• Journal of the Korean Chemical Society
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• v.39 no.12
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• pp.910-917
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• 1995

Analytical conditions for single column ion chromatographic determination of five anions such as F-, Cl-, NO2-, NO3-, and SO42- were optimized with respect to analysis time and separation efficiency. At the optimum condition of 2.0 mM phthalic acid at pH 4.5, five anions were effectively separated in 10 minutes so that analysis time could be reduced by 40% compared to other recommended conditions. Under this condition all the calibration curves of five anions were linear with a correlation coefficient > 0.999. Analytical results for nine commercial bottled waters were presented.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2005.05a
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• pp.178-182
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• 2005

본 연구에서는 추출제가 함유된 추출레진$(75{\sim}150{\mu}m)$으로 채워진 저압액체크로마토그래피를 이용하여 용리온도$(20{\sim}60^{\circ}C)$와 유속$(1.41{\sim}7.04cm/min)$에 따른 Dy와 Ho의 분리특성을 조사하였다. 용리액인 HCl의 농도는 $0.25{\sim}0.5mol/L$가 적절한 것으로 판단되며, HCl $0.5mol/L$ 이상에서는 분리효과가 거의 없었다. 일정한 용리액 농도에서 유속이 느릴수록, column의 온도가 높을수록 분리도와 해상도는 개선되었으며, 유속이 느릴수록 용리액의 소모량은 감소, 분리시간은 증가하였다. 적정조건인 용리온도 $60^{\circ}C$, 유속 7.04cm/min, HCl 0.25mol/L에서 분리도는 ${\alpha}_{Dy}^{Ho}=1.36$로 가장 높았다.

• The Journal of the Petrological Society of Korea
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• v.24 no.4
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• pp.365-371
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• 2015

The rare earth element(REE)s play an important role in understanding of rock formation and evolution because of their similar geochemical behaviors. Sm and Nd are more useful than other REEs because Sm-Nd isotopic system has important applications for geochemical interpretation like age dating and crustal evolution. These studies require a chromatographic technique for Sm and Nd separation from the geological samples. Ln-resin method using 0.25 M HCl as the eluent is widely used for Nd separation. However, this technique has a disadvantage of the poor elemental selectivity that the Nd fraction contains Ce as a tailing of the previous fraction. This technical report is a comparison study on the effect of eluent concentration between 0.25 M HCl and 0.15 M HCl on the separation of Nd with Ln-resin method for improving the technique of Nd separation. The results showed that the separation of Ce and Nd using 0.15M HCl as the eluent was not effective compared to the separation using 0.25 M HCl. In this experiment, we could confirm that the dilution of eluent might not be effective on the high purity separation of Nd with Ln-resin method.

• Resources Recycling
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• v.2 no.4
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• pp.27-32
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• 1993

A process has been studied to recover gallium from steelmaking dust which had several hundreds ppm of gallium. Aqueous solution containing 38 mg/l gallium was obtained by leaching of dust with 2.25 mol/l sulfuric acid. The leach liquor contained iron and zinc about 1,000 times greater than gallium. Gallium was then concentrated by ion exchanger of chelating resin with functional group of amino carboxylic acid after reduction of ferric ion to ferrous ion and pH adjustment. Gallium was concentrated to be 13 g/l in the resulting eluate by double ion exchanges. The liquor was further treated to remove impurities by solvent extraction technique empolying TOMAC as extractant. The galluim with 99% purity was finally obtainable.

• Journal of the Korean Chemical Society
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• v.24 no.6
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• pp.452-456
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• 1980

An anion exchange method for separating Y, La, Ce, Pr, and Nd element in monazites and into enriched fractions has been developed. The complexed rare earth ions with EDTA at pH 8.4 passed through the resin column of the various size and eluted with 0.0301 M EDTA as eluent at flow rate of 1 ml/min and 2 ml/min. The result of separation is good in the high column length rather than the low on using the resin of the same amount and the volume of eluent required in eluting all the rare earths at 2 ml/min flow rate is larger than that at 1 ml/min and the result of separation obtained here is unsatisfactory.

• Journal of the Korean Chemical Society
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• v.39 no.5
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• pp.379-383
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• 1995

The elution behaviors of stannous ion by PSA(phenol sulfonic acid) as an eluent on chelating resin, Amberlite IRC-718 have been investigated. When 0.10 M stannous solution was adsorbed on the resin and eluted with various concentrations of PSA, the two peaks of stannous ion were appeared in the elution curve. These two peak areas were changed according to the PSA concentration. Using these results, the stability constant of the complex formation between Sn2+ and PSA was calculated. This value is 2.0 ${\times}$ 10-1.

• Journal of the Korean Chemical Society
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• v.34 no.1
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• pp.44-50
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• 1990

The liquid chromatographic retention behavior of structural isomers of phenols was investigated by a change of the mobile phase properties. The retention behavior of structural isomer of phenols in reversed phase liquid chromatography was affected by eluent electrolyte added. It can be seen that this behavior is illustrated by a mechanism of Langmuir isotherm and ion exchange between phenolate and the reversed phase coated with ions. The retention behavior was represented as two different areas according to the concentration of the electrolytes. These areas can be explained as counter ion and co-ion effect, respectively. The maximum retention values were dependent not upon the kinds of organic modifier but upon the kinds of electrolyte.

• Resources Recycling
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• v.25 no.4
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• pp.60-67
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• 2016

This study was conducted to establish the adsorption-desorption mechanism and the optimum condition of chromatographic operation for separations of heavy rare earth elements (Gd, Tb, Dy) using a p507-containing resin. By employing Langmuir and Freundlich isotherm together with pseudo first and second order kinetics, absorption-desorption reaction mechanism was investigated. Langmuir and Freundlich isotherm was applied under assumption that adsorption reaction occurs in form of monolayer, and because the result was identical to the assumption, now we know adsorption of heavy rare earth elements occurs in form of monolayer. Concerning the pseudo first and second order kinetic, the pseudo second order seemed to be more suitable to represent heavy rare earth element adsorption mechanism. By using the extraction chromatography to separate heavy rare earth elements, ${\alpha}^{Tb}_{Gd}=1.24$, and ${\alpha}^{Dy}_{Tb}=1.03$ were confirmed in eluent HCl 0.25 M which indicates almost perfect separations of three elements. Furthermore, as concentrations of eluent became higher, the resolution value decreased and the elution area got shortened.

• Journal of the Korean Chemical Society
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• v.18 no.5
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• pp.358-362
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• 1974

The anion exchange separation of a number of benzoic acid and its derivatives has been studied in various concentrations of $NiCl_2-methanol$ solvent medium. The volume distribution coefficients with Amberlite CG-400, $Cl^-$form have been measured in these medium. Several synthetic mixtures of organic acids were separated quantitatively by elution with a suitable concentration of $NiCl_2-MeOH$ solution suggested by the distribution data. The concentration of organic acids were determined by UV spectrophotometry.

• Journal of the Korean Chemical Society
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• v.32 no.5
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• pp.452-457
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• 1988

Capacity factors (k') of some inorganic anions including $BF_4^{-1}$ were measured on cetylpyridinium coated column, and with dynamic system using tetrabutylammonium salicylate on PRP-1 reversed-phase column, respectively. After optimum separation condition was obtained this method was applied to the determination of boron in some different type samples.