• Journal of the Korean Chemical Society
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• v.47 no.6
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• pp.671-674
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• 2003

• Applied Chemistry for Engineering
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• v.10 no.7
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• pp.1079-1085
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• 1999

An investigation was made of the effect of various transition metal catalysts, ligands, and a promoter on the synthesis of N,N'-diphenylurea(DPU) from nitrobenzene, aniline, and carbon monoxide. Homogeneous Pd and Ni catalysts were found to be highly efficient, giving almost quantitative isolated DPU yields at 100% nitrobenzene conversion. Bidentate ligand, 1,3-bis(diphenylphosphino)proane(dppp) showed much improved activity and significantly different reactivity relative to the usual monodentate $PPh_3$ ligand in the presence of Ni and Pd catalysts. These results were inferred to the effect of the cis coordination of bidentate dppp ligand on the metal. The use of a promoter $Et_4NCl$ was indispensable in the case of $PPh_3$, yet inhibited the reaction if used with dppp. It was possible to reuse the Pd-dppp catalyst system, although the catalytic activity was reduced slowly.

• The Korean Journal of Pesticide Science
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• v.12 no.1
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• pp.1-8
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• 2008

The widespread and diverse sulfonylurea (SU) resistance problem has found in Korea, where one-shot-treatment herbicides such as pylazosulfuron/molinate and bensulfuron/molinate have been used continuously since 1989. The SU-resistant weeds of 7 annual weeds and 3 perennial weeds as of 2008 have confirmed in paddy fields in Korea. An effective management to SU-resistant weeds requires an integrated approach toward the weed control system, in particular, as to the drastic changes of herbicides development. Recent trend of new paddy herbicides in Japan has been developing to maximize the management of SU-resistant weeds. In the future, it is expected that the development of paddy herbicides in Korea is likely to be shifted toward the new "one-shot-treatment" included with herbicides of over 3-ways to maximize the control of resistant weeds. Bromobutide and carfentrazone are effective against sedges and broad-leaved weeds, respectively, and benzobicyclone and pyrimisulfam are effective against sedges and broad-leaved weeds.

• Economic and Environmental Geology
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• v.53 no.3
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• pp.287-296
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• 2020

Mine Reclamation Project is being carried out with the aim of ensuring a sustainable green living and helping to develop eco-friendly mines by analyzing, removing and preventing the harmful factors. Mines developed during the japanese colonial period and mining boom period are still not repaired throughout the country, and from these scattered risks, public safety is worth pursuing as a top priority. The project that is close to public safety in the mine recalmation project is an emergency treatment, and the most widely used method is a filling method similar to the ground subsidence prevention. If dangerous mine cavity or tunnels are located in the mountains, charging with existing materials may not be possible, or unreasonable cases may occur, and new methods of technological development are required. Emergency actions should be carried out safely and efficiently to prevent the loss of precious people's lives on the hiking paths adjacent to dangerous mining sites. In these field conditions, urethane foam materials may be an alternative. In this study, the applicability of urethane foam materials in mining was reviewed through overseas cases. It was also tested on the appropriate depth of top soil for the protection of urethane foam materials through forest fire simulation test. The test result show that approximately 15cm of soil covering (recommended 20cm over) was suitable for maintaining the function of foam materials from forest fires.

• Journal of Adhesion and Interface
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• v.14 no.1
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• pp.28-35
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• 2013

In this study, we produced heat-shield coating materials using surface-treated Ga-doped ZnO (GZO) and investigated the dispersity of particle, visible light transmittance, ultraviolet light cut off, infrared light cut-off, heat-shielding property by surface-treating compounds and treatment conditions. In the case of using IPA or acryl binder for heat-shield coating, the dispersity of inorganic oxide particles was poor but in the case of using surface-treated inorganic oxide particles by hybrid compound having urethane (urea) group, acryl group and silica, dispersity of particle, visible light transmittance and haze were improved. We used the measurement kit and sunlamp for measuring heat-shielding property and confirmed that the internal temperature of the measurement kit using heat-shield film was lower more than $4.8^{\circ}C$ in comparison with using PET film for itself.

• Journal of Power System Engineering
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• v.21 no.5
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• pp.71-78
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• 2017

The purpose of this study is to propose the basic data for the development of a sensor capable of simultaneously measuring the liquid-level, concentration and temperature of a urea tank using ultrasonic and electrical conductivity sensors for diesel vehicles with a urea-SCR system. It was found that the liquid-level of the urea tank using the ultrasonic sensor showed a good linearity with the actual liquid-level, and the urea concentration maintained good linearity in the range of 32.5 wt% to 10 wt%. It was an effective measurement of urea concentration to use the electrical conductivity sensor in the temperature range of $-10{\sim}22^{\circ}C$ and to use the ultrasonic sensor at $22^{\circ}C$ or more. Simultaneous measurement of concentration, liquid-level and temperature of the urea tank will be possible by attaching the electrical conductivity sensor and the ultrasonic sensor (split-type) to one sensor together.

• Transactions of the Korean Society of Automotive Engineers
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• v.22 no.5
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• pp.13-19
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• 2014

Urea-SCR system is the selective catalytic reduction to reduce nitrogen oxides ($NO_x$) emitted from diesel vehicles. The objective of this study is numerical analysis of 3-dimensional unsteady melting problems of frozen urea by using an electric heater. It can be applied to determine capacity of power with respect to time and the location of the urea suction pipe in urea storage tank. The study includes the change of liquid volume fraction, temperature profiles and a influence of natural convection by using the commercial software STAR-CCM+(v7.06). The accuracy of the numerical analysis is estimated by comparisons with experimental data. After validation, a numerical analysis for freezing urea is conducted with four different heating power. From the results, it was found that relation of velocity of phase interface and amount of melting urea by increasing heating power in a container. There is also a difference in trend between velocity of phase interface and amounts of melting urea because of effect of natural convection.

• Journal of the Korean Applied Science and Technology
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• v.19 no.4
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• pp.311-319
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• 2002

Environmental friendly acrylic/urea high-solid paint(MUHC) were prepared through the curing reaction of acrylics resin(EBHC) containing 70wt% of solids content and butylated urea curing agent. The synthesis of EBHC Was done at $150^{\circ}C$ for 6 hours, and the results were obtained as follows : $M_{n}=1830{\sim}2190$, $M_{w}$ $3290{\sim}4000$, $M_{w}/M_{n}$=1.80{\sim}1.83$ viscosity=$110{\sim}352$ cps, and conversion=$82{\sim}92$%. After the film was coated with MUHC, the various physical properties were measured. They showed that enhancement of the coating properties such as adhesion, flexibility, abrasion resistance, impact resistance, and water resistance could be expected through introdl1cing caprolactone acrylate component in acrylics resin for the high-solids content acrylics/urea coatings.

• Journal of Power System Engineering
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• v.15 no.2
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• pp.55-60
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• 2011

The popularity of diesel engines is derived primarily from their higher thermal efficiency resulting from higher compression ratio. NOx removal from the diesel emissions is very important to meet stringent emission regulations. NOx emission from diesel engines is removed by an urea-SCR or an LNT system. The urea-SCR system needs the urea-solution supply system with concentration and level sensor. This study was carried out to develop a sensor for the measurement of urea-solution concentration by an electric conductivity method. Considering experimental parameters were the material of electrode, two kinds of electric power(AC or DC), the distance between two electrodes, and the length of electrode. It was found that the AC electric power was more useful to measure the urea-solution concentration compared to DC, because it prevented an ionization of the urea-solution. The silver rod coated with Pt is the most useful electrode, tendency of which is similar to Pt rod, and the cost is more economic. We could also find out the optimum distance between two electrodes and the length of electrode was 10mm and 3mm, respectively.

• Applied Chemistry for Engineering
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• v.3 no.1
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• pp.100-110
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• 1992

Arylsulfonyl urea derivatives can be easily prepared in good yield by treating amines with arylsulfonyl carbamates in aqueous solution : 1) N-Arylsulfonyl-N'-aryl urea derivatives, 2) N-Arylsulfony-N'-alkyl urea derivatives, 3) N-Arylsulfonyl-N'- heterocyclic urea derivatives. The proposed reaction mechanisms for preparing arylsulfonyl ureas involve formation of an ion-pair conformation by initial acid-base reaction, then formation of a so-called tetrahedral intermediate by nucleophilic addition, followed by an acid-catalyzed elimination of an alkoxide ion and loss of a proton.