• Title/Summary/Keyword: 열퇴화

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Thermal Degradation of Black Cobalt Solar Selective Coatings (흑색 코발트 태양 선택흡수막의 열퇴화)

  • Lee, Kil-Dong
    • Journal of the Korean Solar Energy Society
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    • v.35 no.4
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    • pp.9-15
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    • 2015
  • Black cobalt solar selective coatings were prepared by using an electroplating method. The changes in the optical properties of the black cobalt selective coating due to thermal degradation were analyzed by using the Auger electron spectroscopy (AES) and spectrophotometer. The black cobalt selective coating was prepared on a copper substrate by using a synthesized electrolyte with $CoCl_2$ and KSCN at a current density of ${\sim}0.5A/dm^2$ for 45s ~ 60s. Its optical properties were a solar absorptance (${\alpha}$) of the order of 0.80 ~ 0.84 and a thermal emittance (${\epsilon}$) of 0.01. From the AES depth profile analysis of heated sample, thermal degradation of the black cobalt selective coating heated for 33 hours at temperature of $350^{\circ}C$ occurred primarily due to interdiffusion at interface of cobalt and copper substrate. This results were predictable that the ${\alpha}$ decreases due to the thermal oxidation and diffusion.

Experimental Study on the Isobaric Thermal Expansion Coefficient Density and Zero-shear-rate Viscosity of Viscoelastic Fluid (점탄성 유체의 정압 열팽창계수, 밀도 및 전단속도 0에서의 점동에 대한 실험연구)

  • 최민구
    • The Korean Journal of Rheology
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    • v.7 no.3
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    • pp.181-191
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    • 1995
  • 점탄성유체의 물성치들 중 정압열팽창계수 및 밀도는 자연대류 열전달 연구에 전단 속도 0에서의 점도는 점탄성유체에 대한 모델들 사용 시 필요하다. 본 연구에서는 점탄성유 체이며 마찰 감소 첨가제, 유전자 분리용액동으로 사용하는 Separan AP-273 용액의 정압열 팽창계수, 밀도 및 전단속도 0에서의 점도에대한 농도 및 온도의 영향을 조사하였다. 작동유 체의 물성치들은 10~6$0^{\circ}C$의 온도범위와 100~20,000wppm의 농도범위에서 측정되었다. 작 동유체의 물성치들에 미치는 열주기와 노화의 영향을 조사하기 위해서 정압열팽창계수와 전 단속도 0에서의 점도를 교대로 두 번씩 측정했다. 정압열팽창계수 및 밀도를 측정하는 장치 의 측정 정밀도는 증류수에 대한 측정치와 문헌에 나타난 자료를 비교하여 얻었고 이는 $\pm$ 2%이내였다. Separan AP-273용액의 정압열팽창계수 및 밀도는 증류수의 값들로 대치될수 있다. 작동유체의 정압열팽창계수와 밀도는 열주기와 노화의 영향을 받지 않았다. 낙하식 점 도계를 사용해 측정한 겉보기점도 값들을 나타내느 flow curve에서 전단속도가 0이 되는방 향으로 겉보기점도를 외삽시켜 Separan AP-273용액에 대한 전단속도0에서의 점도를 얻었 다. 정압열팽창계수 측정 전후에 측정한 작동유체에 대한 전단속도 0에서의 점도는 열주기 와 노화로 인해 퇴화되었다.

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Effect of Wollastonite and Nitrogen Application on the Growth of Rice Plant (퇴화염토에서 수도생육에 대한 질소와 규회석의 시용효과)

  • 김규진;이주열
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.26 no.4
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    • pp.279-286
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    • 1981
  • This study was conducted to find out the effect of wollastonite application in degraded saline soil condition on the growth of japonica rice variety. The variety, Palgweng was tested with 4 levels of wollastonite (200, 400, 600 and 400/200 kg/l0a) and two nitrogen levels (12 and 16 kg/l0a). The effect of wollastonite was higher in 16 than 12 kg of nitrogen application. The wollastonite application reduced rice leaf blast and dead left at lower nodal position, and increased percentage of effective tillers, percentage of ripened grains and 1, 000 grain weight. The SiO$_2$ content of upper leaf was higher than lower leaf in 200 kg of wollastonite application, but there was no difference under high wollastonite application (400 kg/l0a). Highly significant positive correlationships were obtained between SiO_2 content of plant at heading and percentage of ripened grains, (r=0.613) and SiO_2 content of flag leaf and percentage of ripened grains (r=0.407). Wollastonite application did not affect the development and degeneration of primary and secondary rachis branches of panicles, but it increased the number of spikelets. The highest grain yield was obtained with 16 kg of nitrogen and 600 kg of wollastonite.

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An experimental study on the thermal entrance lengths for viscoelastic polymer solutions in turbulent tube flow (점탄성 특성을 가진 폴리머용액의 난류유동 열적입구길이에 관한 실험적 연구)

  • 유상신;황태성;엄정섭
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.12 no.5
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    • pp.1189-1196
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    • 1988
  • Thermal entrance lengths of turbulent tube flow for viscoelastic polymer solutions are investigated experimentally in the recirculating flow system with tubes of inside diameters 8.5mm(L/D=710) and 10.3mm(L/D=1158), respectively. In the present system, the hydrodynamic and thermal boundary layers develop simultaneously from the beginning of the test section. To provide the boundary condition of constant heat flux at the wall, the test tubes are heated directly by electricity. The polymer solution used in the current study is 1000 wppm aqueous solution of polyacrylamide(Separan AP-273). The apparent viscosity of the polymer solutions circulating in the flow system are measured by the capillary tube viscometer at regular time intervals. Thermal entrance lengths vary due to the rate of degradation. The entrance lengths of degraded polymer solutions are about 500~600 times the diameter. However, the entrance lengths of fresh polymer solutions are greater than the lengths of the test tubes used in this study suggesting that thermal entrance lengths for viscoelastic polymer solutions are greater than 1100 tube times the diameters. Friction factor is almost insensitive to the degradation, but the heat transfer $j_{H}$-factor is affected seriously by degradation. Based on the present experimental data of fresh solutions a correlation for the heat transfer $j_{H}$-factor is presented.ted.

Rutherford Backscattering of Black Chrome Solar Selective Coatings (흑색크롬 태양광 선택흡수막의 Rutherford산란)

  • Lee, Kil-Dong;Chea, Young-Hi;Auh, Paul-Chung-Moo
    • Solar Energy
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    • v.10 no.1
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    • pp.57-62
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    • 1990
  • The influence of substrate materials on the thermal stability of black chrome coating was investigated by Rutherford backscattering spectrometry(RBS). In order to study thermal degradation the sample were annealed in air for 24 hour at temperature of 450. Cu, Ni, and S.S(Stainless steel 304) were used as substrate for selective coating. The experimental results of substrate diffusion was discussed. It was found that little diffusion of substrate material occurred for the sample pre. pared on stainless steel.

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Contact Resistance and Electrode Degradation on Semiconducting PTC $BaTiO_3$ Ceramics (반도성 PTC $BaTiO_3$ 세라믹에서 전극의 접촉 저항 및 퇴화)

  • 박철우;조경호;이희영;이재열
    • Journal of the Korean Ceramic Society
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    • v.33 no.11
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    • pp.1231-1236
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    • 1996
  • The electrode resistance of semiconducting PTC BaTiO3 ceramic material was studied in some detail. Comme-rical In-Ag paste In-Ga alloy and electroless plated Ni as well as evaporated Al were chosen as electrode. The contact resistance of electroded samples were measured by both dc resistivity and ac impedance analysis. The aging effect on contact resistance under cyclic loading from -1$0^{\circ}C$ to 85$^{\circ}C$ was also monitored for the prolonged period of time. In case of Al electroded samples the heat treatment and protective coating had effects on the stability against contact resistance degradation. It was also found that the samples with commercial In-Ag paste and electroless plated Ni electrode had good properties of contact resistance against aging.

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The heat transfer characteristics of viscoelastic non-newtonian fluids in the entrance region of circular tube flows (원형관속을 유동하는 점탄성 유체의 입구 영역 열전달 특성에 관한 연구)

  • 엄정섭;황태성;유상신
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.5
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    • pp.1032-1043
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    • 1989
  • The heat transfer characteristics of the drag reducing polymer solutions are investigated experimentally in the thermal entrance region of circular tube flows. Fluids used in experiments are the aqueous solutions of high molecular polymer, polyacrylamide Separan AP-273 and the range of polymer concentrations is from 20 to 1000 wppm. Two stainless steel tubes with inside diameter 8.5mm(L/D=712) and 10.3mm(L/D=1160) are used for the heat transfer flow loops. The flow loop is set up to measure friction factors and heat transfer coefficients of test sections in two different modes; the recirculating flow system and once-through flow system. The test tubes are heated directly by electricity to apply the constant heat flux boundary conditions to the wall. Three different types of adaptors are used to observe the effects of the upstream flow conditions of the heat transfer test sections. The viscosity and characteristic relaxation time of the test fluids circulating in the flow system are measured by the capillary tube viscometer and falling ball viscometer at regular time intervals. The installed adaptors exhibit slight effect on the entrance heat transfer of Newtonian fluid. However, no noticeable effects are observed for the entrance heat transfer of the drag reducing fluids. The order of magnitude of the thermal entrance lengths of the drag reducing fluids which follow the minimum friction asymptote is much longer than that of Newtonian fluids in turbulent flows. A new dimensionless parameter, the viscoelastic Graetz number, is defined and all the experimental data are recasted in terms of the viscoelastic Graetz number. The local Nusselt number of the viscoelastic fluids is represented as a function of flow behavior index n and the viscoelastic Graetz number. As degradation continues the viscosity and the characteristic relaxation time of the testing fluids decrease. Weissenberg number defined by the relaxation time and D/V appears to be a proper dimensionless parameter in describing degradation effects on heat transfer of the viscoelastic fluids.

Performance Evaluation of Selective Coatings for Solar Thermal Collectors (태양열 집열기에 사용될 선택흡수막의 성능 평가)

  • Lee, Kil-Dong
    • Journal of the Korean Solar Energy Society
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    • v.32 no.4
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    • pp.43-50
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    • 2012
  • Metal-metal oxide (M-M oxide) cermet solar selective coatings with a double cermet layer film structure were deposited on the Al-deposited glass substrate by using a directed current (DC) magnetron sputtering technology. M oxide (CrO and ZrO) was used as the ceramic component in the cermets, and Cr and Zr used as the metallic components. In addition, black Cr (Cr-$Cr_2O_3$ cermet) solar selective coatings were deposited on the Ni-plated Cu substrate by using a electroplating method for comparison. The thermal stability tests were carried out for performance evaluation of solar coatings. Reflectance measurements were used to evaluate both solar absorptance(${\alpha}$) and thermal emittance (${\epsilon}$) of the solar coatings before and after thermal testing by using a spectrometer. Optical properties of optimized cermet solar coatings were ${\alpha}{\simeq}0.94-0.96$ and ${\epsilon}{\simeq}0.1$ ($100^{\circ}C$). The results of thermal stability test of M-M oxide solar coatings showed that the Cr-CrO cermet solar selective coatings were more stable than the Zr-ZrO cermet selective coatings at temperature of both $400^{\circ}C$ in air and $450^{\circ}C$ in vacuum. The black Cr solar selective coatings were degraded in air at temperature of $400^{\circ}C$. The main optical degradation modes of these coatings were diffusion of metal atoms, and oxidation.

A Study on Characteristics of Drag Reduction Additive under High Temperature Range (고온영역에서 계면활성제의 마찰저감 성능 특성에 관한 연구)

  • Cho, Sung-Hwan;Ryu, Jae-Sung;Jung, Sang-Hoon
    • Journal of Energy Engineering
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    • v.19 no.2
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    • pp.116-120
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    • 2010
  • Overall total length of hydraulic pipe to transport the hot water in the domestic district heating network is above 3,000 Km approximately. This long pipe network requires a lots of the transport pumping power by surface friction of fluid. In this study, the drag reduction(DR) of Amin Oxide $C_{18}$ as non-ionic surfactant according to the fluid velocity, temperature and surfactant concentration under the condition of above $80^{\circ}C$ fluid temperature were investigated experimentally. Results showed that new amin oxide $C_{18}$ surfactant had DR of maximum 30% in fluid temperature of $80^{\circ}C$ and had 15% DR in fluid temperature over $100^{\circ}$ under short time test condition. And amine oxide had 155 hours duration time to keep the DR characteristic in the fluid temperature of $80^{\circ}$ and 1000 ppm concentration. But duration time of DR was decreased when fluid temperature increased.

Study on the Top-Gate Pentacene Thin Film ransistors Using Solution Processing Polymeric Gate Insulator (용액 공정 고분자 게이트 절연체를 이용한 Top-Gate 펜타센 박막 트랜지스터에 관한 연구)

  • Hyung, Gun-Woo;Kim, Jun-Ho;Seo, Ji-Hoon;Koo, Ja-Ryong;Seo, Ji-Hyun;Park, Jae-Hoon;Jung, Young-Ou;Kim, You-Hyun;Kim, Woo-Young;Kim, Young-Kwan
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.3
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    • pp.388-394
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    • 2008
  • 본 논문에서는 용액 공정을 이용한 고분자 절연층을 갖는 top-gate 구조의 펜타센 박막 트랜지스터(Thin Film Transistor, TFT)의 특성을 연구하였다. Top-gate 구조의 펜타센 TFT 제작에 앞서 유기 반도체인 펜타센의 결정성 성장을 돕기 위해서 가교된 PVP (cross-linked poly(4-vinylphenol))를 유리 기판 상에 스핀 코팅을 이용하여 형성한 후, 노광 공정을 통해 니켈/은 구조를 갖는 채널 길이 $10{\mu}m$의 소오스, 드레인 전극을 형성하였다. 그리고 열 증착을 이용하여 60 nm 두께의 펜타센 층을 성막하였고, 고분자 절연체로서 PVA(polyvinyl alchol) 또는 가교된 PVA를 용액공정인 스핀 코팅을 이용하여 형성한 후 열 증착으로 알루미늄 게이트 전극을 성막하였다. 이로써 제작된 소자들의 전기적 특성을 확인한 결과 가교된 PVA를 사용한 펜타센 TFT 보다 PVA를 게이트 절연체로 사용한 소자가 전기적 특성이 우수한 것으로 관찰되었다. 이는 PVA의 가교 공정에 의한 펜타센 박막의 성능 퇴화에 기인한 것으로 사료된다. 실험 결과 $0.9{\mu}m$ 두께의 PVA 게이트 절연막을 사용한 top-gate 구조의 펜타센 TFT의 전계 효과 이동도와 문턱전압, 그리고 전류 점멸비는 각각, 약 $3.9{\times}10^{-3}\;cm^2/Vs$, -11.5 V, $3{\times}10^5$으로써 본 연구에서 제안된 소자가 용액 공정형 top-gate 유기 TFT 소자로서 우수한 성능을 나타냄을 알 수 있었다.