• Title/Summary/Keyword: 옥소(玉所)

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A Kinetic Study of the Substitution of $\beta$-Disketone in Bis($\beta$-diketonato)Oxovanadium (IV) ((베타-디케토네이토) 옥소바나듐 (IV) 착물에서의 베타-디케톤 치환반응에 관한 속도론적 연구)

  • Hwang, Gyu Tak;Kim, Jeong Seong;Sin, Han Cheol;Kim, In Hwan;Kim, Gi Tae
    • Journal of the Korean Chemical Society
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    • v.34 no.4
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    • pp.319-324
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    • 1990
  • Kinetic of substitution of dibenzoylmethanate (dbm) for one acetylacetonate (acac) in VO (acac)$_2$ have been studied in various solvents by spectrophotometry. Under the condition [VO (acac)$_2$] 》[Hdbm], the rate law for the substitution reaction is expressed as, rate = k$_2$K[VO(acac)$_2$] [Hdbm] / (1 + K[VO(acac)$_2$]) where K = [VO (acac)$_2$dbmH] / [VO(acac)$_2$][Hdbm] and the rate constant k$_2$ corresponds to that of proton transfer from coordinated Hdbm to leaving acac- in VO(acac)$_2$dbmH.

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Study on production of visionary drawings with 『Oksogo(玉所稿)』 (『옥소고(玉所稿)』 소재(所載) 몽화(夢畵)의 제작(製作)에 대한 연구(硏究))

  • Choi, Ho-suk
    • Journal of Korean Historical Folklife
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    • no.28
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    • pp.113-142
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    • 2008
  • The purpose of this script is to understand general issues related to production of visionary drawing and correct the fault of previous research by examining the data on visionary drawing featured on Ok So Kwon-Seop's anthology, "Oksogo(玉所稿)" the summary of its contents are as follows. First by analyzing the status of visionary drawings, in among "Oksogo(玉所稿)" which is Ok So's manuscript collection, there are 56 pieces in Je Chun Bon (edition) and 47 in Moon Kyoung Bon(edition). And recorded dreams in visionary drawings are centralized when Ok So was in his late 50's to 70's. And it is estimated that the visionary drawings are the collection of work done by many artists in long period of time. It was confirmed that Kwon Seop himself did not participated in drawings but were done by his brother Kwon Young, his grandson Kwon Shin Eung and Cho Se Gul, the artist from Pyoung Yang. Also visionary drawings were produced in youth years and among the visionary drawings that can be ascertain about the produced year and the oldest is by Cho Se Gul which was estimated to be done in 1695. And the last one to be completed was which was a dream in 1756 turned into a drawing and this was produced between 1756 to 1759 which was a year Ok So passed away. Production of Ki Seung Chup (album) or Mong-Wha Chup (album) was accomplished as follows. When Ok So records his dream in writing he receives response poem from a person he was in dream with and ask artist to draw the vision in dream, then the drawing and scripts were compiled and made into an album. With this some of the issues on visionary drawings featured on "Oksogo(玉所稿)" would have been settled. Recently, 2 more volumes of Ok So's anthology were photo-printed and published and hopefully those issues that was unable to settle in this script will have more detailed answers by discovering new and undisclosed data.

Observation on The Frequency of Chromosomal Aberration and Changes in Number of Peripheral Lymphocytes in Radioactive Iodine Treatment (방사성옥소 투여에 따른 말초혈액 림프구 수의 변화 및 염색체이상 빈도의 관찰)

  • Koo, Chun-Hee;Shin, Min-Ho;Park, Young-Ju;Lee, Jung-Yim;Park, Tae-Yong;Lee, Jae-Yong;Kim, Chong-Soon;Han, Seung-Soo;Kim, Kwang-Hoe;Kim, Hee-Geun;Kang, Duck-Won;Song, Myung-Jae
    • The Korean Journal of Nuclear Medicine
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    • v.29 no.3
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    • pp.343-349
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    • 1995
  • Background : For biological dosimetry of radiation exposure, both observing hematologic change and calculating Ydr by chromosomal analysis as biological indicators are widely used. However, due to the lack of studies on biological dosimetry of radiation dose absorbed in the body such as in the cases of radioactive iodine therapy, the maximal and safe dose is not well known, nor is the extent to which the body can safely endure radiation exposure. Purpose : To investegate the practical applicability of hematologic changes and Ydr as an indicator for estimating radiation exposure, to patients with thyroid diseases after doses of radioactive iodine. Material and Methods : 5 patients with hyperthyroidism and 35 patients who have had thyroid cancer operation were under treatment with radioactive iodine, changes in number of lymphocytes were tracked and Ydr was calculated for more than 2 months by chromosomal analysis in peripheral lymphocytes. Results ; 1) The number of lymphocytes began to decrease 2 weeks after doses of radioactive iodine, and reached the nadir after 6 and 8 weeks, then gradually recovered. 2) The nadir count of lymphocytes was reversely correlated with the administered dosage of radioactive iodine. 3) Ydr was generally stable between 2 and 8 weeks. 4) The maximal value of Ydr was correlated with the administered dosage of radioactive iodine. 5) Ydr value at the 2nd week increased with augmented dosage of radioactive iodine. 6) Ydr value at the 2nd week was correlated with fall of lymphocyte count. Conclusion : Patients must be closely observed, because temporary bone marrow suppression and slight chromosomal aberration can be produced by even generally used dosages of radioactive iodine for diagnosis and therapy. Maximal percent fall of lymphocyte count, Ydr at the 2 week interval and maximal Ydr can be used as the biological predictor of administered dosage of radioactive iodine.

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Analysis of Amoxicillin, Ampicillin, Oxolinic Acid, and Flumequin in Foods (식품 중 아목시실린, 암피실린, 옥소린산 및 플루메퀸의 분석)

  • Kim, Hee-Yun;Choi, Hee-Ju;Kim, Yong-Hoon;Choi, Sun-Hee;Cheong, So-Young;Lee, Hwa-Jeong;Kim, Jae-In;Choi, Gye-Sun;Choi, Jae-Chun
    • Korean Journal of Food Science and Technology
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    • v.41 no.5
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    • pp.490-497
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    • 2009
  • The present study was performed to validate an analytical method for veterinary drugs, including amoxicillin, ampicillin, oxolinic acid and flumequin, in meat, fish, and their products as established in the 2007 Korea Food Code, and to monitor the respective drugs in 6 kinds of foods, namely beef, pork, flatfish, rockfish, freshwater eel and shrimp. Additionally, an HPLC-ESI-MS/MS method was developed for the qualification of these veterinary drugs. As a result of monitoring, these drugs were detected in 14 (3.6%) out of 393 samples. In particular, amoxicillin was detected in 9 flatfish samples, and oxolinic acid and flumequin were detected in 4 samples and 1 sample of freshwater eel, respectively. The detection levels of amoxicillin ranged from 0.009 to 0.078 mg/kg, in which 1 sample of flatfish contained more than the MRL (0.05 mg/kg). Flumequin detected in 1 sample of freshwater eel, was less than the MRL (0.5 mg/kg). Therefore, the majority of detected levels were less than the MRLs, with the exception of 2 samples showing amounts that were 1-2 times higher than the MRLs. The detected veterinary drugs were identified and confirmed by the HPLC-ESI-MS/MS method created in this study.

Effect of Iodine-131 Administration on the Liver of Guinea Pig (방사성 옥소(131I)가 Guinea Pig의 간장에 미치는 영향)

  • Lee, Heung Shik;Lee, Kang Wook
    • Korean Journal of Veterinary Research
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    • v.12 no.1
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    • pp.15-19
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    • 1972
  • This experiment was carried out to investigate the effect on the liver of guinea pig after administration of 4.5mCi per Kg. body wt. with iodine-131. The histological changes in the liver were degeneration of hepatic cells, congestion of sinusoids, dilatation of bile ducts, perivascular infiltration of lymphocytes, and dissociation of hepatic cords. A marked histological changes were produced after treatment for 14 days and the morphological recoveries were observed 28 days after the treatment.

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Rates and Mechanism of the Reaction of Aquaoxomolybdenum(IV) Trimer with Thiocyanate (아쿠아옥소몰리브덴(IV) 삼합체 착물과 티오시안산이온과의 반응에 대한 속도와 메카니즘)

  • Chang-Su Kim;Joong-Ho Lee
    • Journal of the Korean Chemical Society
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    • v.31 no.6
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    • pp.527-533
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    • 1987
  • Kinetic studies on the complexing of aquamolybdenum(Ⅳ) trimer with thiocyanate have been carried out using the spectrophotometric method. The observed rate constant, $k_{obsd}$ is given by $k_{obsd}\;=\;{k_O + k_H[H^+]^2}(SCN^-) + k_r$. At 25$^{\circ}$C and ionic strength of 2.30 the values of $k_f$ and $k_r$ are $(3.78 {\pm} 0.61) {\times} 10^{-4}M^{-1}s^{-1}$ and $(6.93 {\pm} 2.39) {\times} 10^{-4}s^{-1}$, respectively. Activation parameters are ${\Delta}H^* = 50.71{\pm}6.91 kJmol^{-1}$ and ${\Delta}S^* = -121.65JK^{-1}mol^{-1}$. The mechanism is proposed and discussed.

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Contact Microscopy by Using Soft X-ray Radiation from Iodine Laser Produced Plasma (옥소레이저 플라즈마에서 발생된 연 X-선을 이용한 밀착현미경기술)

  • 최병일;김동환;공홍진;이상수
    • Korean Journal of Optics and Photonics
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    • v.1 no.1
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    • pp.46-51
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    • 1990
  • Laser plasma was generated by a 1GW iodine photodissociation laser ($\lambda$=1.315$\mu\textrm{m}$, E=12.7J) whose output beam was focused on a molybdenum target surface. The experiment was conducted in a vacuum chamber under 1D-sTorr and several tens of laser shooting were necessary for sufficient exposure for the PBS resist of 111m thickness. Aluminium was coated on the top of the resist by 0.1$\mu\textrm{m}$ thickness which acts as an X-ray filter to cut off the visible and the ultraviolet lights. A bio-specimen was put directly on the aluminium coated resist and located at a distance of 3 cm from the X-ray source. The replicas of a steel mesh, spider's web. and a red blood cell were obtained by this technique and were observed by Nomarski microscope and SEM. The limitation of its resolution is determined by the X-ray source size and Fresnel diffraction effect, and its theoretical prediction is well matched with the experimental results. In this experiment, a resolution better than 0.1$\mu\textrm{m}$ could be obtained. ained.

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Comparison of Thallium-201, Tc-99m MIBI and I-131 Scan in the Follow-up Assessment after I-131 Ablative Therapy in Differentiated Thyroid Cancer (방사성 옥소 치료 후 분화된 갑상선암 추적관찰에서 Thallium-201 스캔, Tc-99m MIBI 스캔과 I-131 스캔 검사 결과의 비교)

  • Kwon, Jae-Sung;Lee, Sung-Keun;Kim, Doe-Min;Park, Sae-Jong;Jang, Kyong-Sun;Kim, Eun-Sil;Kim, Chong-Soon
    • The Korean Journal of Nuclear Medicine
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    • v.33 no.6
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    • pp.493-501
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    • 1999
  • Purpose: We conducted a comparative study to evaluate the diagnostic values of T1-201, Tc-99m MIBI and I-131 scans in the follow-up assessment after ablative I-131 therapy in differentiated thyroid cancer. Materials and Methods: The study population consisted of 20 patients who underwent surgical removal of thyroid cancer and ablative radioactive iodine therapy, and followed by one or mote times of I-131 retreatments (33 cases). In all patients, T1-201, Tc-99m MIBI, diagnostic and therapeutic I-131 scans were performed and the results were analyzed retrospectively. Also serum thyroglobulin levels were measured in all patients. The final diagnosis of recurrent or metastatic thyroid cancer was determined by clinical, biochemical, radiologic and/or biopsy findings. Results: Positive rates (PR) of Tc-99m MIBI, T1-201, diagnostic and therapeutic I-131 scans in detecting malignant thyroid tissue lesions were 70% (19/27), 54% (15/28), 35% (17/48) and 63% (30/48), respectively. The PR in the group of 20 cases (28 lesions) who underwent concomitant T1-201 and I-131 scans were in the order of therapeutic 131 scan 71%, T1-201 scan 54% and diagnostic I-131 scan 36%. There was no statistically significant difference between T1-201 and diagnostic I-131 scans (p>0.05). In the group of 20 cases (27 lesions) who underwent concomitant Tc-99m MIBI and I-131 scans, the PR were in the order of Tc-99m MIBI scan 70%, I-131 therapeutic scan 52% and I-131 diagnostic scan 33%. The PR of Tc-99m MIBI was significantly higher than that of diagnostic I-131 scan (p<0.05). Conclusion: Tc-99m MIBI scan is superior to diagnostic I-131 scan in detecting recurrent or metastatic thyroid cancer following ablation therapy in patients with differentiated thyroid cancer. T1-201 scan did not showed significantly higher positive rate than diagnostic I-131 scan. Instead of diagnostic I-131 scan before the I-131 retreatment, Tc-99m MIBI scan without discontinuing thyroid hormone replacement would be a prudent and effective approach in the management of these patients.

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Contact Microscopy by Using Soft X-ray Radiation from Iodine Laser Produced Plasma (옥소 레이저 플라즈마에서 발생된 연 X-선을 이용한 밀착 현미경 기술)

  • 최병일
    • Proceedings of the Optical Society of Korea Conference
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    • 1990.02a
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    • pp.49-53
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    • 1990
  • Laser plasma was generated by a 1 GW iodine photodissociation laser(λ=1.315${\mu}{\textrm}{m}$, E-12.7J) whose output beam was focused on a molybdenum target surface. The experiment was conducted in the vacuum chamber under 10-5Torr and several tens of laser shooting were necessary for sufficient exposure to the PBS resist. A speciman was put directly on the resist and located at a distance of 3cm from the X-ray source. The replicas of a mesh, spider's tread, a red blood cell were obtained by PBS resist and were analyzed by Nomarski and SEM. Two main effects of limitation in resolution, source size and Fresnel diffraction, are mentioned and compared with the experimental result. In this experiment, a resolution better than 1000A could be obtained.

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