• Journal of the Mineralogical Society of Korea
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• v.20 no.1 s.51
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• pp.21-33
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• 2007

The dispersion/flocculation behavior of bentonite is a major concern in performance of drilling fluid. We studied the dispersion/flocculation characteristics of three commercial bentonites [two CMC (carboxymethyl cellulose) treated and one untreated] in waters of different pHs and salt concentrations. We also examined changes in the viscosity of bentonite suspensions in such waters as a major rheological property of drilling fluid. The dispersion/flocculation behaviors of bentonites were measured by two methods: colorimetric and light scattering method. Light scattering method allows estimating the floc diameter and flocculation rate. The dispersion and flocculation behaviors were diverse with the different bentonites and water qualities. In distilled water, all the bentonites were well dispersed up to first 10 minutes. After that, the CMC-bearing bentonites were flocculated. In salt waters, all the samples were flocculated and the flocculation rate is varied with salt concentration and polymer content. The volume of settled flocs decreased with increasing salt concentration. The flocculation rate and floc diameter increased with decreasing pH of solutions, whereas the volume of settled flocs increased with increasing pH of solutions. The bentonites of fast flocculation behavior had low viscosity. The results of the present study will be helpful in applying bentonites to drilling fluids in diverse environments.

• Membrane Journal
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• v.6 no.2
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• pp.96-100
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• 1996

In order to improve the permeability of the homogenous membrane of poly(carbobenzoxy-L-lysin)(PCLL), which has very high selectivity of helium gas to nitrogen gas, asymmetric porous membranes of PCLL were prepared by casting from 20% solutions in dioxane and dimethylformamide(DMF), respectively. The membranes were characterized by measuring the number of the pores, the pore size distribution of the surface(the skin layer) and the thickness of the skin layer by scanning electron microscope and transmission electron microscope. The mean pore size and the pore density were lower for the membrane cast from dioxane than that from DMF, which was explained by the mechanism of the formation of the pores in the asymmetric porous membrane. The permeability coefficient observed could be roughly explained by the viscous flow through the skin layer. However, the selectivity observed was against the theory of the viscous flow.

• The Korean Journal of Rheology
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• v.10 no.3
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• pp.173-183
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• 1998

본 연구에서는 Advanced Rheometric Expansion System(ARES)를 사용하여 대진폭 진동 전단 변형하에서 발생하는 폴리이소부틸렌(PIB) 농후 용액의 비선형 점탄성 거동을 저 장탄성율과 동적점도의 변형량 의존성 및 응력파형의 fast Fourier transform(FFT) 해석을 통해 고찰하였다. 스트레인 진촉을 단계적으로 증가시키면서 측정한 동적 점탄성으로 부터 저장탄성율 및 동적점도의 선형응답한계를 결정하고 이들에 미치는 각주파수의 영향을 조사 하였다. 그리고 응력파형의 Fourier 전개로부터 유도되는 비선형 점탄성함수를 사용하여 비 선형 거동을 설명하였다. 끝으로 비선형 점탄성 거동의 정도를 나타내는 비선형 거동 지수 를 정의하고 이들에 미치는 각주파수의 영향에 대해 검토하였다. 이상의 연구를 통해 얻어 진 결과를 요약하면 다음과 같다.(1) 선형 응답한계는 고분자 용액의 특성시간의 역수보다 높은 각주파수 범위에서는 일정한 값을 유지하지만 특성시간의 역수보다 낮은 각주파수 영 역에서는 각주파수가 감소할수록 증가한다. (2)선형응답한계 이상의 대변형하에서는 3차비선 형 점탄성 함수 이상의 고차항의 영향이 크게 작용하며 이로인해 비선형 거동이 발생된다. (3) 스트레인 진폭을 단계적으로 증가시키면서 측정한 저장탄성율 및 동적점도의 변형량 의 존성은 응력파형의 Fourier transform으로부터 유도된 1차 비선형 점탄성 함수의 변형량 의 존성을 나타낸다 (4) 저장탄성율 및 동적점도의 변형량 의존성으로부터 유도된 비선형 거동 지수는 탄성적 서질과 점성적 성질에 대한 비선형 특성을 평가하기 위한 유요한 방법으로 인정된다. (5) 비선형 점탄성 거동의 정도를 나탄는 비선형 거동지수는 특정한 각주파수에서 최대치를 가지며 또한 탄성적 거동이 점성적 거동에 비해 더욱 큰 각주파수 의존성을 나타낸다.

• Proceedings of the Korean Geotechical Society Conference
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• 2004.03b
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• pp.313-318
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• 2004

When plan breakdown by permeation of fill dam, bank by original decision scale model test of sound, original decision scale model test of sound that destroy having used water was carried out. And original decision scale model test of sound that use viscous fluid is carried out, but doubt remains in experiment result in state that verification of law of similarity is not achieved. In this study, verified according to Modeling of Models' method effecting law of similarity to use n ship horoscope solution of water.

• Applied Chemistry for Engineering
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• v.10 no.4
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• pp.581-585
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• 1999

The surface treated hydroxypropyl methylcellulose(HPMC) which could adjust the soluble time was synthesized when 40 wt % glyoxal solution and $KH_2PO_4$ were sprayed and reacted. And also, the solution dynamic at different ratios of two adding agents were identified If the surface of HPMC was treated with only glyoxal, the dispersion characteristics at different ratios of two adding agents were identified If the surface of HPMC was treated with only glyoxal, the dispersion was observed in the neutral solution and the viscosity was increased after directly dissolved as the solution become alkali condition. But the fine-powder type of HPMC which reacted with glyoxal and $KH_2PO_4$ was dispersed regardless of pH of solution and observed that it was dissolved and its viscosity increased after elapsing some time. With increasing amount of glyoxal and $KH_2PO_4$, the soluble time was delayed. The reaction condition was about 60 min at $75{\sim}85^{\circ}C$. Especially, the removal process of organic solvent after reaction was not required due to reaction under water solution without organic during glyoxal and $KH_2PO_4$ treatment. And also, the HPMC which could adjust the soluble rate in water or organic solvent by changing the degree of substitution of HPMC was synthesized.

• Korean Journal of Food Science and Technology
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• v.28 no.2
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• pp.384-388
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• 1996

Volatile flavor compounds of a sea tangle powder and two kinds of extract were analyzed by GC/MS. Extract I was prepared by boiling for 2 hours and centrifugation, while extract II by a sequential procedure of enzymatic hydrolysis, boiling in 1.5% NaCl solution. centrifugation and ultrafiltration to remove viscous materials. Fifty six volatile compounds from the dried sea tangle powder and the extracts were identified. The GC profiles of the extract II were different from those of the dried powder and the extract 1, indicating most volatile compounds were lost during removing viscous materials. Particularly those compounds in the initial and later parts of the GC profiles were significantly decreased and some of the compounds such as fatty acids. 3,5-nonadien-2-ol and 1-penton-3-ol were not detected.

• Applied Biological Chemistry
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• v.39 no.3
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• pp.165-171
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• 1996

The rheological properties of biopolymers produced by Bacillus sp. K-1 and its mutant strains(KM-21, KM-83) were studied. Apparent viscosity of biopolymers decreased as rising the temperature. The biopolymer produced by KM-21 strain showed 1.7 times low viscosity, 2.7 times low viscosity by K-1 and 1.9 times low viscosity by KM-83 at $80^{\circ}C$ compared with at $20^{\circ}C$ respectively. The viscosity of biopolymer solution also increased with increasing the polymer concentration and showed pseudoplastic characteristics which is high temperature dependency in all concentration. The change of the biopolymer viscosity on the pH showed the highest value at the pH 7.0 and it showed lower at acidic condition than at alkaline condition comparatively.

• Journal of the KSME
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• v.25 no.4
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• pp.312-319
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• 1985

유탁액(emulsion), 현탁액(suspension), 고분자용액(polymer solution) 및 고분자 용식물(polymer melt) 등의 유동에 대하여는 응력과 속도구배 사이에 선형적인 관계가 성립되지 않는다. 이런 유체들은 뉴우튼유체들의 경우와는 달리 단한번의 점성계수 측정만으로는 완전한 유변학 적(rheological) 특징을 파악할 수 없으므로 이들을 통털어서 비뉴우튼유체(non-Newtonian fluid )라고 한다. 이들의 응력과 속도구배 사이의 비선형적인 관계를 고찰하는 비뉴우튼유체역학은 최근에 빠르게 발전하고 있는 유체역학의 한 분야이며, 고분자 공정, 식품, 생물공학 및 유전등의 여러 산업부문에서 많은 관심의 대상이 되고 있다. 여기서는 뉴우튼유체에서 관찰될 수 없는 비뉴우튼유체의 독특한 유동 현상에 대한 이해를 증진시킴으로써, 비뉴우튼유체역학의 여러 문 제들을 취급하는데 필요한 기본지식을 제공하고자 한다.

• Journal of the KSME
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• v.35 no.1
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• pp.26-35
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• 1995

직물은 경사와 위사가 직각으로 교차하여 만들어진 것으로 여기에 사용하는 경사와 위사를 준 비하는 것을 제직 준비라 한다. 사이징(sizing)은 원사에 풀을 먹이는 제직 준비 공정의 한 가 지로서 제직시에 발생하는 마찰, 긴자으로부터 사(사)를 보호하여 제직 효율을 향상시키는 데 목적이 있다. 이러한 작업에서 호재가 균일하게 접착되고 양호한 품질로 대량생산을하여 경제 적인 합리화를 이루기 위하여 기계 사이징을 한다. 그림 1은 일반적인 합성 섬유용 사이징기의 구조이다. 호재는 용액상태로 준비되며, 원사는 호재용액을 가로질러 이동하여 연결되는 다음 공정에서 용이하게 취급되도록 건조되어 권추된다. 표면에 점성이 높은 호재가 부착된 원사를 단시간에 효과적으로 건조시키는 것이 사이징기 건조부의 역할이며, 가공되는 원사의 종류가 다양해짐에 따라 각 원사의 특성에 적합한 건조방법이 발전되어 왔다. 이 글에서는 건조시스템의 이론적인 고찰과 신합섬용 사이징기 SUPER-500에 대한 건조 시스템의 구조 및 동작 원리를 소개하고 향후 발전 방향을 제시코자 한다.

• Membrane Journal
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• v.6 no.4
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• pp.203-212
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• 1996

The operating parameters influencing on limiting flux was investigated in the ultrafiltration of PVA, and a new model, which is based on the Amiar model using the concept of heat transfer coefficient, was devised to overcome the limitation of gel-layer model. Using polysulfone plate-unit membrane (MWCO=20,000) and hollow-fiber membrane (MWCO= 30,000), ultrafiltration characteristics of PVA was examined with the variation of operating parameters such as cross flow velocity, transmembrane pressure, temperature, and PVA concentration. According to experimental results, the ultrafiltration of PVA through polysulfone membrane is mainly controlled by well-known phenomena of concentration polarization caused by gel-layer formation. On the contrary, in hollow fiber membrane was observed upward limiting flux which can not be explained by gel-layer model. New model was applied to predict the upward limiting flux behavior with partial satisfaction. The application of new model including viscosity correction factor, however, revealed that PVA ultrafiltration is closely related to the viscosity of permeating fluid.