• Title/Summary/Keyword: 염화물 침투저항성

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Strength and Durability of Polymer-Modified Mortars Using Ground Granulated Blast-Furnace Slag (고로슬래그 미분말을 혼입한 폴리머 시멘트 모르타르의 강도 및 내구성)

  • 주명기;김남길;연규석
    • Journal of the Korea Concrete Institute
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    • v.14 no.2
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    • pp.164-170
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    • 2002
  • Effect of the polymer-binder ratio and slag content on the properties of combined wet/dry-cured polymer-modified mortars using granulated blast-furnace slag are examined. Results shows that the flexural and compressive strengths of polymer-modified mortar using the slag tend to increase with increasing slag content, and reaches a maximum at a slag content of 40 %, and is inclined to increase with increasing polymer-binder ratio. Water absorption, carbonation depth and chloride ion penetration depth tend to decrease with increasing polymer-binder ratio and slag content. Accordingly, the incorporation of slag into polymer-modified mortars at a slag content of 40% is recommended for a combined wet/dry curing regardless of the types of polymer.

Properties of Epoxy-Modified Mortars with Alkali Activators and Ground Granulated Blast Furnace Slag (알칼리자극제 및 고로슬래그미분말을 병용한 에폭시수지 혼입 폴리머 시멘트 모르타르의 성질)

  • Kim, Wan-Ki
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.1
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    • pp.85-92
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    • 2021
  • The purpose of this study is to investigate the properties of hardener-free epoxy-modified mortars(EMMs) using ground granulated blast furnace slag(GGBFS) and alkali activators. The hardener-free EMMs with a GGBFS content of 20% using 4 types of alkali activators were prepared with various polymer-binder ratios, and tested for strengths, water absorption, carbonation depth, chloride ion and H2SO4 penetration depth. The conclusions obtained from the test results are summarized as follows: The compressive strength of the EMMs with a GGBFS content of 20% attains a maximum at a polymer-binder ratio of 10%. The flexural strength of the hardener-free EMMs using Ca(OH)2 as a alkali activator is improved with increasing polymer-binder ratios. However, the flexural strength of the EMMs using NaCO3, Na2SO4 and Li2CO3 is gradually decreased with increasing polymer-binder ratios. Regardless of the type of alkali activator, the water absorption, chloride ion penetration and carbonation depth are remarkably decreased with increasing polymer-binder ratios due to the epoxy film formed in the EMMs. The H2SO4 penetration depth of the hardener-free EMMs with a GGBFS content of 20% is gradually increased with increasing polymer-binder ratio. In this study, the properties of hardener-free EMMs using Ca(OH)2 as a alkali activator are more excellent than those of other alkali activators.

Chloride Penetration Resistance of Ternary Blended Concrete and Discussion for Durability (삼성분계 혼합콘크리트의 염화물 침투 저항성 및 내구성에 대한 고찰)

  • Song, Ha-Won;Lee, Chang-Hong;Lee, Kewn-Chu;Kim, Jae-Hwan;Ann, Ki-Yong
    • Journal of the Korea Concrete Institute
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    • v.20 no.4
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    • pp.439-449
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    • 2008
  • Mineral admixtures are used to improve the quality of concrete and to develop sustainability of concrete structures. Supplementary cementitious materials (SCM), such as silica fume (SF), granulated blast furnace slag (GGBS) and pulverized fly ash (PFA), are gradually recognized as useful mineral admixture for producing high performance concrete. The study on ternary blended concrete utilizing mainly three major mineral admixtures is limited and the study on durability and chloride induced corrosion resistance of ternary blended concrete is very few. This study examines the durability characteristics of the ternary blended concrete composed of different amount of the SCM with ordinary Portland concrete and the study experimentally focuses on corrosion resistance evaluation of ternary blended concrete subjected to chloride attack. In this study, 50% replacement ratio of mineral admixture to OPC was used, while series of combination of $20{\sim}40%$ GGBS, $5{\sim}15%$ SF and $10{\sim}45%$ PFA binder were used for chloride corrosion resistance test. This study concerned the durability properties of the ternary blended concrete including the corrosion resistance, chloride binding, chloride transport and acid neutralization capacity. It was found that the ternary blended concrete utilizing the SCM densified the pore structures to lower the rate of chloride transport. Also, increased chloride binding and buffering to acid were observed for the ternary blended concrete with chlorides in cast.

Effect of the Kinds and Replacement Ratios of Mineral Admixtures on the Development of Concrete Resistance against the Penetration of Chloride Ions (혼화재 종류 및 치환율이 콘크리트의 내염성능 향상에 미치는 영향에 관한 연구)

  • Kim Young-Jin;Lee Sang-Soo;Kim Dong-Seuk;Yoo Jae-Kang
    • Journal of the Korea Concrete Institute
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    • v.16 no.3 s.81
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    • pp.319-326
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    • 2004
  • This paper investigates the effect of the concrete containing mineral admixtures(pozzolanic materials such as fly-ash, ground granulated blast-furnace slag, silica fume and meta kaolin) on the resistance properties to chloride ion invasion. The purposed testing procedure was applied to the concrete replaced mineral admixtures for 3${\~}$4 replacement ratios under water-binder ratios ranged from 0.40 to 0.55. For the electro-migration test, Tang and Nilsson's method was used to estimate the diffusion coefficient of chloride ion. As a results, the water-binder ratios, kinds of mineral admixtures and replacement ratios, water curing periods had a great effect on the diffusion coefficient of chloride ion, and the optimal replacement ratios had a limitation for each mineral admixtures. Also, the use of mineral admixtures by mass(replacement of OPC) enhance the resistance ability against chloride penetration compared with the plain concrete. The compressive strength was shown related to the diffusion coefficient of chloride ion, the compressive strength increases with the diffusion coefficient of chloride ion decreasing. Below the 50 MPa, the variation of diffusion coefficient of concrete replaced mineral admixtures was bigger than that of plain concrete.

Mechanical Properties And Chlorde Penetration Resistance of Shotcrete according to Mineral Admixture Types and Supplemental Ratio (광물성 혼화재료의 종류 및 혼입율에 따른 숏크리트의 역학적 특성 및 염해 저항성)

  • Han, Seung-Yeon;Yun, Kyong-Ku;Nam, Kyeong-Gung;Lee, Kyeo-Re;Eum, Young-Do
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.7
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    • pp.4960-4968
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    • 2015
  • In this study to improve the chloride durability of the shotcrete structure depending on types and contents of mineral admixture chloride resistance was evaluated by NT BUILD 492 of european test standards. It was also evaluated with the mechanical properties such as static strength and chloride penetration resistance. For shotcrete mixed crushed stone aggregate of the maximum size 10mm of coarse aggregates was produced. Based on 28days compression strength the variable mixed with 15% silica fume showed the highest strength in 67.55MPa. As the content of fly ash and blast furnace slag increased, the strength lowered. In the chloride penetration resistance test, OPC showed "high grade" and In the case of admixture, the penetration resistance tended to increase in all variables except the fly ash. In order to evaluate the service life, the accelerated chloride penetration test was conducted by the standards of KCL, ACI, FIB. Test results were obtained with the lowest spreading factor in a variable mixed with silica fume of 15%. At the KCI standards, It was found to have a service life of about 65 years and at the FIB standards, It was found to have a service life of 131 years. Among standards, the service life of KCI standard in all of the variables was evaluated as the lowest.

The corrosion behaviour of steel in high alumina cement concrete (알루미나 시멘트 콘크리트의 철근 부식 저항성)

  • Lee, Ho-Jae;Kim, Jae-Hwan;Ann, Ki-Yong;Song, Ha-Won
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.289-290
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    • 2009
  • In this study, the resistance of calcium aluminate cement (CAC) against chloride-induced corrosion was assessed by testing for the strength, chloride transport, and corrosion behaviour. The study found that the CAC concrete had better performance than ordinary Portalnd cement(OPC) in resisting the corrosion of steel.

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Durability of Ultrarapid-Hardening Polymer-Modified Mortar Using Redispersible Polymer Powder (재유화형 분말수지 혼입 초속경 폴리머 시멘트 모르타르의 내구성)

  • 이윤수;주명기;연규석;정인수
    • Journal of the Korea Concrete Institute
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    • v.14 no.5
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    • pp.660-667
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    • 2002
  • The effects of polymer-cement ratio and antifoamer content on the durability of ultrarapid-hardening polymer-modified mortars using redispersible polymer powder are examined. As a result, regardless of the antifoamer content, the setting time of the ultrarapid-hardening polymer-modified mortars using redispersible polymer powder tend to delay with increasing polymer-cement ratio. The water absorption and chloride ion penetration depth of the ultrarapid-hardening polymer-modified mortars using redispersible polymer powder decrease with increasing polymer-cement ratio and antifoamer content. The resistance of freezing and thawing and chemicals improvement is attributed to the improved bond between cement hydrates and aggregates because of the incorporation of redispersible polymer powder

A Study for Microstructure and Durability of Metakaolin Concrete (메타카올린 콘크리트의 미세 공극구조 및 내구성에 관한 연구)

  • Kim, Myung-Yu;Yang, Eun-Ik;Yang, Joo-Kyoung;Park, Hae-Geun;Chun, Sang-Eun;Lee, Myeong-Sub
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.417-420
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    • 2008
  • The requirement for durability of concrete is increasing recently as a large-scale concrete structure is built. For this reason, the concern about high-durable concrete is being high. Recently, metakaoline to be profitable in economical aspect as well as to have strength and durability of level similar to silica fume is evaluated highly as new admixture. In this study, the scaling, the drying shrinkage, the chloride resistance and the air-void structure are compared for both metakaolin and silica fume concrete. According to the results, the replacement of metakaoline improved the resistance of chloride penetration, freezing and thawing in concrete. On the other hand, as metakaolin was replaced to 10%, it was similar level with OPC in the property of scaling. It was showed that replacement of only metakaoline was similar with OPC in the drying shrinkage. However, MS5 reduced the drying shrinkage about 10%. In conclusion, replacement of the metakaoline 10% is the most excellent performance in terms of durability of concrete.

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Experimental Study on Physical Properties and Water Absorption Resistance Evaluation of Cement Mortar Incorporating Inorganic Metal Salt-based Water Repellent Powder (무기물 금속염계 발수분체를 혼입한 시멘트 모르타르의 물리적 특성 및 수분흡수저항성에 대한 실험적 연구)

  • Lee, Won Geun;Yoon, Chang Bok
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.609-616
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    • 2021
  • In this experimental, water-repellent powder, which is a metal salt-based inorganic substance, and natural zeolite powder, which is a pozzolan-based material, were mixed into cement mortar, and their physical properties and resistance to moisture were confirmed. It was confirmed that the test specimen using natural zeolite at the same time had excellent resistance in the water permeation test and the chloride penetration test as compared with the test specimen in which the inorganic metal salt-based water-repellent powder was mixed alone. When a metal salt-based water-repellent powder is used, it cannot be uniformly dispersed inside water due to its insoluble property, and is limited to the surface. When used at the same time as natural zeolite, the setting time at the initial stage of hydration is fast due to the pozzolan reaction, and the water-repellent powder adheres to the porous of the natural zeolite and is evenly distributed inside the test specimen to generate some water resistance.

An Experimental Study on Relation between Chloride Diffusivity and Microstructural Characteristics for GGBS Concrete (슬래그 미분말 혼합 콘크리트의 공극구조와 염화물 확산계수와의 관계에 대한 실험적 연구)

  • Kim, Tae-Sang;Jung, Sang-Hwa;Choi, Young-Cheol;Song, Ha-Won
    • Journal of the Korea Concrete Institute
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    • v.21 no.5
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    • pp.639-647
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    • 2009
  • In order to evaluate the durability of reinforced concrete structures under chloride attack from sea water and frost damage, it is important to analyze both the microstructural characteristics of concrete and its diffusion resistance of concrete against chloride ingress. In this study, a relation between micro-pore structures of concrete obtained by the Mercury Intrusion Porosimetry and accelerated chloride diffusivity as well as long term chloride diffusivity were studied for ground granulated blast furnace slag(GGBS) concrete. Different water-cement ratio of 40, 45, 50% and different unit cement concrete of 300, 350, 400 or 450 kg/$m^3$ of the GGBS concrete along with OPC concrete were used and freeze and thawing, and the change in diffusivity and microstructure were observed for both GGBS concrete and damaged GGBS concrete due to rapid freezing and thawing.