• Journal of the Korea Organic Resources Recycling Association
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• v.17 no.1
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• pp.88-95
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• 2009

This study is for understanding the domestic possibilities of the high temperature incineration of waste containing Polychlorinated Biphenyls (PCBs) with the analysis of normal operation case and waste gas, fly ash, dioxin about bottom ash, Total-PCBs, Co-PCBs, and the for analysis the heavy metal leaching feature included by bottom ash and fly ash, heavy metal leaching experiment was implemented. The result shows the dioxin density of the waste gas from waste containing PCBs was $0.00699{\sim}0.00763ng-TEQ/Nm^3$, which is lower than $0.0192ng-TEQ/Nm^3$ from the normal operation case. And each Co-PCBs and total PCBs shows $0.00043{\sim}0.00112ng-TEQ/Nm^3$ and $3.06{\sim}3.87ng/m^3$ respectively. The bottom ash test result shows Dioxin 0.00225~0.00630ng-TEQ/g, Co-PCBs 0.00027~0.00082ng-TEQ/g, Total PCBs 0.9~2.6ng/g, and the fly ash shows Dioxin 0.00164~0.00344ng-TEQ/g, Co-PCBs 0.00053~0.00054ng-EQ/g, Total PCBs 0.64~0.84ng/g. The bottom ash and fly ash experiments for heavy metal leaching did not show any leaching but when it comes to the ingredients of the fly ash, Pb elements shows 31.01~237.7ppm, higher than leaching criterion. The analysis of the density of all air pollution material from the waste gas shows the lower value than permissible criterion.

• Atmosphere
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• v.34 no.3
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• pp.283-304
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• 2024

This study analyzed the variability and correlation between ground-level air pollutant concentrations and the atmospheric mixing layer height using data from four types of air pollutants (PM_2.5, PM₁₀, NO₂, and O₃) collected at AirKorea monitoring stations nationwide over a five-year period (2018~2022), and aerosol backscatter data observed by the Vaisala CL31 to derive atmospheric mixing layer heights. The five-year trends and variability of ground-level air pollutant concentrations under seasonal and hourly conditions were examined, as well as the seasonal distribution and diurnal variation of the atmospheric mixing layer height. Five correlation coefficient methodologies were applied to analyze the correlations between ground-level air pollutants and atmospheric mixing layer height under various seasonal and hourly conditions, confirming the dilution effect of the atmospheric mixing layer height. The results showed that PM_2.5, PM₁₀, and NO₂ generally had negative correlations with the atmospheric mixing layer height, while O₃ showed a strong positive correlation up to an altitude of 1,200~1,500 meters, and a negative correlation beyond that altitude. It was also shown that a single high concentration event (e.g., PM₁₀) can alter the overall correlation. The correlation can also vary depending on the characteristics of the correlation coefficient methodology, highlighting the importance of applying the appropriate methodology for each case during the analysis process.

• Korean Chemical Engineering Research
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• v.62 no.4
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• pp.344-354
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• 2024

Silica nanoparticles were synthesized by precipitation method using a Taylor vortex reactor from sulfuric acid and water glass as precursor materials. The effects of factors controlling the average particle size of the nanopowders, such as stirring speed and concentration of water glass, were derived from the experimental data, and the differences in average particle size and standard deviation were compared with those of a conventional reactor. It was found that the Taylor vortex reactor can be used to synthesize silica powder with a relatively uniform particle size. Utilizing MTCS, a silane coupling agent, the silica particles were modified to be hydrophobic by replacing the hydroxyl groups on the silica surface with methyl groups, and the surface modification conditions affecting the amount of oil absorption per unit mass of the hydrophobic powder were derived. Particles absorbing 3.14 times more oil per gram of silica powder were prepared, and are expected to be useful in the removal of contaminants.

• Journal of the Korean Institute of Traditional Landscape Architecture
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• v.42 no.2
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• pp.47-55
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• 2024

As climate change issues intensify, the importance of green spaces, a Nature-based Solution (NbS), is being emphasized for urban climate change adaptation. This study analyzes the carbon neutrality effects of the historical landscape forests of Seolleung and Jeongneung, large green spaces in urban areas, using the i-Tree Eco simulation. By doing so, the study underscores the significance of maintenance and management from a climate change adaptation perspective. For the simulation analysis, an inventory was established based on field-measured tree monitoring data of 10,643 trees within the study area, linked with climate data from nearby weather observation stations. The analysis results showed that the trees within the study area annually reduced air pollutants by 5,400 kg, stored 1,260 tons of carbon, and sequestered 98.23 tons of carbon. Additionally, since the study area primarily consists of forest species, it was found that it can secure relatively higher biomass accumulation compared to trees applied to street trees and park green spaces. This emphasizes the need for maintenance and management of historical landscape forests as urban resources that can contribute to national carbon neutrality due to their high forest structure integrity, in addition to their heritage preservation value.

• Journal of the Korean Association of Geographic Information Studies
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• v.8 no.3
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• pp.74-83
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• 2005

The Riparian Buffer Zone has many potential values including the preservation of water quality as well as being ecologically friendly. This study aims to quantitatively analyze the landscape structure index of the Riparian Buffer Zone in the Kyoung-an stream and to produce base information necessary for proper management. The study used aerial images that were applied to geometric corrections for a time series from 1966 to 2000 for land data and also used FRAGSTATS, which is a type of ARCVIEW extension module, as an analysis tool. An analysis of land use change and the Landscape Index revealed that the area of farm land has decreased and that the area of residential property has increased. In addition, there was a slight change for land used for purposes other than farming or for residence. The results of analyzing the Landscape Structure Index, revealed that the NP has increased from 437 in 1966 to 695 in 2000. This data reveals that the change of land use is influenced by various artificial factors. The NPS, which represents the declining degree of patch, decreased from 9.441 to 5.934, revealing that the change of land use has been progressing considerably. In regard to forest areas, land use reduced somewhat but did not indicate a significant change. Therefore, an analysis of the total index reveals that the edge of patch has become more complicated and that the variation index of patch has increased significantly. However, this study reveals that barriers to block pollution have weakened as a result and that there is a need to concentrate on the implementation and the management of the Riparian Buffer Zone. Consequently, this study reveals that substantial research is necessary in order to carry out the proper management of the Riparian Buffer Zone, especially in light of the distribution type of each patch and the change in conditions regarding them.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.3
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• pp.348-356
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• 2007

Statistical and probabilistic method was used in the analysis of data, which is the most effective one in describing the various natures, and the methodology relating the results with the design was developed. Influents and effluents of three treatment plants were analyzed and the focus was made on BOD, COD, SS, IN, TP The fluctuations of influent such as BOD, COD, SS were extremely large and their standard deviations(st.dev) were more than 10 mg/L. but those of TN, TP were small; the st.dev was 6.6 mg/L for TN, 0.6 mg/L for TP, respectively. But, effluent concentration showed consistent pattern regardless of the influent fluctuations, the st.dev was ranged between 0.28 and 4.48 mg/L. Effluent distributional characteristics were as follows; BOD, COD were distributed normally, but SS, TN, and TP, log-normally; unsymmetric and skewed to the right. The coefficient of reliability(COR) based on the results of statistics of data was introduced to evaluate the process performance an4 to reflect the process performance to the process design. The coefficient of reliability relates the design value(the goal) with the standards and it can be used in operating treatment facilities under a certain reliability level and/or in evaluating the reliability of the treatment facilities on operation. Each treated water quality of effluent showed the half of water quality standards in the level of 50% percentile and all treatment plant was achieved 100% probability of water quality standards. It was concluded that the variability of the process performance should be reflected to the design procedure and the standards through the analysis based on the statistics and the probability.

• Korean Journal of Environmental Agriculture
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• v.20 no.4
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• pp.289-296
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• 2001

The effects of HRT and effluent time on removals of pollutants in the electrochemical pilot were investigated. COD removal after 8 hour electrochemical reaction time in HRT 30 and 60 minutes were higher than that of 15 minute HRT. Turbidity removal was 90% or greater regardless of conditions during effluent time. Removals of T-N and T-P during effluent time in HRT 30 and 60 minutes were $71{\sim}74%$ and $85{\sim}98%$, respectively. To evaluate the combination of activated sludge process and continuous electrochemical as pretreatment, the removal efficiencies of pollutants was investigated. In two treatment processes of a single activated sludge system and a electrolysis pilot plus activated sludge systems, SVI and MLSS during effluent time were kept with $82{\sim}112$ and $1,230{\sim}1,750$ mg/L, respectively. COD removal was approximately 90% at early effluent time for both treatment systems, but COD removal in a single activated sludge was slightly decreased as effluent time went by, compared with the single activated sludge COD removal was slightly increased in the early stage of the electrolysis plus activated sludge system. Turbidity removal during effluent time was higher than 95% for both treatment systems. T-N removals during effluent time in a single activated sludge system and a electrolysis pilot plus activated sludge systems were $62{\sim}74%$ and $72{\sim}86%$, respectively. T-P removal in a electrolysis pilot plus activated sludge systems was increased by 9% at early effluent time and 15% after 72 hours of effluent time in compared with a single activated sludge system.

• Korean Journal of Environmental Agriculture
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• v.32 no.3
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• pp.224-230
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• 2013

BACKGROUND: Perchlorate(${ClO_4}^-$) is an anion that is extremely water-soluble and environmentally stable. It mostly exists in the form of sodium perchlorate, ammonium perchlorate and potassium perchlorate which are used in rocket fuels, propellants, ignitable sources, air bag inflation systems and explosives. Perchlorate can be taken into the thyroid glands and interfere with iodide uptake. The determination of perchlorate in agricultural products is important due to its potential health impact on humans. The objective of this study was to determine the perchlorate concentrations in the samples of various agricultural products and soils. METHODS AND RESULTS: In this study, samples of cereal(Rice, Barley, Corn, Bean), vegetable(Spinach, Lettuce, Sesame, Chives, Chili, Pumpkin, Tomato), fruit(Apple, Pear, Tangerine, Grape) were analyzed for perchlorate contents. Perchlorate concentrations were analyzed by liquid chromatography-tandem mass spectrometry. The results showed that agricultural products respectively contained perchlorate concentrations in the range of : cereals N.D.~$7.46{\mu}g/kg$, vegetables $0.52{\sim}23.06{\mu}g/kg$, fruits $0.19{\sim}2.66{\mu}g/kg$. Bioconcentration factor was in the order of : vegetables > cereals > fruits. Bioconcentration factor was highest follwed by Sesame 37.88, Corn 21.51, Spinach 10.57, Tangerine 4.39, Chives 2.89 and Lettuce 1.90. The recoveries of perchlorate from spiked agricultural products and soils ranged from 87.72~111.26% and 102.09~111.23%. CONCLUSION(S): The health risk assessment results obtained in this study are lower than the RfD(Reference Dose, 0.0007 mg/kg/body weight/day) value as suggested by the Integrated Risk Information System(US IRIS). Our results indicate that, people currently exposed to perchlorate from agricultural products consumption are considered as safe.

• Applied Chemistry for Engineering
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• v.5 no.5
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• pp.808-818
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• 1994

Effects of ceria additive on the activity and thermal aging behavior of supported Ru catalysts were investigated using Ru/${\gamma}$-$Al_2O_3$and Ru/$CeO_2$-${\gamma}$-$Al_2O_3$. The catalysts were characterized by $^{129}Xe$-NMR and $H_2$ chemisorption. The cataltic activity for conversion of CO, HC and $NO_x$ was measured using simulated automobile engine exhausts under lean, rich and stoichiometric conditions. For both fresh and aged catalysts, Ru/$CeO_2$-${\gamma}$-$Al_2O_3$ was more active than Ru/${\gamma}$-$Al_2O_3$ for all three pollutants. Results of $^{129}Xe$-NMR and $H_2$ chemisorption indicated that sintering of Ru particles occurred to the same extent for both catalysts during the thermal aging process. After thermal aging at 673K, however, the catalytic activity of the aged Ru/$CeO_2$-${\gamma}$-$Al_2O_3$ was substantially higher than that of the fresh one, while the activity of Ru/${\gamma}$-$Al_2O_3$ decreased after the thermal aging. This finding may suggest new active sites were created during the thermal aging, probably in the vicinity of the interface between Ru and Ce. For more quantitative investigation of the effect of a cation such as Ce on the thermal aging of Ru metal particles, Ru catalysts supported on cation-exchanged Y-zeolites were used as the model catalysts. The results indicated that when Ba, Ca, La, Y or Ce was used for the cation exchange, the exchanged cation did not affect the thermal aging behavior of Ru in Y-zeolite, as evidenced by $^{129}Xe$-NMR and EXAFS.

• Korean Journal of Ecology and Environment
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• v.45 no.4
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• pp.378-391
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• 2012

The objective of this study was to determine temporal patterns and longitudinal gradients of water chemistry at eight artificial reservoirs and ten streams within the Han-River watershed along the main axis of the headwaters to the downstreams during 2009~2010. Also, we evaluated chemical relations and their variations among major trophic variables such as total nitrogen (TN), total phosphorus (TP), and chlorophyll-a (CHL-a) and determined intense summer monsoon and annual precipitation effects on algal growth using empirical regression model. Stream water quality of TN, TP, and other parameters degradated toward the downstreams, and especially was largely impacted by point-sources of wastewater disposal plants near Jungrang Stream. In contrast, summer river runoff and rainwater improved the stream water quality of TP, TN, and ionic contents, measured as conductivity (EC) in the downstream reach. Empirical linear regression models of log-transformed CHL-a against log-transformed TN, TP, and TN : TP mass ratios in five reservoirs indicated that the variation of TP accounted 33.8% ($R^2$=0.338, p<0.001, slope=0.710) in the variation of CHL and the variation of TN accounted only 21.4% ($R^2$=0.214, p<0.001) in the CHL-a. Overall, our study suggests that, primary productions, estimated as CHL-a, were more determined by ambient phosphorus loading rather than nitrogen in the lentic systems of artificial reservoirs, and the stream water quality as lotic ecosystems were more influenced by a point-source locations of tributary streams and intense seasonal rainfall rather than a presence of artificial dam reservoirs along the main axis of the watershed.