• Title/Summary/Keyword: 열적환경

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Thermal Degradation Characteristics of Carbon Tetrachloride in Excess Hydrogen Atmosphere (과잉수소 반응조건하에서 사염화탄소의 고온 분해반응 특성 연구)

  • Won, Yang-Soo;Jun, Kwan-Soo;Choi, Seong-Pil
    • Journal of Environmental Science International
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    • v.5 no.5
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    • pp.569-577
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    • 1996
  • pure compound chloromethanes; methyl chloride, methylene chloride, chloroform and The carbon tetrachloride were used as a model of chlorocarbon system with Cl/H ratio to investigate thermal stability and hydrodechlorination process of carbon tetrachloride under excess hydrogen atmosphere. The parent thermal stability on basis of temperature required for 99% destruction at 1 second no was evaluated as $875^{\circ}C$ for $CH_3Cl$, $780^{\circ}C$ for $CH_2Cl_2$, $675^{\circ}C$ for $CHCl_3$ and $635^{\circ}C$ for $CCl_4$. Chloroform was thermally less stable than $CCl_4$ at fairly low temperatures $(<570^{\circ}C).$ The lion of $CCl_4$ became more sensitive to increasing temperature, and $CCl_4$ was degraded CHCl3 at above $570^{\circ}C.$ The number and quantity of chlorinated products decreases with increasing temperature for the Product distribution of $CCl_4$ decomposition reaction system. Formation of non-chlorinated hydrocarbons such as $CH_4$, $C_2H_4$ and C_2H_6$ increased as the temperature rise and particularly small amount of methyl chloride was observed above $850^{\circ}C$ in $CC1_4$/$H_2$ reaction system. The less chlorinated products are more stable, with methyl chloride the most stable chlorocarbon in this reaction system.

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Disposal of Polychlorinated Biphenyls(PCBs) by a Combined Chemical with Thermal Treatment (화학 및 열적 처리를 이용한 폴리염화바이페닐(PCB)의 제거)

  • Ryoo, Keon Sang
    • Journal of the Korean Chemical Society
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    • v.43 no.3
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    • pp.286-293
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    • 1999
  • A comnprehensive process which combines chemical with thermal treatment by controlled counterflow oxidation has been developed for disposal of PCBs in transformer oil. PCBs which not completely removed by chemical treatment, after being filtered with appropriate adsorbent during the oil circulations, was thermally treated. Destruction efficiencies of better than 99.99% was obtained, with no measurable formation of PCDDs (polychlorinated dibenzo-p-dioxins) or PCDFs (polychlorinated dibenzofurans). The combination also permits high recovery of oil and inorganic supports from scrap power transformers. The process is environmentally benign, easy to use and less capital intensive than other available technologies.

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Mass flow rate of Knudsen pump According to Membrane Type for Micro Propulsion Applications (초소형 추진장치에 적용을 위한 누센펌프의 멤브레인 종류에 따른 질유량 특성)

  • Kim, Hye-Hwan;Huh, Hwan-Il
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.11a
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    • pp.36-40
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    • 2008
  • Minimization of nozzle induces many flow losses in micro-propulsion system. In this study, we studied about thermal transpiration based new conceptual micro propulsion system to overcome these losses. Thermal transpiration device(Knudsen pump) having no moving parts can self-pump the gaseous propellant by temperature gradient only (cold to hot). We designed, fabricated the knudsen pump and analyzed pressure gradient efficiency of membrane according to Knudsen number under vacuum condition. In this paper, we compared mass flow rate of Knudsen pump by using different membrane type ; Polyimide and Hangi, Korean traditional paper.

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종이의 유전 특성 향상을 위한 표면 사이즈제의 열적 안정성 및 유동현상 평가

  • 이학래;서만석
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2001.11a
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    • pp.53-53
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    • 2001
  • 종이의 전기적 성질 가운데 유전율은 전기장에 대한 종이의 물리화학적인 반응으로 일반적으로 종이의 밀도와 종이를 구성하는 성분의 쌍극자 모멘트에 비례하며 온도에 따라서도 변화한다. 일반적으로 온도가 상승하면 열에너지를 얻게된 쌍극자가 전기장에 배열됨으로써 유전율이 상승하지만 온도가 유리전이점 이상으로 높아질 경우에는 열적 교란에 의해서 분극능력이 감소하게 되어 유전완화 현상이 나타난다. 전기절연지로 사 용될 종이의 절연특성을 이해하기 위해서는 사용환경에 따른 유전적 특성 및 tan 0에 관한 연구가 필요하며 필름형성능력이 우수한 polyvinyl a1cohoHPV A)와 acrylonitrile을 이용하여 시아노에틸화한 PYA의 표면처리에 의해 종이의 유전적 특성이 향상되었음을 기존의 연구를 통하여 확인할 수 있었다. 본 연구에서는 전기절연지가 사용되는 환경조건에서 PYA를 기본물질로하는 유전필름 의 열적 안정성을 평가하였으며, 아울러 표면사이징 공정에서의 적용성 검토를 위하여 용액의 유동특성을 분석하였다. 유전특성 향상을 위해서는 표면 사이즈제의 유도체화 과정에서 쌍극자 모벤트의 밀도 증가를 통한 유전율 향상이 요청되며 이와 동시에 네트원 구조를 통하여 전기장에 대 한 물리적 특성이 유지되어야 한다. 본 연구에서는 W AXD( wide angle x-ray diffraction)를 이용하여 시아노에틸화 반응 과 고온에서의 열화에 의한 필름의 결정화도를 평가하였으며 온도 상승에 따른 흡열 피크의 변화를 통하여 온도 변화에 따른 PYA 분자구조의 변화와 유리전이온도의 추이 를 분석하였다. 또 열화과정에서 수반되는 필름의 중량감소율을 평가함으로써 열안정성 을 평가하였다. 그 결과 시아노에틸화한 PYA가 안정된 분자구조를 유지하고 있음을 확인할 수 있었다. 시아노에틸화한 PYA용액의 점탄성 평가를 위하여 storage modulus와 loss modulus 를 분석하였다. 일반적 유변특성 평가 결과 PYA용액은 shear-thinning, pseudoplastic 한 특성을 나타내어 표면사이즈 공정에서의 적용 가능성을 확인할 수 있었다.

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Thermal and Vibration Analysis of TR Module Structural Model for Environmental Test Evaluation (환경시험 평가를 위한 TR 모듈 구조모델의 열/진동 해석)

  • Dong-Seok Kang;Jong-Pil Kim;Yuri Lee;Sung-Woo Park;Jin-Ho Roh
    • Journal of Aerospace System Engineering
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    • v.18 no.4
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    • pp.96-101
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    • 2024
  • The Synthetic Aperture Radar (SAR) is equipped with a Transmitter/Receiver (TR) module, which serves as the signal transmission and reception unit for acquiring image data. The TR module generates significant heat during signal generation and amplification, potentially degrading performance or causing mission failure. Furthermore, launch and operational environments may result in structural damage to the components. Thus, assessing the thermal and structural safety of the TR module through thermal and vibration tests is essential to guarantee its safety. Safety assessments can be verified through environmental tests prescribed in MIL-STD-883. This paper explores the thermal and structural safety characteristics of the TR module by simulating test environments using finite element analysis prior to conducting environmental tests.

An Investigation in the Thermal Effect on a Low Earth Orbit Satellite under Yaw Motion for the Visibility of a Star Sensor (저궤도 위성에서 별센서의 가시성을 위한 Yaw Motion에 따른 열적 영향 고찰)

  • Kim, Hui-Kyung;Lee, Jang-Joon;Hyun, Bum-Seok
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.37 no.7
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    • pp.709-716
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    • 2009
  • Thermal condition according to the operation attitude of a satellite in orbit would be essential to be known because the orbit attitude is a dominant factor to affect satellite thermal design. In this paper, the change in space thermal environment and the thermal effect in thermal design are studied for a low earth orbit satellite according to the yaw motion. The present satellite retains sun-pointing attitude during daylight due to the fixed type solar arrays. And it also moves along the orbit with constant yaw motion in a longitudinal axis so that a star tracker which is a star sensor for satellite's attitude control always looks into the deep space. This attitude is considered in its better visibility to the stars for a successful mission operation. Also, it is required to access the corresponding thermal effects due to the yaw motion. Therefore, we try to verify these by the thermal analysis for the satellite thermal model with the yaw motion.

A Study on Thermally-Induced Vibration of Flexible Space Structures (유연 우주구조물의 열적 유기 진동에 관한 연구)

  • Gong, Chang-Deok;O, Gyeong-Won;Y.Sugiyama
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.31 no.9
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    • pp.46-54
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    • 2003
  • The purpose of this study is to analyze the phenomena of the thermally-induced vibration for the flexible space structure due to abrupt change of radiation heating circumstance using the numerical analyze and experiment test. In order to verify this structure, numerical approaches on the simplified flexible tube were compared with experimental test results at the ground experimental facility. In this analyze, it was found that the thermal deformation occurs firstly due to fast radiation heating of flexible structure and then the thermally-induced vibration would be induced due to small periodic change of temperature. According to comparison of numerical and experimental results, in case of no tip mass, the first mode vibration by the numerical analyze was a.78Hz same as that of the experimental result. However in case of increase tip-masses of 8g, 16g, 50g and 100g, the first modes vibration theoretical analyze were 1.75Hz, I.3Hz, a.87Hz and 0.73Hz, in decrease trend respectively and those by experimental test were 2.34Hz, 1.5Hz, 0.78Hz and 0.78Hz in decrease trend respectively. Although using the simpled equation for the estimation, the estimation results were similar to experimental results.

A Study on Thermal Characteristics of Biodiesel (바이오디젤의 열적특성에 관한 연구)

  • Bae, Byong-Mok;Lim, Woo-Sub;SaKong, Seong-Ho;Mok, Yun-Soo;Choi, Jae-Wook
    • Journal of the Korean Society of Safety
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    • v.25 no.6
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    • pp.92-97
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    • 2010
  • A study is conducted on thermal characteristics of biodiesel which is already being produced in many countries because of its stable supply of energy in non oil-producing countries and economical benefits against increasing oil price, and environment conservation. So biodiesel has been used as important energy source in the fuel fields and a mount of production has increased year by year. Therefore, it is very important to find out the thermal characteristics of biodiesel for ignition temperature, maximum pressure and thermal behavior. The purpose of this study is to compare on thermal characteristics of biodiesel, petroleum diesel and those mixtures. Also, the main study was performed by flash point testers and modified closed type of pressure vessel test (MCPVT). Based on the data of flash point and MCPVT, the ignition temperature and the maximum pressure of biodiesel was $182^{\circ}C$ and 40.1bar, and petroleum diesel was $54^{\circ}C$ and 29.8bar.

A Study on the Effective Method for Linking Time Series Triangulation Points (시계열 삼각점의 효율적인 연계방안에 대한 연구)

  • Kyung, Myoung Yeol;Song, Yeong Sun;Park, Kyeong Sik
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.36 no.4
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    • pp.235-243
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    • 2018
  • The national geodetic control point is very important as a framework for drafting plans for construction and civil engineering works as well as mapping for various development and utilization plans related to the national land. Since the 1910s, Korea has established and managed the national geodetic control points, the triangulation points and the benchmarks. Currently, these point information is provided through the land information platform. The national geodetic control point has been changed through the process of loss, re-establishment, and re-location by the events and environment of the times. Therefore, it is very important to provide information by linking these past national geodetic control points in time series. In this study, we classified the triangulation points into five groups(Japanese Government General of Korea, YUCCA Project, National Construction Institute, Past Control Point Data Sheet, and Current) by age and then suggests a method to match the same control points in each time period. Finally we also applied the proposed method to Jecheon and analyzed the results.

Thermal Performance and Impact Resistance Evaluations of Composite Insulation Mat Reinforced Polyurethane Foam (복합 단열 매트 보강 폴리우레탄 폼의 열적 성능 및 내충격성 평가)

  • Hwang, Byeong-Kwan;Bae, Jin-Ho;Lee, Jae-Myung
    • Composites Research
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    • v.32 no.5
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    • pp.290-295
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    • 2019
  • In the present study, composite insulation mat was reinforced over polyurethane foam (PUF) to improve the thermal performance and impact resistance of the PUF applied to the liquefied natural gas carrier insulation system. The composite insulation mat used Kevlar, aerogel, and cryogel composite mat that can be applied in a cryogenic environment. The thermal conductivity was measured at $20^{\circ}C$ to investigate the thermal performance, and the drop impact test was carried out under impact energy of 30 J at $20^{\circ}C$, $-163^{\circ}C$ to investigate the impact resistance. The measured thermal performance was compared with neat PUF through effective thermal conductivity theoretical value. The shock resistance was evaluated of contact force, contact time, and absorb energy. In experimental results, cryogel composite mat was the best performance in terms of thermal performance, and aerogel composite mat was the best performance in terms of impact resistance.