• Title/Summary/Keyword: 염화칼륨

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Solubility and Yield Characteristics of KCl in Cement By-Pass Dust (시멘트 바이패스 더스트에 존재하는 염화칼륨의 용해 및 수득 특성)

  • Yun, Youngmin;Jeong, Jaehyun;Chu, Yongsik
    • Resources Recycling
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    • v.25 no.3
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    • pp.43-48
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    • 2016
  • Cement manufacturing plant uses various kinds of industrial/municipal waste. The waste contains considerable amount of potassium, chlorine and small amount of heavy metal. Many researches were performed to fabricate valuable resources from the waste. In this study, various methods, which dissolves and crystallizes potassium/chlorine to extract potassium chloride, were experimented. Especially amount of water, slurry temperature, and stirring time were controlled. Then kind of heavy metal and content of potassium chloride were analyzed. The yield of potassium chloride increased, as the amount of water for slurry increased but it increased slightly, when the water content was over 200%. The yield tended to increase, when the temperature of slurry was over a certain point. The yield did not increase in case of over 10 minutes stirring time. The kind and content of heavy metal in potassium chloride were various according to stirring time. The main heavy metals were Pb, Cu, and $Cr^{6+}$.

Effect of chloride to electroplating of zinc in chloride Bath (염화아연욕에서 염화물이 전기아연도금에 미치는 영향)

  • Kim, Jae-Min;Lee, Jeong-Hun;Kim, Yong-Hwan;Jeong, Won-Seop
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2009.05a
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    • pp.123-124
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    • 2009
  • 염화물이 전기아연도금에 미치는 영향을 분석해본 결과 염화물의 양이 부족한 경우에는 도금이 원활하지 않았지만 교반속도를 충분히 주면 도금이 가능하였고, 염화칼륨의 양에 따라서 우선성장하는 면이 달랐으며 가격이 비싼 염화칼륨을 염화나트륨으로 대체 가능성이 확인되었다.

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Conversion of Potassium Chloride to Potassium Nitrate by the Reaction of Nitrogen Dioxide (Potassium Chloride로부터 Nitrogen Dioxide 반응에 의한 Potassium Nitrate로의 전환)

  • Yim, Going
    • The Journal of Natural Sciences
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    • v.8 no.2
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    • pp.129-136
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    • 1996
  • The direct conversion of solid potassium chloride to solid potassium nitrate by the reaction of the chloride with gaseous nitrogen dioxide is suggested for the preparation of potassium nitrate. Thermodynamic calculations indicate that the free energy change is favorable at ordinary temperatures and that the reaction is exothermic. Experiments are described in which it was found that the reaction takes place at ordinary temperatures in the presence of a small amount of water with good yield. Nitrosyl chloride is produced simultaneously.

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Preparation of KCl through Removal of Heavy Metals from Chlorine By-Pass Dust (염소 바이패스 더스트를 이용한 염화칼륨 제조 및 중금속 제거)

  • Yun, Youngmin;Yeom, Nari;Lee, Kabsoo;Eom, Seonhui;Lee, Yonghyun;Chu, Yongsik
    • Resources Recycling
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    • v.26 no.2
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    • pp.11-17
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    • 2017
  • Many problems are occurred by using industrial by-product and municipal solid waste in the cement manufacturing process. The main components of chlorine by-pass dust generated by the use of the wastes are $K^+$, $Cl^-$, and a slight amount of heavy metals is also contained. In terms of waste recycling, it is necessary to eliminate the heavy metals. Therefore, in this study, the experiments for the removal of heavy metals from KCl which was produced by chlorine by-pass dust were conducted. In order to find optimum conditions for the removal of heavy metals, we have controlled the amount of water and precipitator. The type and concentration of heavy metals in KCl were analyzed. The concentration of heavy metals decreased as amount of precipitator increased. The heavy metals such as Pb, Cd, and As were not detected in dust A and B, when the mixing ratios between dust A(B) and water were controlled to be 1:2 (1:2, 1:3.5) with the addition of 3% precipitator (NaOCl).

Effect of Wallastonite, Potssium chloride and Potassium sulphate on the mineraligation of Urea (규회석 분말, 염화칼륨 및 황산칼륨이 요소질소의 유효화에 미친 영향)

  • Oh, Wang-Keun;Kim, Jea-Yeang
    • Korean Journal of Soil Science and Fertilizer
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    • v.23 no.4
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    • pp.293-296
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    • 1990
  • The effect of wallastonite, potassium chloride and potassium sulphate on the ammonification and nitrification of urea was studied in a non-planted green house experiment, filling with 500g soil in plastic pot and incubating for 17 days. Potassium sulphate gave superior effect on the neutralizing soil acidity of wallastonite than potassium chloride and raised soil pH which promoted ammonification and subsequent nitrification of urea. Less than 20% $NO_3-N$ against the sum of $NH_4-N$ and $NO_3-N$ was accumulated in soils incubated bellow pH 6.0. It seemed that pH 5.2 to 6.0 was the critical range for the nitrification of ammonium, or raising the concentration of ammonia in soils to the toxic level to the nitrification. It appeared that the nitrification could be occuring in low moisture, air dried, conditions of soil.

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3價크롬염에 의한 크롬鍍金

  • Go, Seok-Su;Park, Byeong-Ga
    • Journal of the Korean institute of surface engineering
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    • v.10 no.3
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    • pp.3-11
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    • 1977
  • The trivalent choromium plating process have been studied by serveral group of orkers in the recent years. In the plating process, Alecra 3 process is the most familiar one. Potassium formate and potassium chloride of the bath compositions in the above process, are exchanged for sodium formate and sodium chloride, and then they have been examined characteristics of the electrodeposition using above bath solution and a few optimum conditions. The results are as follows, (1) The characteristics of the electrodeposition ; that is, throwing power, covering power, appearance, and deposition rate are most satisfied when concentration of $CrCl_3{\cdot}6H_2O$ is 0.4 mol/l, and mol ratio of HCOONa to Chromium(III); HCOONa/$Cr^{3+}$, is 2 to 3. (2) Throwing power, covering power, color and deposit rate show a similiar tendency to Alecra 3 process.

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Physico-chemical and Sensory Characteristics of Cooked Sausage Substituted with KCl or MgCl2 for NaCl (KCl 또는 MgCl2의 NaCl 대체 소시지의 이화학적 및 관능적 특성)

  • Jin, Sang-Keun;Kim, Il-Suk;Hur, In-Chul;Nam, Sang-Hae;Kang, Suk-Nam;Shin, Daekeun
    • Journal of agriculture & life science
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    • v.45 no.5
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    • pp.81-89
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    • 2011
  • This study was carried out to investigate changes in physicochemical and sensory properties of cooked sausages replaced sodium chloride (NaCl) to potassium chloride (KCl) or magnesium chloride ($MgCl_2$) during storage for 30 days under $4^{\circ}C$. All sausages were prepared with different combination of salts as follow; CTL (1.5% NaCl), KCL (0.9% NaCl+0.6% KCl), MCL (0.9% NaCl+0.6% $MgCl_2$), KML (0.9% NaCl+0.3% KCl+0.3% $MgCl_2$) and PST (1.5% PanSalt). Among sausages moisture content in KML was the highest (p<0.05). Lightness and redness in CTL were lower than those of other treatments, but MCL and KML containing $MgCl_2$ showed higher CIE $L^*$ and $a^*$ values than CTL. The pH in CTL was the highest during storage, however, no significant difference was determined between two treatments, MCL and KML (p>0.05). Crude fat content and water holding capacity (WHC), hardness and cohesiveness of MCL sausages were higher than those of CTL. In sensory characteristics of cooked sausages, saltness in MCL was the lowest during 10 and 20 days of storage (p<0.05). Yellowness in PST was lower than other treatmeants. Gumminess and chewiness of texture property of sausages from MCL and KML were higher than CTL. The results indicate that the replacement of NaCl by KCl improved texture, but meat color was not improved as expected. In contrast, the replacement of NaCl by $MgCl_2$ enhanced color, texture and WHC, whereas partial replacement of NaCl by $MgCl_2$ must reduce bitter taste as compared to sausages manufactured with a NaCl only. Therefore, $MgCl_2$ may be a salt replacing NaCl in cooked pork sausages.

Growth and Yield Response of Chinese Cabbage and Radish on Application of Potassium Chloride Fertilizer (염화칼리 시용에 따른 배추와 무의 생육과 수량)

  • Song, Yo-Sung;Kwak, Han-Kang;Yeon, Byeong-Yeol;Yoon, Jung-Hui;Jun, Hee-Joong
    • Korean Journal of Soil Science and Fertilizer
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    • v.36 no.6
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    • pp.399-406
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    • 2003
  • The application of potassium above the optimum level may cause the inhibition of plant growth, fertilizer loss, and environmental pollution. Therefore, application rate of K fertilizer should be recommended on the basis of soil test. In order to determine critical K content in soils causing growth inhibition of vegetables, $1m^2-pot$ experiments with Chinese cabbage and radish were accomplished with various K-application rates. The threshold concentrations of exchangeable potassium causing the inhibition of plant growth were $0.96cmol_c\;kg^{-1}$ for Chinese cabbage in spring, and $1.28cmol_c\;kg^{-1}$ for radish in autumn. Above those concentration levels, the yields of them were decreased with the increase of potassium levels in soils. Germination rate of Chinese cabbage in spring decreased with increase of the electrical conductivity (EC) of soils due to application of potassium fertilizer. In the harvesting stage, the potassium contents of plant were increased with the increase of K application rate while plant uptake of nutrients was decreased at the K adjustment level of over $2.0cmol_c\;kg^{-1}$.