• Title/Summary/Keyword: 열 싸이클

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Ageing Characteristics of Porcelain Interface by Forest Fire Thermal Shock (산불 열충격에 의한 자기애자의 계면열화 특성)

  • Han, Se-Won;Choi, In-Hyuk;Lee, Dong-Iil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.454-455
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    • 2007
  • 송전용 자기 애자에 대하여 산물화염 특성과 송전선로의 환경 검토를 토대로 송전용 절연물에 대한 산불화염 열화특성을 1)내열충격 열화와 2) 열충격 싸이클 열화로 나누어 가속시킨 후 절연물의 성능을 시험 평가하였다. 또한 승전용 자기애자 (254mm, 36,000lbs)를 대상으로 실제 삼불열화 조건을 근간으로 기계적, 열적 환경을 고려한 자기애자의의 수축, 팽창 변위에 따른 계면의 응력거동을 열충격 및 내열충격 시험의 결과와 비교 분석하였다.

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온도분포가 이동하는 액체금속로 원통용기의 열적 라체팅 해석

  • Lee, Hyeong-Yeon;Kim, Jong-Beom;Lee, Jae-Han;Koo, Kyung-Hoe;Yoo, Bong;Gwak, Dae-Yeong;Im, Yong-Taek
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05d
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    • pp.235-240
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    • 1996
  • 본 연구에서는 고온의 천이 열하중을 받는 304 SS 재질의 액체금속로 원통용기에 대하여 진행성 변형기구인 열적 라체팅(thermal ratcheting) 변형거동을 해석하였다. 재료의 반복 소성을 나타내는 구성식으로서 Chaboche모델을 이용하였으며 이 모델의 적용을 위하여 ABAQUS의 사용자 프로그램을 개발하였다. 열천이 과정이 반복되는 동안에 축방향의 온도분포 이동에 따른 탄소성 해석을 수행한 결과 소성변형이 각 싸이클마다 누적되어 점진적 변형이 일어났으며 이 해석결과를 시험치와 비교함으로써 해석의 타당성을 검토하였다. 반복 소성거동에 대한 Chaboche 모델을 이용하면 천이 열하중을 받는 304 SS. 재질의 고온구조물에 대하여 라체팅 거동을 정량적으로 평가 할 수 있는 것으로 나타났다.

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Mechanical and Thermal Characteristics of Cement-Based Composite for Solar Thermal Energy Storage System (태양열 에너지 저장시스템 적용을 위한 시멘트 기반 복합재료의 역학 및 열적 특성)

  • Yang, In-Hwan;Kim, Kyoung-Chul
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.4
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    • pp.9-18
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    • 2016
  • The thermal and mechanical properties of fiber-reinforced cement-based composite for solar thermal energy storage were investigated in this paper. The effect of the addition of different cement-based materials to Ordinary Portland cement on the thermal and mechanical characteristics of fiber-reinforced composite was investigated. Experiments were performed to measure mechanical properties including compressive strength before and after thermal cycling and split tensile strength, and to measure thermal properties including thermal conductivity and specific heat. Test results showed that the residual compressive strength of mixtures with OPC and slag was greatest among cement-based composite. Thermal conductivity of mixtures including graphite was greater than that of any other mixtures, indicating favor of graphite for improving thermal transfer in terms of charging and discharging in thermal energy storage system. The addition of CSA or zirconium increased specific heat of fiber-reinforced cement-based composite. Test results of this study could be actually used for the design of thermal energy storage system in concentrating solar power plants.

Thermal Cycling and High Temperature Storage Reliabilities of the Flip Chip Joints Processed Using Cu Pillar Bumps (Cu Pillar 플립칩 접속부의 열 싸이클링 및 고온유지 신뢰성)

  • Kim, M.Y.;Lim, S.K.;Oh, T.S.
    • Journal of the Microelectronics and Packaging Society
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    • v.17 no.3
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    • pp.27-32
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    • 2010
  • For the flip chip joints processed using Cu pillar bumps and Sn pads, thermal cycling and high temperature storage reliabilities were examined as a function of the Sn pad height. With increasing the height of the Sn pad, which composed of the flip chip joint, from 5 ${\mu}m$ to 30 ${\mu}m$, the contact resistance of the flip chip joint decreased from 31.7 $m{\Omega}$ to 13.8 $m{\Omega}$. Even after thermal cycles of 1000 times ranging from $-45^{\circ}C$ to $125^{\circ}C$, the Cu pillar flip chip joints exhibited the contact resistance increment below 12% and the shear failure forces similar to those before the thermal cycling test. The contact resistance increment of the Cu pillar flip chip joints was maintained below 20% after 1000 hours storage at $125^{\circ}C$.

A Study on Hydrogen Production with High Temperature Solar Heat Thermochemical Cycle by Heat Recovery (열회수에 따른 고온 태양열 열화학 싸이클의 수소 생산에 관한 연구)

  • Cho, Ji-Hyun;Seo, Tae-Beom
    • Journal of the Korean Solar Energy Society
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    • v.37 no.2
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    • pp.13-22
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    • 2017
  • Two-step water splitting thermochemical cycle with $CeO_2/ZrO_2$ foam device was investigated by using a solar simulator composed of 2.5 kW Xe-Arc lamp and mirror reflector. The hydrogen production of $CeO_2/ZrO_2$ foam device depending on heat recovery of Thermal-Reduction step and Water-Decomposition step was analyzed, and the hydrogen production of $CeO_2/ZrO_2$ and $NiFe_2O_4/ZrO_2$ foam devices was compared. Resultantly, the quantity of hydrogen generation increased by 52.02% when the carrier gas of Thermal-Reduction step is preheated to $200^{\circ}C$ and, when the $N_2/steam$ is preheated to $200^{\circ}C$ in the Water-Decomposition step, the quantity of hydrogen generation increased by 35.85%. Therefore, it is important to retrieve the heat from the highly heated gases discharged from each of the reaction spaces in order to increase the reaction temperature of each of the stages and thereby increasing the quantity of hydrogen generated through this.

Thermal/Mechanical Properties of Hafnium Carbide Coatings on Carbon-Carbon Composites (탄소-탄소 복합재료의 하프늄 탄화물 코팅재의 열적/기계적 특성)

  • Choi, So-dam;Seo, Hyoung-IL;Lim, Byung-Joo;Sihn, Ihn Cheol;Lee, Jung Min;Park, Jong Kyoo;Lee, Kee Sung
    • Composites Research
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    • v.31 no.5
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    • pp.260-266
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    • 2018
  • This study investigates thermal and mechanical characterization of Hafnium carbide coating on the $C_f-C$ composites. The hafnium carbide coatings by vacuum plasma spray on the C/C-SiC composites are prepared to evaluate oxidation and wear resistance. We perform the thermal durability tests by thermal cycling at $1200^{\circ}C$ for 10cycles in air and investigates the weight change of each cycle. We also evaluate the wear and indentation behavior using tungsten carbide ball indenter as a mechanical evaluation. As a result, the HfC coating is beneficial to reduce of weight loss during thermal cycling test and improve the elastic property of C/C-SiC composite. Especially, the HfC coating improves the wear resistance of C/C-SiC composite.

Electrochemical Properties of Al Doped Li(Ni1/3Co1/3Mn1/3-xAlx)O2, Cathode Materials (알루미늄이 첨가된 Li(Ni1/3Co1/3Mn1/3-xAlx)O2 양극활물질의 전기화학적 특성)

  • Kim Seon-Hye;Shim Kwang-Bo;Kim Chang-Sam
    • Journal of the Korean Electrochemical Society
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    • v.9 no.2
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    • pp.64-69
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    • 2006
  • Cathode materials of Al-doped $Li(Ni_{1/3}Co_{1/3}Mn_{1/3-x}Al_x)O_2$ (x=0.0, 0.005, 0.01 0.05) for lithium ion batteries were synthesized with ultra-sonic spray pyrolysis method and single-step heat treatment. No secondary phases were found in all synthesized powders. The intensity ratio of $I_{003}\;to\;I_{104}$, however, slightly decreased and the particle size increased with the Al contents. The cells with bare, 0.5 and 1.0 at% Al-doped powders showed the initial discharge capacities of 182, 180 and $184mAhg^{-1}$ in a voltage range of $3.0\sim4.5V$ at 1C rate, and the capacity retentions of 81, 77 and 78% at the end of 30 cycles, respectively. But in the voltage range of $3.0\sim4.6V$, the Al-doping significantly enhanced the cycle stability. For example, the discharge capacity after 50 cycles was maintained to 70% in the 0.5 at% Al-doped sample compared to only 30% in no doped sample. The improvement of the cycle stability was thought to be due to $Mn^{3+}$ ion decrease as the Al doping from the XPS analysis results.

Hydrogen Production with High Temperature Solar Heat Thermochemical Cycle Using Dual-zone Reactor and CeO2/ZrO2 Foam Device (Dual-zone reactor와 CeO2/ZrO2 Foam Device를 이용한 고온 태양열 열화학 싸이클의 수소 생산)

  • Cho, Ji-Hyun;Seo, Tae-Beom
    • Journal of the Korean Solar Energy Society
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    • v.37 no.5
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    • pp.27-37
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    • 2017
  • In this study, an artificial solar simulator composed of a 2.5 kW Xe-Arc lamp and mirror reflector was used to carry out the solar thermal two step thermochemical water decomposition cycle which can produce high efficiency continuous hydrogen production. Through various operating conditions, the change of hydrogen production due to the possibility of a dual-zone reactor and heat recovery were experimentally analyzed. Based on the reaction temperature of Thermal-Reduction step and Water-Decomposition step at $1,400^{\circ}C$ and $1,000^{\circ}C$ respectively, the hydrogen production decreased by 23.2% under the power off condition, and as a result of experiments using heat recovery technology, the hydrogen production increased by 33.8%. Therefore, when a thermochemical two-step water decomposition cycle is conducted using a dual-zone reactor with heat recovery, it is expected that the cycle can be operated twice over a certain period of time and the hydrogen production amount is increased by at least 53.5% compared to a single reactor.

A Study on the Fabrication and Characteristics of Continuous W-Cu FGM by Spark Plasma Sintering (방전플라즈마소결법에 의한 W-Cu 연속경사기능재료의 제조와 특성에 관한 연구)

  • 신철균;강태훈;권영순;김지순;김환태;석명진
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.217-217
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    • 2003
  • W-Cu 합금은 우수한 전기적, 열적 특성으로 인하여 열소산재료(Heat sink)로 많이 응용되고 있다. 첨단 전자부품 이외에도 핵융합로의 Diverter가 그 예로서, 내부는 고강도와 고융점의 특성을 요구하는 반면, 외부는 높은 열전도성을 필요로 한다. 그래서 동일한 조성의 일반적인 W-Cu 합금보다 W과 Cu의 조성이 점차적으로 변화하는 경사기능재료(Functionally Graded Materials)가 냉각효율이 클 것으로 기대된다. 현재, W-Cu FGM에 대한 많은 연구가 진행되고 있지만, 그 조성이 연속적으로 변화하는 W-Cu FGM에 대한 연구는 전무한 실정이다 본 연구에서는 방전플라즈마 소결장치(Spark Plasma Sintering System)와 용침고정을 이용하여 연속적인 조성변화를 갖는 W-Cu FGM을 제조하고 그 특성에 관해 분석하고자 하였다. 소결체가 밀도 변화를 갖게 되도록 제작한 특수 경사기능 몰드에 W분말을 장입한 후, 15㎬의 압력하에서 SPS를 이용하여 W소결체를 제조하였다. 제조된 W소결체는 수평관상로에서 수소분위기 하에 Cu 용침을 실시하여 W-Cu FGM을 제조하였다 SEM을 이용한 각 위치별 조직관찰과 Image Analyzer를 이용한 W과 Cu의 면적비, 그리고 비커스경도계에 의한 경도 측정을 실시하였다. 또 열기계적 분석기를 이용하여 측정된 선팽창률로부터 열팽창계수를 구하였다. 80$0^{\circ}C$에서 ?칭하는 반복적인 싸이클을 통해 열충격시험을 실시하였고, Laser flash method로 열확산계수를 측정하였다.

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A Study on Natural Ventilation by the Caloric Values of HLW in the Deep Geological Repository (지하처분장내 고준위 방사성 폐기물 발열량에 따른 자연환기력 연구)

  • Roh, Jang-Hoon;Choi, Heui-Joo;Yu, Yeong-Seok;Yoon, Chan-Hoon;Kim, Jin
    • Tunnel and Underground Space
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    • v.21 no.6
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    • pp.518-525
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    • 2011
  • In this study, the natural ventilation pressure resulting from the large altitude difference which is a characteristic of high radioactive waste repository and the caloric value of the heat emitted by wastes was calculated and based on the results, natural ventilation quantities were calculated. A high radioactive waste repository can be considered as being operated through closed cycle thermodynamic processes similar to those of thermal engines. The heat produced by the heating of high radioactive wastes in the underground repository is added to the surrounding air, and the air goes up through the upcast vertical shaft due to the added heat while working on its surroundings. Part of the heat added by the work done by the air can be temporarily changed into mechanical energy to promote the air flow. Therefore, if a sustained and powerful heat source exists in the repository, the heat source will naturally enable continued cyclic flows of air. Based on this assumption, the quantity of natural ventilation made during the disposal of high radioactive wastes in a deep geological layer was mathematically calculated and based on the results, natural ventilation pressure of $74{\sim}183$Pa made by the stack effect was identified along with the resultant natural ventilation quantity of $92.5{\sim}147.7m^3/s$. The result of an analysis by CFD was $82{\sim}143m^3/s$ which was very similar to the results obtained by the mathematical method.