• Title/Summary/Keyword: 완충 시간

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고급산화공정을 이용한 1,4-dioxane분해 연구

  • Park, Won-Seok;Park, Jin-Do;Lee, Hak-Seong
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2006.05a
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    • pp.365-369
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    • 2006
  • [ $O_3$ ]/catalyst를 이용한 고급산화공정에서 pH변화에 따른 1,4-dioxane의 화학적 분해 특성을 알아보기 위해 이 실험을 수행하였다. 초기 pH를 6, 8, 10으로 조절하여 변화를 보면 오존의 pH 완충효과에 의해 시간이 지남에 따라 알칼리와 산의 경우 중성 쪽으로 중화되는 것을 확인하였다. 그리고 시간에 따른 1,4-dioxane의 제거율은 pH 10 > pH 8 > pH 6 의 순서로 나타는 것을 보였다. 이는 오존이 산성에서는 안정하지만 알칼리성에서는 불안정함으로 인해 자기분해를 일으켜 OH라디칼의 생성을 촉진시켜 제거율이 높게 나타났다. 초기 pH를 조절한 실험, 초기 pH를 일정하게 유지한 실험에서의 50분 후의 최종 제거율은 비슷하였지만, 초기 pH를 일정하게 유지한 실험에서 제거율이 꾸준히 감소하는 것을 알 수 있었다.

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The Growth of Vibrio vulnificus in Meat Homogenates of Fish and Shellfish (어패육에서의 Vibrio vulnificus의 증식에 관한 연구)

  • KIM Young-Man;HUR Sung-Ho;CHANG Bong-Suck
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.21 no.2
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    • pp.80-84
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    • 1988
  • The change of cell counts of Vibrio vulnificus in meat homogenates of fish and shellfish by the storage time and temperature was examined to get basic information for precautionary steps against septicemia from slices of raw fish (sashimi). Therefore, we inoculated raw and cooked meat homogenates of fish and shellfish with Vibrio vulificus M-8 (isolated from shellfish ) and stored them at $-20^{\circ}C,\;4^{\circ}C\;and\;30^{\circ}C$ for 72 hours. Vibrio vulnificus M-8 was not detected in 32 hours when it was frozen and stored at $-20^{\circ}C$ after inoculating them into phosphate buffer solution at concentration of $10^5\;cell/ml$, while the existance of Vibrio vulnificus was identified after 72 hours of storage at the same temperature in case of inoculation into the meat homogenate of yellow tail. The cell count of Vibrio vulnificus was decreased as about $20\%$ of initial count after 2 hours storage at $4^{\circ}C$ in phosphate buffer solution with fish and shellfish homgenates. From the experimental results it was recognized that Vibrio vulnificus was labile to the cold stress. In comparison to the growth of growth of Vibrio M-8 at $30^{\circ}C$ in the raw and cooked meat of the yellow tail(Seriola guingueradita), snapper(Chrysophrys major), ark shell(Anadra brouhgtonii), and oyster(Crassostrea gigas), the raw meat homogenates were more excellent than the cooked ones though all fish and shellfish meat homogenates were proves to be good for the growth of the microbe.

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Effects of Fiber Sources on Ruminal pH, Buffering Capacity and Digestibility in Sheep (섬유소 공급원이 면양의 반추위 pH, Buffering Capacity 및 소화율에 미치는 영향)

  • Seo, In-Jun;Kim, Myeong-Hwa;Kim, Dong-Sik;Lee, Sang-Rak;Maeng, Won-Jai
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.25 no.3
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    • pp.177-184
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    • 2005
  • This study was conducted to study the effect of fiber sources on ruminal pH and buffering capacity and whole digestive tract digestibility with five ruminally fistulated sheep. Evaluated fiber sources were alfalfa hay cube (AHC), corn cob (CC), com silage (CS), cotton seed hull (CSH), peanut hull (PHL), rice straw (RS), and sugarcane bagasse (SCB). Sheep were fed consecutively a diet containing each tested fiber source $(45\%)$ with a corn-based concentrate diets $(55\%)$ during each experimental period. Ruminal pH showed no difference among fiber sources except the significantly lower pH at 8h (p<0.05) with RS (pH; 5.78) than those in other sources. Buffering capacity showed significant differences at 0h (p<0.05) and 2h (p<0.05) after feeding in CS compared to those from SCB and CC, while there was higher in PHL (p<0.01) at 12h post feeding except AHC than CC, CS, SCB, and RS. Dry matter digestibility was significantly higher in CS (p<0.001) than in other sources. Neutral detergent fiber digestibility was higher in CC, CS, CSH, and RS than other fiber sources (p<0.001). These results suggest that ruminal pH and buffering capacity and whole digestive track digestibility were significantly affected by fiber sources in ruminant diet, and, therefore, should be took those effects into account for TMR formulation.

Isolation of Epithelial Like Cells from the Rabbit Myometrium: the Distribution of Creatine Kinase and Plasminogen Activator (토끼 자궁근충에서 분리한 상피세포의 배양 분리 : 크레아틴 카이네이스와 플래스민 활성인자의 분포)

  • Lee, Chung-wha;Iyengar, M. Raja
    • Korean Journal of Veterinary Research
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    • v.24 no.2
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    • pp.137-147
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    • 1984
  • Cells with an epithelioid morphology were isolated from the rabbit myometrium and were grown in culture. The cells had a doubling time of 53 hours when grown in the presence of 10% fetal calf serum in Basal Eagle's medium with 3mM glutamine. In the presence of estrogen plus insulin, doubling time was reduced to 40 hours. Creatine kinase activity upon reaching confluency was determined to be 0.019 unit per mg protein. Approximately 30% of the activity was extractable only in high ionic strength buffer. Cells also contained plasminogen activator with a specific activity of 140 CTA units per million cells. Creatine kinase was mainly BB form. The cells contained a cross reactive protein against bovine smooth muscle uterine anti-myosin.

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Drug Release by Poly(DL-lactide) Coated Chitosan Derivatives Matrices (Poly(DL-lactide)로 피막된 키토산 유도체 매트릭스에서의 약물방출)

  • 차월석;나재운이동병
    • KSBB Journal
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    • v.10 no.4
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    • pp.461-467
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    • 1995
  • In this study, the release experiments of drug were operated in the phosphate buffer solutions of pH 7.4 and pH 1.2 by using drug carriers(chitosan, chitosan hydrochloride, and sulfonated chitosan)coated by poly(DL-lactide) with prednisolone for delivery drug. The release time of drug was more delayed in pH 7.4 than in pH 1.2. The release time of according to the kinds of drug carrier was delayed in the order of chitosan, sulfonated chitosan, and chitosan hydrochloride. In short, the formulation allows biodegradable coated monolithic polymetic matrices to suppress the burst effect of the drug release mechanism, which led to the sustained release pattern.

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전기화학증착 방법으로 성장시간에 따라 형성한 SnO2 나노세선의 구조적 성질

  • Lee, Chang-Hun;No, Yeong-Su;Lee, Dae-Uk;Kim, Tae-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.398-398
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    • 2012
  • SnO2 나노세선은 n-형 전기적 성질과 화학적인 안정성 때문에 가스센서, 투명 전극 및 태양전지와 같은 전자소자와 광소자에 널리 사용되고 있다. 화학 기상 증착, 전자빔 증착과 전기화학증착법을 사용하여 SnO2 나노세선을 제작하고 있다. 여러 가지 증착 방법중에서 전기화학증착방법은 낮은 온도와 진공 공정이 필요하지 않으며 대면적 공정이 가능하고 빠른 성장 속도로 나노구조를 효과적으로 성장할 수 있는 장점을 가지고 있다. 본 연구에서는 전기화학증착법을 이용하여 Indium Tin Oxide (ITO) 기판 위에 SnO2 나노세선 성장하고 성장시간에 따라 형성한 SnO2 나노세선의 구조적 성질을 조사하였다. SnO2 나노세선을 성장하기 위하여 D.I. water와 Entanol을 7:3의 비율로 섞은 용액을 $65^{\circ}C$로 유지하였고, 0.015 M의 Tin chloride pentahydrate ($Cl4{\cdot}Sn{\cdot}5H2O$)를 타겟 물질로 이용하였고, 0.1 M의 Potassium chloride (KCl)를 완충 물질로 사용하였다. 전기화학증착 방법을 사용하여 제작한 ITO 기판위에 성장한 SnO2 나노세선 위에 전극을 제작하고 전류-전압 특성을 측정하였다. SnO2 나노세선이 성장되는 전기화학증착 전압을 1.2 V로 고정하고, 성장시간을 15분, 30분 및 1시간으로 변화하여 SnO2 나노세선의 구조적 특성을 분석하였다. X-선회절 (X-ray diffraction; XRD) 실험 결과는 $31^{\circ}$에서 (101) 성장방향을 갖는 SnO2 나노세선이 성장함을 확인하였고, 성장 시간이 길어짐에 따라(101) 성장방향의 XRD 피크의 intensity가 증가하였다. 전기화학증착 성장 시간이 길어짐에 따라 SnO2 나노세선의 지름이 60 nm에서 150 nm로 변화하는 것을 주사전자현미경으로 관측하였다. 이 실험 결과는 전기화학증착방법을 사용하여 제작한 SnO2 나노세선의 성장 시간에 따른 구조적 특성들을 최적화하여 소자제작에 응용하는데 도움이 된다.

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Electrokinetic Remediation of Cobalt Contaminated Soil using Acetic Acid (초산을 이용한 동전기적 방법에 의한 코발트 오염토양 복원)

  • 김계남;김길정;손종식;배상민;오원진
    • Journal of Soil and Groundwater Environment
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    • v.6 no.1
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    • pp.13-21
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    • 2001
  • The characteristics of $Co^{2+}$ removal in the kaolinite column were analyzed by electrokinetic remediation. Ethanoic buffer was injected in the kaolinite column and $CH_3$COOH was continuously added to the cathode reservoir to restrain the pH increase. The pH of the cathode of the kaolinite column was 4.0 at first. Since it was controlled to be under 6.5 after 43.6 hours due to ethanoic buffer, precipitation of ${Co(OH)}_2$ was not formed in the column. Effluent rate increased with time and $Co^{2+}$ removal in the column at initial time was mainly controlled by ion migration. 13.1% of total $Co^{2+}$ in the column was removed after 10 hours, the 46.8% of total $Co^{2+}$ after 20.8 hours, and the 71.7% of total $Co^{2+}$ after 30.1 hours, the 94.6% of total $Co^{2+}$ after 43.6 hours, Meanwhile, the residual concentrations in the column calculated by the developed model were similar to experiment results.

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Influence of Hydrothermal Treatment of Wheat Bran on Phytate-P Content and Performance of Broiler Chickens (수침처리가 밀기울의 피틴태 인 함량과 육계의 생산성에 미치는 영향)

  • Kim, B. H.;Paik, I. K.
    • Journal of Animal Science and Technology
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    • v.45 no.2
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    • pp.229-240
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    • 2003
  • An in vitro test and a broiler feeding trial were conducted to test the effect of hydrothermal treatment of wheat bran on phytate-P degradation and it’s feeding effect on performance of broilers. Hydrothermal treatment of wheat bran was carried out at 55$^{\circ}C$ with pH 5.5 buffer solution. Phytate-P content of wheat bran decreased quadrically as the wheat bran: buffer solution ratio increased from 1:0.5 to 1:5. Phytate-P degradation was not significantly affected by incubation times above 10 min., drying temperature (55$^{\circ}C$, 65$^{\circ}C$ and 75$^{\circ}C$) or pH of the buffer solution (5.5 and 7.0). A feeding trial was conducted with 240 sex separated d-old broiler chickens (Ross$^{\circledR}$). Broilers were randomly housed to 24 cages of 10 birds each. Six cages (3 of each sex) were assigned to 4 treatments: Control-normal level of non-phytate-P (NPP); LP-low NPP treatment which had 0.1% lower NPP than Control; LPWB-LP with wheat bran which provided 475 IU of plant phytase per kg diet; LPHWB-LP with hydrothermally treated wheat bran. Results of the feeding trial showed that broilers in the LP treatment gained significantly less than other treatments in starter period (1-21d) but only male broilers for growing LP gained significantly less than Control in the grower (22-35d) and overall period. There were no significant differences in weight gain among the birds of LPWB, LPHWB and Control. Feed intake during the overall period was not significantly different between LPWB and Control but that of LP was lower than LPHWB and that of LPHWB was lower than Control. Feed/gain ratio was significantly lower in LPHWB and LP than in Control and LPWP. Mortality was highest in LPHWB. Availability of crude fat, crude ash and Ca was significantly lower in LP than other treatments. Availability of P and Zn was higher in LPWB and LPHWB than in Control and LP. Availability of P, Mg and Zn was highest in LPHWP treatment. Excretion of P was significantly lower in low NPP treatments than in Control. Serum Ca level was highest whereas serum P level was lowest in LP. Tibial crude ash content was higher in wheat bran treatments, but lower in LP than Control. However, tibial Ca content was higher in Control and LP than wheat bran treatments. Tibial P content of LP and LPWB was lower than Control. However, tibial content of Fe was highest in LP. It was concluded that wheat bran, a source of plant phytase, could be used in low NPP broiler diets to prevent the depression of performance. Reduction of P excretion can be achieved concomitantly. Hydrothermal treatment of wheat bran was effective in improving utilizability of some minerals but was not effective in improving performance of broilers.

An Analysis of the Water Saturation Processes in the Engineered Barrier of a High Level Radioactive Waste Disposal System (고준위폐기물처분시스템 공학적 방벽에서의 지하수 포화공정 해석)

  • Park, Jeong-Hwa;Lee, Jae-Owan;Kwon, Sang-Ki
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.9 no.1
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    • pp.23-32
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    • 2011
  • An engineering scale test, which is called KENTEX, was carried out to understand and to analyze the coupled thermal, hydrological and mechanical phenomena in the engineered barrier system(EBS) of Korean reference disposal system. Using the experimental data obtained from KENTEX, the water saturation processes in bentonite could be analyzed. From the comparison between the model calculation using ABAQUS and the experimental results, the difference of the water content between them in the unsaturating part was large because the drying phenomena due to moisture redistribution by the temperature gradient could not be included in the model. In the saturating part, the difference of the water content between them was decreased gradually and showed to be small in the full saturation. And the time of about 95% saturation could be estimated about 500 days from the model calculation and experimental results. Also it could be known that the moisture redistribution in the unsaturated part could not be affected on the saturation time of bentonite in the repository. Therefore, it is considered that this model could be used to quantitatively predict the water saturation time in bentonite as EBS for the disposal system.

Comparison of Caries Activity of Some Children's Beverages Inoculated with Streptococcus mutans (Streptococcus mutans를 접종한 일부 어린이 음료의 우식활성능 비교)

  • Young-Nam PARK
    • Korean Journal of Clinical Laboratory Science
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    • v.55 no.3
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    • pp.195-202
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    • 2023
  • The caries activities of some commercially available children's beverages were measured to determine the risk of dental caries and provide basic data for preventing dental caries. For the experimental beverage, the beverages with the highest market share among carbonated beverages, fruit beverages, milk, and fermented milk products sold in the domestic market were selected. As a control, 0.25% glucose trypticase soy broth was prepared and used. The pH of the beverages, titrate acid and buffering capacity, and the acid production and vitality were measured over time after inoculating the beverages with Streptococcus mutans. The pH of children's beverages was the lowest in soda (2.61±0.02), and milk had the lowest in titratable acid (14.00±0.58). Fermented milk (80.33±3.64) had the highest buffering capacity, and carbonated beverage (9.40±1.06) had the lowest (P<0.05). Carbonated beverages (3 hr and 25 min) had the highest acid production, and milk (4 hr) had the lowest. In conclusion, thorough oral hygiene management is necessary after consuming children's beverages because they have a low pH promote high acid production of S. mutans.