industries and technologies that reflect regional characteristics. The purpose of this study is to measure the knowledge relatedness and technological complexity in Busan, Ulsan, and Gyeongnam, and to identify technologies with potential for regional industrial differentiation strategies. Using patent data from 2015 to 2019, co-occurrence matrices were derived from 652 IPC codes, and the knowledge relatedness density and technology complexity index were calculated. Network analysis was performed using the knowledge relatedness density. As a result of analysis, it was found that mechanical engineering occupied a large proportion, followed by chemistry and electrical engineering. As a result of applying the risk-benefit framework to derive technologies with the potential to differentiate local industries, the technological capabilities of low-risk-high-benefit were different. Among mechanical engineering, technologies such as engine, machine operation, and transportation were included in Busan. In Ulsan, environmental technology in chemical and materials, and heat treatment technology in mechanical engineering were technologies with low-risk and high-benefit capabilities. Gyeongnam showed competence in mechanical engineering, chemistry, and electrical engineering in some areas such as Gimhae, Yangsan, and Changwon. The results of this study are meaningful in that they identified technologies with potential for selecting and deriving strategic industries for regional growth based on latent knowledge in the region.