• Title/Summary/Keyword: 오염지하수

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Application of a Pilot-Scale Electrodialysis System for Groundwater Polluted with Arsenic and Manganese (파일롯 규모 전기투석 막여과 시스템을 이용한 비소와 망간오염 지하수 처리)

  • Choi, Su Young;Kwon, Min Wook;Park, Ki Young;Cha, Ho Young;Kim, Hee Jun;Kweon, Ji Hyang
    • Journal of Korean Society on Water Environment
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    • v.33 no.3
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    • pp.334-340
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    • 2017
  • A pilot-scale electrodialysis system was designed and constructed to treat groundwater polluted with arsenic and manganese. Synthetic groundwater, in which some amount of arsenic and manganese was added to make 500 mg/L of Mn and $50{\mu}g/L$ of As, was used as a feed for the ED system. The limiting current density, linear water velocity, applied voltage, and membrane surface area were investigated to obtain efficient and economic operation of the ED system. The linear water velocity was increased 0.74 cm/s to 11 cm/s based on evaluation of limiting current density. The water quality of diluate for 85 minutes of operation was satisfied with water quality criteria for drinking water using the ED system with 14 pairs of ion exchange membranes. The increased membrane pairs to 21 and 42 pairs were very effective to reduce conductivities of the diluate. The operation cost of the ED system was assessed using specific energy consumption, which was $1.065{\sim}1.2kWh/m^3$. Considering low salt concentrations of the groundwater, improvement of the ED system are required to increase current utilization and to apply low voltage while the ED system was applicable to produce drinking water.

Interaction between Selenium and Bacterium and Mineralogical Characteristics of Biotreated Selenium (셀레늄-미생물간의 반응 및 셀레늄 광물화 특성)

  • Lee, Seung-Yeop;Oh, Jong-Min;Baik, Min-Hoon
    • Journal of the Mineralogical Society of Korea
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    • v.24 no.3
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    • pp.217-224
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    • 2011
  • Removal of dissolved selenium by D. michiganensis, a iron-reducing bacterium, and effects of dissolved metal elements such as iron, sulfate, and copper were investigated. Selenide that was reduced from selenite (2 mM) by D. michiganensis was gradually removed from the aqueous medium. As the reduced selenide was combined with aqueous iron, it was precipitated as a nanoparticulate iron-selenide. Sulfate and copper negatively affected the microbial selenite reduction, and the copper was especially toxic to the bacterium, inhibiting a microbial removal of dissolved selenite. These results show that it should be carefully biotreated for a selenium-contaminated site considering in situ sulfate or copper distribution and concentration. Consequently, the formation of iron-selenide by bacteria will be an important measure for preventing a long-distance migration of selenium in the subsurface environments.

Analysis of Oil Species of Illegally Disposed Oil (무단 투기 유류에 대한 유종 해석)

  • Lim, Young-Kwan;Lee, Eun-Yul;Seong, Sang-Rae;Kim, Jong-Ryeol
    • Applied Chemistry for Engineering
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    • v.27 no.6
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    • pp.664-668
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    • 2016
  • The contamination in soil, underground water and river environment became serious due to illegal waste dumping. In this study, our research group analyzed the oil species of illegally disposed oils from J City. After pretreating the mixture of oil, water and solid phases to obtain homogeneous phase components, the physical property analysis, atom analysis, and gas chromatography were performed. From the results showing 11.8% of oxygen content, $-6^{\circ}C$ of pour point and chromatogram pattern. the contaminated oil was identified as a vegetable one. High performance liquid chromatography (HPLC) analysis was also performed in order to know what kind of vegetable oil was, and the ratio of LLO, OOL and POL was found to be high indicating that the disposed oil is majorly the used soybean oil with some vegetable oil mixtures. This study can be used for identifying contaminators for oils from the illegal waste dumping.

Studies on the Sorption and Fixation of Cesium by Vermiculite (II)

  • Lee, Sang-Hoon
    • Nuclear Engineering and Technology
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    • v.6 no.2
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    • pp.97-111
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    • 1974
  • The adsorption mechanism of Cs-137 in low level radioactive solution by vermiculite treated with Na ion is studied in order to investigate its effective utilization for the radioactive effluent treatment. The beneficial role of Na-vermiculite is that Na ion can induce the wider c-axis spacing in which Cs ion can be sorbed in vermiculite. Cation exchange capacity and distribution coefficient of cesium seems to be influenced by the variation of c-axis spacing of vermiculite. Comparative identification and detection with the characteristic analyses of X-ray diffraction and electron diffraction patterns, diffrential thermal analysis and electron microscopy of Na-, K- and Cs-vermiculite are studied for the phemomena of Cs adsorption by vermiculite. This importance of the utilization in terms of adsorption and fixation of cesium involving vermiculite is discussed. It is found that the Na-vermiculite is valuable outside charging material for high level radioactive liquid waste storage tank of underground to protect the pollution of the underground water.

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Reductive Degradation Kinetics and Pathways of Chlorophenolic Organic Pollutants by Nickel-Coated Zero Valent Iron (니켈로 코팅된 영가금속을 이용한 염소계 페놀화합물의 반응경로 및 반응율 평가)

  • Shin, Seung-Chul;Kim, Young-Hun;Ko, Seok-Oh
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.5
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    • pp.487-493
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    • 2006
  • Reductive dechlorination of chlorophenols by nickel coated iron was investigated to understand the feasibility of using Ni/Fe for the in situ remediation of contaminated groundwater. Zero Valent Iron(ZVI) was amended with Ni(II) ions to form bimetal(Ni/Fe). Dechlorination of five chlorophenol compounds and formation of intermediates were examined using Ni/Fe. Rate constant for each reaction pathway was quantified by the numerical integration of a series of differential rate equation. Experimental results showed that the sequence of hydrodechlorination rate constant was in the order of 2-CP>4-CP>2,4-DCP>2,4,6-TCP>2,6-DCP. The hydrodechlorination pathways for the conversion of each chlorophenol compound involves a full dechlorination to phenol via both concerted and stepwise mechanisms. Reaction pathways and corresponding kinetic rate constants were suggested based on the experiments and numerical simulations.

Valuing the restoration of the Abandoned Roads (폐도로 복원의 경제적 가치 추정)

  • Park, Sang-Soo;Jeon, Giseong;Lee, Chung-Ki
    • Journal of Environmental Policy
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    • v.13 no.3
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    • pp.21-42
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    • 2014
  • Abandoned roads, abandoned expressways included, cause a lot of problems such as contamination and environmental damages to underground water, fragmentation of wildlife habitats yet they are not appropriately maintained or managed because of jurisdictional conflicts and, often more importantly, insufficient budget of governments. The restoration of abandoned roads is known to benefit society and its constituents by providing better environment and higher living standards but the monetary value of the benefit is hard to measure because of non-marketability of the good that the restoration brings about. In this case, the contingent valuation method(CVM) is most powerful in evaluating non-marketable value of goods and hence it is used widely. We also used the CVM to value the benefit of restoration of abandoned expressways to find out: about 40% of total households are willing to contribute positive amount for restoration; better awareness of environmental issues leads to higher willingness-to-pay.

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Effects of Paper Mill Sludge in submerged Soil (제지(製紙)슬러지의 답토양(畓土壤) 시용효과(施用效果))

  • Choi, Jong Woo;Jo, Jeong Rye;Lee, Kyu Seung;Kim, Moon Kyu
    • Korean Journal of Agricultural Science
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    • v.19 no.2
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    • pp.187-193
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    • 1992
  • The effects of continuous restoration of sludge into the reclamating paddy soil and leaching test of sludge components by soil column were investigated. 1. The contents of nitrogen, phosphorus, potassium, C.E.C. and organic matter(O.M.) were increased in/on the paddy soil treated with paper mill sludge than non-treated. 2. Humic layer depth recognized by color showed the non-treated(10 cm), second year(15 cm) and third year(20 cm), respectively. 3. The effects of sludge treatment showed in the contents of O.M. such as non-treatment(0.9 %) < second year(1.39 %) < third year(1.75 %) in 10 cm depth. 4. All components in soil tested with column were increased by holding capacity of sludge, and the contamination effects of soil and ground water were not found by leaching test.

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The State-of-the-Art of Geophysical Exploration Technology applied to Site Characterization in Civil Engineering and Construction in Japan (일본에서의 토목${\cdot}$건설 지반조사를 위한 물리탐사 활용 현황)

  • Park, Sam-Gyu;Kim, Hee-Joon
    • 한국지구물리탐사학회:학술대회논문집
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    • 1999.08a
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    • pp.1-20
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    • 1999
  • In Japan, geophysical exploration methods have been widely applied to civil engineering and construction fields for a long time. In particular, seismic refraction has long played a significant role in geotechnical site investigations for tunnels, dams and landslides. However, our growing interest on the social and natural environment makes the methods available and its application fields diversify. Digital technologies such as personal computer have revolutionized our ability to acquire large volumes of data rapidly, and to produce more reliable results for subsurface image. Also, color graphics easily visualizes survey results In a more understandable manner, These days geophysical methods are essential to assessing grouting effects, predicting the front of tunnel cutting face, monitoring the movement, pollution and purification process of groundwater. Now three-dimensional exploration techniques have developed for the site characterization in civil engineering and construction needs.

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A Study on the Concrete Compressive Strength Characteristics mixing Stone Dust Produced by Stone Block Manufacturing (석재(石材) 가공(加工)시 발생한 석분(石粉)이 혼합된 콘크리트의 압축강도(壓縮强度) 특성(特性)에 관한 연구)

  • Chae, Young-Suk;Min, In-Ki;Song, Gab-Young
    • Resources Recycling
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    • v.18 no.6
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    • pp.46-53
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    • 2009
  • The stone dusts produced during the manufacturing process of stone blocks are considered as one of industrial waste materials. This stone dusts are managed to either burying under the ground or stacking in the yard, but this disposal process is required an extra costs. The stone dust disposal like burying or stacking also cause environmental pollution such as ground pollution and subterranean water pollution. Thus, this study was conducted to explore the possibility of recycling stone dusts as a concrete mixing material in order to extend recycling methods. Based on the experiment results on various ratios of cement to stone dust content, the compressive strengths of concrete were recorded in the range of $20{\sim}30\;N/mm^2$. The results did not show any decrease in compressive strength due to the stone dust content. It can be concluded that the stone dusts produced by stone block manufacturing can be sufficiently recycled as one of concrete mixing materials in the aspect of compressive strength.

A Numerical Study on Safety Evaluation of Prefabricated Sewage-Pipe Plastic Foundation Based on Pipe Diameters and Buried Soil Depths (하수관거 직경과 심도를 고려한 하수관거 플라스틱 받침기초의 안전성 평가를 위한 해석연구)

  • Park, Rae-Jin;Park, Jong-Sup
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.6
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    • pp.4322-4327
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    • 2015
  • Improper backfill materials and compaction controls under pipelines have become one of the major causes of failure in many sewage pipeline systems. A study on backfill materials and compaction controls has been considered for a long time. However, structural supporters under the pipe were recently concerned because of pipeline repair and maintenance. This paper presents a prefabricated plastic foundation for supporting a sewage pipe system and increasing the performance function of the pipes. Several analytical models for the plastic foundations were investigated using finite-element program, ABAQUS, for checking safety. Comparing with the results of analyses, some of economic design sections based on the sizes of pipe diameters, 600mm, 700 and 600mm, were evaluated. These results could be applied to a pipeline system with a prefabricated plastic foundation with respect to pipe diameters and buried depths.