• Title/Summary/Keyword: 우라늄광물

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Hydrochemistry of Groundwater in the Uraniferous Sedimentary Rocks of the Ogcheon Belt, Republic of Korea (옥천대 우라늄 광화대 부근 퇴적암 지하수의 수리화학적 특성)

  • Hwang, Jeong
    • Journal of the Korean earth science society
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    • v.31 no.3
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    • pp.205-213
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    • 2010
  • A hydrochemical comparative study of groundwater in uraniferous sedimentary rock of the Ogcheon belt was carried out to investigate the genetic relationship between uraniferous groundwater of Daejeon area and uraniferous sedimentary rocks of the Ogcheon zone. The groundwater shows weak alkaline pH values rangingfrom 6.4 to 8.1 and low Eh values ranging from -50 to 225 mV. The groundwaters to Ca-$HCO_3$ type that shows high concentration of $Ca^{2+}$ and $HCO_3^_$ due to the dissolution of carbonate mineral in limestone. The concentration of uranium in the groundwater was measured very low below $3.2{\mu}g/L$, while it was detected as much as $1165{\mu}g/L$ in the mine waste water. The low Eh value of groundwater is one of the main causes of low uranium concentration of groundwater in uraniferous sedimentary rocks in the Ogcheon belt. It is suggested that the uranium of groundwater in granitic region of Daejeon area was not mainly provided from uraniferous sedimentary rocks in the Ogcheon belt.

Hydrochemistry and Occurrence of Natural Radioactive Materials within Borehole Groundwater in the Cheongwon Area (청원지역 시추공 지하수의 수리화학 및 자연방사성물질 산출 특성)

  • Jeong, Chan-Ho;Kim, Moon-Su;Lee, Young-Joon;Han, Jin-Seok;Jang, Hyo-Geun;Jo, Byung-Uk
    • The Journal of Engineering Geology
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    • v.21 no.2
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    • pp.163-178
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    • 2011
  • A test borehole was drilled in the Cheongwon area to investigate the relationship between geochemical environment and the natural occurrence of radioactive materials (uranium and Rn-222) in borehole groundwater. The borehole encountered mainly biotite schist and biotite granite, with minor porphyritic granite and basic dykes. Six groundwater samples were collected at different depths in the borehole using the double-packed system. The groundwater pH ranges from 5.66 to 8.34, and the chemical type of the groundwater is Ca-$HCO_3$. The contents of uranium and Rn-222 in the groundwater are 0.03-683 ppb and 1,290-7,600 pCi/L, respectively. The contents of uranium and thorium in the rocks within the borehole are 0.51-23.4 ppm and 0.89-62.6 ppm, respectively. Microscope observations of the rock core and analyses by electron probe microanalyzer (EPMA) show that most of the radioactive elements occur in the biotite schist, within accessory minerals such as monazite and limenite in biotite, and in feldspar and quartz. The high uranium content of groundwater at depths of -50 to -70 m is due to groundwater chemistry (weakly alkaline pH, an oxidizing environment, and high concentrations of bicarbonate). The origin of Rn-222 could be determined by analyzing noble gas isotopes (e.g., $^3He/^4He$ and $^4He/^{20}Ne$).

Thiobacillus와 종속영양 미생물의 상호작용에 대하여

  • 이홍금
    • The Microorganisms and Industry
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    • v.16 no.2
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    • pp.14-16
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    • 1990
  • 미생물을 이용한 광물의 제련(microbial leaching)은 미생물의 몇가지 기전에 의해 광물성 sulfide를 산화시킴으로써 금속을 수용화시키는 과정이다. 이 방법은 현재는 구리나 우라늄 제련에 이용되고 있으며 광물질에 금속의 함량이 낮을 때 재래적 화학적 처리로 제련하는 것에 비해 훨씬 경제적이므로 앞으로의 자원획득문제에 기술적 및 생태적 중요성을 갖고 있다. 본 연구에서는 호산성의 Thiobacilli와 같은 biotope에 생존하는 종속영양미생물을 분리한 후 혼합 배양을 통해 Thiobacilli의 일차 생산자로서의 역할및 이때 생성된 유기물의 영향및 종속영양 미생물이 Thiobacilli에 미치는 영향에 대해 조사하고자 하였다.

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Geochemical Occurrence of Uranium and Radon-222 in Groundwater at Test Borehole Site in the Daejeon area (대전지역 시험용 시추공 지하수내 우라늄 및 라돈-222의 지화학적 산출특성)

  • Jeong, Chan Ho;Ryu, Kun Seok;Kim, Moon Su;Kim, Tae Sung;Han, Jin Suk;Jo, Byung Uk
    • The Journal of Engineering Geology
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    • v.23 no.2
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    • pp.171-186
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    • 2013
  • A drilling project was undertaken to characterize the geochemical relationship and the occurrence of radioactive materials at a test site among public-use groundwaters previously known to have high occurrence of uranium and radon-222 in the Daejeon area. A borehole (121 m deep) was drilled and core rocks mainly consist of two-mica granite, and associated with pegmatite and dykes of intermediate composition. The groundwater samples collected at six different depths in the borehole by a double-packed system showed the pH values ranging from neutral to alkaline (7.10-9.3), and electrical conductivity ranging from 263 to 443 ${\mu}S/cm$. The chemical composition of the borehole groundwaters was of the $Ca-HCO_3(SO_4+Cl)$ type. The uranium and Rn-222 contents in the groundwater were 109-1,020 ppb and 9,190-32,800 pCi/L, respectively. These levels exceed the regulation guidelines of US EPA. The zone of the highest groundwater uranium content occurred at depths of 45 to 55m. The groundwater chemistry in this zone (alkaline, oxidated, and high in bicarbonate) is favorable for the dissolution of uranium into groundwater. The dominant uranium complex in groundwater is likely to be $(UO_2CO_3)^0$ or $(UO_2HCO_3)^+$. Radon-222 content in groundwater shows an increasing trend with depth. The uranium and thorium contents in the core were 0.372-47.42 ppm and 0.388-11.22 ppm, respectively. These levels are higher values than those previously been reported in Korea. Microscopic observations and electron microprobe analysis(EPMA) revealed that the minerals containing U and Th are monazite, apatite, epidote, and feldspar. U and Th in these minerals are likely to substitute for major elements in crystal lattice.

Review on bioleaching of uranium from low-grade ore (저품위(低品位) 우라늄철(鑛)의 미생물 침출법(浸出法))

  • Patra, A.K.;Pradhan, D.;Kim, D.J.;Ahn, J.G;Yoon, H.S.
    • Resources Recycling
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    • v.20 no.2
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    • pp.30-44
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    • 2011
  • This review describes the involvement of different microorganisms for the recovery of uranium from the ore. Mainly Acidithiobacillus forrooxidans, Acidithiobacillus thiooxidans and Leptospirillum ferrooxidans are found to be the most widely used bacteria in the bioleaching process of uranium. The bioleaching of uranium generally follows indirect mechanism in which bacteria provide the ferric iron required to oxidize $U^{4+}$. Commercial applications of bioleaching have been incorporated for extracting valuable metals, due to its favorable process economics and reduced environmental problems compared to conventional metal recovery processes such as smelting. At present the uranium is recovered through main bioleaching techniques employed by heap, dump and in situ leaching. Process development has included recognition of the importance of aeration of bioheaps, and improvements in stirred tank reactor design and operation. Concurrently, knowledge of the key microorganisms involved in these processes has advanced, aided by advances in molecular biology to characterize microbial populations.