• Journal of the Korean Chemical Society
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• v.46 no.4
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• pp.323-330
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• 2002

The protonation equilibrium of 5-substituted 2-furaldehydes is investigated spectrophotometrically in aqueous sulfuric acid at $25^{\circ}C$ and the basicity constants(p$K_{BH+}$) of the substrates is calculated by means of the excess acidity method. The basicity constant of 5-metyl-2-furaldehyde having electron donating group is larger than that of 5- nitro-2-furaldehyde having electron withdrawing group. Difference between the basicity constants(p$K_{BH+}$) of these two compounds was about 3.25 pK unit. The m value which is the degree of solvation of the protonated substrate is similar to that of acetophenone having same protonation site. The dependence of p$K_{BH+}$ on m value shows good linear cor-relation.

• Journal of the Korean Chemical Society
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• v.38 no.4
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• pp.265-270
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• 1994

The aquation and base hydrolysis of [Co(en)$_2$NH$_3$Cl]$^{2+}$ were studied by UV spectroscopic method in various SDS aqueous solution. The base hydrolysis of [Co(en)$_2$NH$_3$Cl]$^{2+}$ with the addition of 0, 0.05, 0.1 mol dm$^{-3}$ sodium chloride was studied. For the aquation of the complex, the rate constant in the micellar phase(kH$^M$) was a little larger than that in the aqueous phase(kH$^W$). With the increase of SDS concentration, the second order rate constant(kOH) for the base hydrolysis unchanged below the CMC and sharply decreased down to a limiting value after the CMC was reached. The effect of added NaCl on the rate behavior of the complexes in the micellar solution were investigated by using an ion-exchanged model.

• Journal of the Korean Chemical Society
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• v.28 no.4
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• pp.210-216
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• 1984

Solvatochromic comparison methods were applied to determine Taft's solvent parameters, ${\pi}^{\ast}$(solvent polarity-polarizability), ${\alpha}$(solvent hydrogen bond donor acidity) and ${\beta}$ (solvent hydrogen bond acceptor basicity) for MeOH-MeCN solvent mixtures. Swain's solvent parameters A(anion solvation scale) and B(cation solvation scale) were also determined by least square fitting of kinetic data in the same binary solvent mixtures. It was found that: (i)${\beta}$ depends on the basicity of the solvent and increases with the MeOH content owing to the increase in polymeric structure of methanol; (ii) ${\pi}^{\ast}$depends on the dipole moment of the solvent and increases with the MeCN content of the solvent; (iii) ${\alpha}$ increases rapidly with the MeOH content as the hydrogen bond donor acidity of the solvent mixtures increases. Taft's reaction constants a and s and Swain's reaction constants a and b were determined for the reactions reported from our laboratory previously using solvent parameters determined in this work. No meaningful inter-relationship was found between the two set of reaction parameters, but a good linear correlation was found between the ratios a/s and a/b. Solvent effect on the reaction mechanism, substituent effect and leaving group ability were examined in the light of these reaction constants ratios.

• Journal of Korean Society of Environmental Engineers
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• v.37 no.6
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• pp.325-331
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• 2015

The experimental results of the characteristics of aluminum based and ferric based coagulants for the Nakdong River water showed that the main hydrolysis species contained in alum and $FeCl_3$ are monomeric species of 98% and 93.3%, respectively. The PACl of r=1.2 produced by the addition of base contained 31.2% of polymeric Al species and the PACl of r=2.2 contained 85.0% of polymeric Al species, as showing more polymeric Al species with increasing r value. Coagulation tests using Al(III) and Fe(III) salts coagulants for the Nakdong River water showed that the coagulation effectiveness of turbidity and organic matter was high in the order of $FeCl_3$ > PACl (r=2.2) > PACl (r=1.2) > alum. $FeCl_3$ has showed better flocculation efficiency than Al(III) salts coagulants. In addition, in case of Al(III) coagulants, the Al(III) coagulants of higher basicity, which contained more polymeric Al species, resulted in better coagulation efficiency for both turbidity and organic matter removed. The optimum pH range for all of the coagulants investigated was around pH 7.0 under the experimental pH range of 4.0~9.5. Especially, the highest basicity PACl (r=2.2) and $FeCl_3$ were considered as more appropriate coagulants for the removal of turbidity in the case of raw water exhibiting higher pH.

• Journal of the Korean Chemical Society
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• v.16 no.6
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• pp.369-372
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• 1972

The dissociation constants of dibasic carboxylic acids $(HOOC(CH_2)_nCOOH$, n = 0~4] in methanol, N, N-dimethylformamide and acetonitrile have been determined by the potentiometric method with a glass electrode. The difference between over-all dissociation constants in each other solvent is found to be of the same order of magnitude, and the $K_1/K_2$ ratios in aprotic dimethylformamide and acetonitrile are much greater than those in protic methanol and water.

• Journal of the Korean Chemical Society
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• v.35 no.5
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• pp.512-519
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• 1991

The axial ligations of nitrogenous bases (pyridine, imidazole, 1-methylimidazole and 2,6-lutidine) to Zn(II)-, Cu(II)-, and Ni(II)-tetrakis(o-chlorophenyl)porphyrin(o-ClTPP), and -tetraphenylporphyrin (TPP) were investigated in organic solvents $(CH_2Cl_2,\;C_6H_6,\;CH_3NO_2,\;(CH_3)_2CO,\;CHCl_3,\;DMF\;and\;DMSO)$ and at 0.01M of ionic strength. The equilibrium constants for the ligation reactions of methalloporphyrins were determined using spectrophotometric method at 15∼35${\circ}C$. In case of M(II)-TPP the equilibrium constants K were considerably larger than those of M(II)-(o-Cl)TPP, depending on steric effect of the porphyrin. The linear relationships between logK of the axial ligation and $pK_a$ of nitrogenous base were shown in M(II)-TPP, but not in M(II)-(o-Cl)TPP. The stabilities of MTPP(L) were controlled by the reation enthalpy and entropy, while those of M(o-Cl)TPP almost by the reaction entropy. The coordinating power of solvent to the methalloporphyrin were also studied in $CHCl_3,\;(CH_3)_2CO$, DMF and DMSO. From those results the solvent effects on the equilibrium constants were discussed.

• Proceedings of the Korean Information Science Society Conference
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• 2003.10a
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• pp.496-498
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• 2003

접미사 배열은 긴 문자열에 대해 효율적인 문자열 검색을 가능하게 하는 자료구조이다. 접미사 배열은 문자열의 접미사들의 사전식 정렬순서를 배열로 저장한다. 비슷한 효과를 가진 접미사 트리에 비해서 접미사 배열은 저장 공간을 적게 차지하기 때문에 생명정보과학의 염기 서열 등 큰 크기의 문자열의 처리에 더욱 유리하다. 본 논문에서는 2003년에 발표된 Ko-Aluru, K$\square$rkk$\square$inen-Sanders 및 기존의 Manber-Myers 등 세 개의 접미사 배열 생성 알고리즘들의 염기 서열 입력 자료에 대한 실행 시간 및 기억 장치 사용량을 실험을 통해 비교한다. 특히 Ko-Aluru와 K$\square$rkk$\square$inen-Sanders 알고리즘은 실행 시간 및 저장 공간의 이론적인 복잡도가 O(n)으로 동일하기 때문에 실험을 통해서 계산 복잡도에 숨어있는 상수를 비교한다. 실험 결과 K$\square$rkk$\square$inen-Sanders 알고리즘이 가장 효율적임을 보인다.

• Proceedings of the Korean Society of Computer Information Conference
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• 2019.01a
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• pp.315-318
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• 2019

본 논문은 화학에서 사용되는 2가지 산, 염기 모델에 대한 이해를 높이고자 각 모델의 핵심 알고리즘가 반영된 단계별 교육용 콘텐츠를 개발하는데 목적이 있다. 이를 위해 먼저 Arrhenius와 Brønsted-Lowry 모델이 갖는 핵심 알고리즘을 탐색하였으며, 이러한 핵심 알고리즘을 반영된 단계별 교육용 콘텐츠를 JAVA를 이용하여 개발하였다. 개발된 교육용 콘텐츠는 총 5단계로 구성되어 있다. 1단계는 화학에서 다루어지는 입자들이 개별적으로 무작위하게 운동함으로 표현하였으며, 2단계는 화학반응이란 이러한 무작위적 운동 중 입자 간 충돌에 의해 반응이 개시됨을 보여주었다. 3단계에서는 단일입자에 대해 정반응과 역반응을 동시에 고려한 진행되는 상황을, 4단계는 여러 입자가 동시다발적으로 정반응과 역반응에 참여한 상황을 구현하였다. 마지막 5단계는 정반응과 역반응의 공존의 비율이 다른 상황을 통해 평형상수의 의미를 고찰하도록 하였다. 창발적 사고의 핵심은 여러 입자를 생각하는 확률적 사고와 이러한 여러 입자가 개별적으로 움직인다는 사고가 반영되어야 한다. 이 연구에서 개발한 교육콘텐츠를 활용한다면 학생들이 보다 창발적 사고를 하는데 도움을 줄 것으로 기대된다.

• Korean Journal of Microbiology
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• v.32 no.3
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• pp.177-181
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• 1994

The sequences of the cytoplasmic 5S rRNAs(EMBL accession number X73589 and X73890) from two polupores, Ganoderma applanatum and Schizopora paradoxa, were determined by the direct chemical method for sequencing RNA and compared to the sequences of 9 reported mushrooms. 5S rRNAs of Ganoderma applanatum and Schizopora paradoxa consisted of 118 bases and fit the secondary structure model of the 5S rRNAs of basidiomycetes proposed by Huysmans et al. Based on Kimura’s K_nuc values, the closest fungus to Ganoderma applanatum was Ceratobasidium cornigerum and the one to Schizopora paradoxa was Bjerkandera adusta. When the secondary structures of 5S rRNAs of 11 mushrooms were compared the base substitution occurred at helix regions more than at loop regions. When a phylogenetic tree was constructed using the Neighbor program of the PHYLIP package, it partially discriminated and separated the mushrooms of the Hymenomycetes by the order.

• Journal of the Korean Chemical Society
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• v.44 no.5
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• pp.429-434
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• 2000

The rate constants for the hydrolysis of styryldiphossphine oxide(SDPO) were deter-mined by ultraviolet visible spectrophotometric method and rate equation which can be applied over wide pH ranges was obtained. On the basis of pH-rate profile, hydrolysis product analysis, general base catalysis and substituent effect, a plausible hydrolysis mechanism is proposed : Below pH 4.5, the hydrolysis reaction is pro-ceeded by the attack of water to carbocation after protonaticentration of hydroxide ion.