• Title/Summary/Keyword: 용해도 상수.

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Absorption Properties of Carbon Dioxide in Aqueous 2-Amino-2-methyl-1-propanol Solution (2-Amino-2-methyl-1-propanol 수용액에 대한 이산화탄소의 흡수특성에 관한 연구)

  • Park, Sang Hyun;Kim, Sung Hyun;Min, Byung Moo
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.107-114
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    • 1998
  • The solubilities of $CO_2$ in 20wt% and 30wt% aqueous AMP solution were obtained from experiments at 40, 50, 60, 70, $80^{\circ}C$. Using the modified Kent-Eisenberg model, equilibrium constants and correlations were determined from the regression of experimental results of 30wt% aqueous AMP solution. There were good agreements between the predicted $CO_2$ solubilities in 20wt% aqueous AMP solution and experimented values. The prediction was conducted at the condition in the literature and the predicted values calculated from the model and correlations which were obtained from this work agree well with the prediction from Deshmukh-Mather model. Thus, the modified Kent-Eisenberg model and correlated equations suggested by this work, resonably well represent vapor-liquid equilibrium of $CO_2$ with aqueous AMP solution. The calculation of chemical species concentration in the liquid phase was performed uslng equilibrium model and from this calculation, we confirm that good absorption capacity is due to the formation of unstable carbamate. Heat of solution(${\Delta}Hs$) was calculated from the solubility data using the Gibbs-Helmholtz equation.

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Study on the Dissolution of Sandstones in Gyeongsang Basin and the Calculation of Their Dissolution Coefficients under CO2 Injection Condition (이산화탄소 지중 주입에 의한 경상분지 사암의 용해반응 규명 및 용해 반응상수값 계산)

  • Kang, Hyunmin;Baek, Kyoungbae;Wang, Sookyun;Park, Jinyoung;Lee, Minhee
    • Economic and Environmental Geology
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    • v.45 no.6
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    • pp.661-672
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    • 2012
  • Lab scale experiments to investigate the dissolution reaction among supercritical $CO_2$-sandstone-groundwater by using sandstones from Gyeongsang basin were performed. High pressurized cell system (100 bar and $50^{\circ}C$) was designed to create supercritical $CO_2$ in the cell, simulating the sub-surface $CO_2$ storage site. The first-order dissolution coefficient ($k_d$) of the sandstone was calculated by measuring the change of the weight of thin section or the concentration of ions dissolved in groundwater at the reaction time intervals. For 30 days of the supercritical $CO_2$-sandstone-groundwater reaction, physical properties of sandstone cores in Gyeongsang basin were measured to investigate the effect of supercritical $CO_2$ on the sandstone. The weight change of sandstone cores was also measured to calculate the dissolution coefficient and the dissolution time of 1 g per unit area (1 $cm^2$) of each sandstone was quantitatively predicted. For the experiment using thin sections, mass of $Ca^{2+}$ and $Na^+$ dissolved in groundwater increased, suggesting that plagioclase and calcite of the sandstone would be significantly dissolved when it contacts with supercritical $CO_2$ and groundwater at $CO_2$ sequestration sites. 0.66% of the original thin sec-tion mass for the sandstone were dissolved after 30 days reaction. The average porosity for C sandstones was 8.183% and it increased to 8.789% after 30 days of the reaction. The average dry density, seismic velocity, and 1-D compression strength of sandstones decreased and these results were dependent on the porosity increase by the dissolution during the reaction. By using the first-order dissolution coefficient, the average time to dissolve 1 g of B and C sandstones per unit area (1 $cm^2$) was calculated as 1,532 years and 329 years, respectively. From results, it was investigated that the physical property change of sandstones at Gyeongsang basin would rapidly occur when the supercritical $CO_2$ was injected into $CO_2$ sequestration sites.

수처리용 약품과 소독제의 관리

  • Korea Water and Wastewater Works Association
    • 수도
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    • s.52
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    • pp.48-60
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    • 1990
  • 이 글은 경상남도에서 자체 실시한 상수도 교육 교재 중에서 수처리 약품, 소독제의 성상과 관리에 대한 내용을 발췌하여 계재하는 것으로 업무에 많은 참고 바랍니다.

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선박의 추진에너지 손실을 고려한 RCGA 기반 PID 형 자동조타시스템

  • An, Jong-Gap;Lee, Yun-Hyeong;Jin, Gang-Gyu;So, Myeong-Ok
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2007.12a
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    • pp.63-64
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    • 2007
  • 대양 항행하는 거의 모든 선박에서 항해사를 도와 선박의 회두각 유지 및 변침을 목적으로 사용되는 일반적인 오토파일럿 시스템용 대부분 PID형 제어기가 장착되어 있다. 오토파일럿 시스템의 제어상수는 운항 경제성 관점에서 선박의 추진 에너지 손실량(연료소비량)으로써 평가해야 한다. 본 논문에서는 선박 자동 조타 시스템의 정량적인 평가함수를 바탕으로 추진 에너지 손실량이 최소가 되도록 오토파일럿의 제어상수를 구하고자 한다. 이 때 제약조건, 즉 설계사양을 고려한 RCGA를 이용하여 제어상수를 탐색하고, 제안한 방법을 시뮬레이션을 통해 검증한다.

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The Microwave Dielectric Properties of Sintering Condition of ZST Ceramics for Movile Telecommunication System (이동 통신용 ZST세라믹스의 소결조건에 따른 고주파 유전 특성)

  • Seo, Jung-Chull;Lee, Hee-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05b
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    • pp.257-260
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    • 2000
  • 소결온도 및 소결시간의 변화가 ZST세라믹의 유전상수 $\varepsilon_{\tau}$, 품질계수 $Q{\cdot}f$ 및 공진주파수의 온도계수 $\tau_f$에 미치는 영향에 대하여 연구하였다. 소결온도를 $1420^{\circ}C$까지 올렸을 때 공진기 섭동방법으로 1.6GHz에서 측정한 품질계수 Q가 가장 높았으나, 소결밀도 및 유전상수는 오히려 감소하였다. 소결시간의 증가에 따른 품질계수 Q는 $1300^{\circ}C{\sim}1380^{\circ}C$ 온도 범위에서는 소폭 상승하였으며, 소결밀도 및 유전상수는 거의 일정하였다. 공진주파수의 온도계수 $\tau_f$는 소결온도 및 소결시간의 변화에는 거의 의존하지 않았다.

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