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The Experimental Study on the Heat Hydration Properties of Concrete According to Binder Conditions (결합재 조건에 따른 콘크리트의 수화발열 특성에 관한 연구)

  • Choi, Sung-Woo;Jo, Hyun-Tae;Ryu, Deuk-Hyun
    • Journal of the Korea Concrete Institute
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    • v.18 no.6 s.96
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    • pp.769-776
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    • 2006
  • Recently, owing to the development of industry and the improvement of building techniques, concrete structures are becoming larger and higher. In hardening of these large connote structures, the heat of hydration gives rise to considerable thermal stress depending on the size and environmental condition of concrete, which might cause thermal cracking. Especially, the crack may cause severe damage to the safety and the durability of concrete structure. This study investigates the thermal properties of concrete according to several binder conditions, such as OPC, Belite rich cement(BRC), slag cement(SC), blast furnace slag(B) added cement fly ash(F) added cement and blast-furnace-slag and fly ash added cement. As a result of this study, the properly of concrete is most better BRC than others, and fly ash(25%) added cement and BFS(35%)-fly ash(15%) added cement gets superior effect in the control of heat hydration. But synthetically considered properties of concrete, workablity, strength heat hydration, etc, it is more effective to use mineral admixture. Especially, to be used Blast Furnace slag is more effective.

A Study on the Electric and Ferroelectric Properties of PZT(30/70) Thick Film Prepared by Using 1,3-Propanediol (1, 3-Propanediol 을 이용해 제작된 PZT(30/70) 후막의 전기적 및 강유전 특성에 관한 연구)

  • 송금석;장동훈;강성준;윤영섭
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.40 no.9
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    • pp.631-637
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    • 2003
  • We have evaluated structural and electric, ferroelectric properties of PZT(30/70) thick film prepared by using 1,3-propanediol based sol-gel method on Pt/Ti/SiO$_2$/Si substrates. Rapid thermal annealing (RTA) is used to reduce the thermal stress and final furnace annealing is processed at $650^{\circ}C$. As the results of SEM analysis, we find that we get 350 nm in thickness for one coating and 1 $\mu$m for three times of coating. In the results of C-D analysis at 1 kHz, dielectric constant ($\varepsilon$$_{r}$) and dissipation factor were 886 and 0.03, respectively. C-V curve is shaped as a symmetrical butterfly. Leakage current density at 200 kV/cm is 1.23${\times}$10$^{-5}$ A/cm$^2$ and in the results of hysteresis loops measured at 150 kV/cm, the remnant polarization (P$_{r}$) and the coercive field (E$_{c}$) are 33.8 $\mu$C/cm$^2$ and 56.9 kV/cm, respectively. PZT(30/70) thick film exhibits relatively good ferroelectric, electric properties.s..

A Study on the Geometric Design Parameters for Optimization of Cooling Device in the Magnetocardiogram System (심자도 장비의 냉각장치 특성 최적화를 위한 기하 설계 변수 연구)

  • Lee, Jung-Hee;Lee, Young-Shin;Lee, Yong-Ho;Lim, Hyun-Kyoon;Lee, Sung-Jin
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.2
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    • pp.153-160
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    • 2010
  • A magnetocardiogram (MCG) is a recording of the biomagnetic signals generated by cardiac electrical activity. Biomagnetic instruments are based on superconducting quantum interference devices (SQUIDs). A liquid cryogenic Dewar flask was used to maintain the superconductors in a superconducting state at a very low temperature (4 K). In this study, the temperature distribution characteristics of the liquid helium in the Dewar flask was investigated. The Dewar flask used in this study has a 30 L liquid helium capacity with a hold time of 5 d. The Dewar flask has two thermal shields rated at 150 and 40 K. The temperatures measured at the end of the thermal shield and calculated from the computer model were compared. This study attempted to minimize the heat transfer rate of the cryogenic Dewar flask using an optimization method about the geometric variable to find the characteristics for the design geometric variables in terms of the stress distribution of the Dewar flask. For thermal and optimization analysis of the structure, the finite element method code ANSYS 10 was used. The computer model used for the cryogenic Dewar flask was useful to predict the temperature distribution for the area less affected by the thermal radiation.

Characterization for Viscoelasticity of Glass Fiber Reinforced Epoxy Composite and Application to Thermal Warpage Analysis in Printed Circuit Board (유리섬유강화 복합재의 점탄성 특성 규명 및 인쇄회로기판 열변형해석에의 적용)

  • Song, Woo-Jin;Ku, Tae-Wan;Kang, Beom-Soo;Kim, Jeong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.2
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    • pp.245-253
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    • 2010
  • The reliability problems of flip chip packages subjected to temperature change during the packaging process mainly occur due to mismatches in the coefficients of thermal expansion as well as features with time-dependent material properties. Resin molding compounds like glass fiber reinforced epoxy composites used as the dielectric layer in printed circuit boards (PCB) strongly exhibit viscoelastic behavior, which causes their Young's moduli to not only be temperature-dependent but also time-dependent. In this study, the stress relaxation and creep tests were used to characterize the viscoelastic properties of the glass fiber reinforced epoxy composite. Using the viscoelastic properties, finite element analysis (FEA) was employed to simulate thermal loading in the pre-baking process and predict thermal warpage. Furthermore, the effect of viscoelastic features for the major polymeric material on the dielectric layer in the PCB (the glass fiber reinforced epoxy composite) was investigated using FEA.

Out-of-Pile Test for Yielding Behavior of PWR Fuel Cladding Material (노외 실험을 통한 가압경수형 핵연료 피복재의 항복거동연구)

  • Yi, Jae-Kyung;Lee, Byong-Whi
    • Nuclear Engineering and Technology
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    • v.19 no.1
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    • pp.22-33
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    • 1987
  • The confirmed integrity of nuclear fuel cladding materials is an important object during steady state and transient operations at nuclear power plant. In this context, the clad material yielding behavior is especially important because of pellet-clad gap expansion. During the steep power excursion, the in-pile irradiation behavior differences between uranium-dioxide fuel pellet and zircaloy clad induce the contact pressure between them. If this pressure reaches the zircaloy clad yield pressure, the zircaloy clad will be plastically deformed. After the reactor power resumed to normal state, this plastic permanent expansion of clad tube give rise to the pellet-clad gap expansion. In this paper, the simple mandrel expansion test method which utilizes thermal expansion difference between copper mandrel and zircaloy tube was adopted to simulate this phenomenon. That is, copper mandrel which has approximately three times of thermal expansion coefficient of zircaloy-4 (PWR fuel cladding material) were used in this experiment at the temperature range from 400C to 700C. The measured plastic expansion of zircaloy outer radius and derived mathematical relations give the yield pressure, yield stress of zircaloy-4 clad at the various clad wall temperatures, the activation energy of zircaloy tube yielding, and pellet-clad gap expansion. The obtained results are in good agreement with previous experimental results. The mathematical analysis and simple test method prove to be a reliable and simple technique to assess the yielding behavior and gap expansion measurement between zircaloy-4 tube and uranium-dioxide fuel pellet under biaxial stress conditions.

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The Formation of Serrated Grain Boundaries and Its Influence on Boron Segregation and Liquation Behavior (파형 결정립계 생성이 보론 편석 및 액화거동에 미치는 영향)

  • Hong, H.U.;Kim, I.S.;Choi, B.G.;Yoo, Y.S.;Jo, C.Y.
    • Proceedings of the KWS Conference
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    • 2010.05a
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    • pp.73-73
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    • 2010
  • 합금원소가 다량 첨가된 고합금강, 스테인리스강, Ni기 초내열합금 등은 용접시 혹은 후열처리 동안 열영향부 (HAZ: heat-affected-zone)에서 결정립계를 따라서 액화균열이 종종 발생한다. 이러한 액화균열은 급속한 가열시 HAZ의 결정립계가 국부적으로 용융되어 액상필름을 형성하고, 냉각시 수축으로 인한 인장구속응력에 의해 필름을 따라서 균열이 발생하여 생성된다. HAZ 결정립계 액화는 탄화물, 황화물, 인화물, 보론계 화합물 등이 급가열시 기지와의 반응에 의해 표피 액상을 형성하는 조성적 액화 (constitutional liquation)에 의한 액상의 결정립계 침투로 설명되거나, 결정립계 자체의 용융점을 상당량 낮추는 보론(B), 인(P), 황(S)등의 편석에 의한 국부적 입계 용융으로 주로 연관 지어 해석한다. HAZ 액화균열은 고온 입계균열 현상이므로, 결정립계의 특성에 따라 크게 영향을 받으며 결정립계 character 설계에 의해 액화균열 저항성을 개선시킬 수 있음을 유추할 수 있다. 한편, 본 연구자들은 최근 Ni기 초내열합금에 있어 입계 serration 현상을 새롭게 발견하였으며, 이론적 접근법을 통해 serration을 위한 특별한 열처리 방법을 개발하였다. 형성된 파형입계는 결정학적인 관점에서 조밀 {111} 입계면을 갖도록 분해 (dissociation)되어 낮은 계면에너지를 갖게 됨을 확인하였으며, 입계형상 변화뿐만 아니라 탄화물 특성변화까지 유도하여 크리프 수명을 기존대비 약 40% 정도 향상시킴을 확인하였다. 본 연구에서는 이러한 직선형 입계 대비 'special boundary'로 간주되는 파형입계가 도입될 경우, 보론 편석 및 HAZ 액화거동에 미치는 영향을 고찰하고자 하였다. SIMS (secondary ion mass spectrometry)를 이용하여 열처리 직후 결정립계 보론편석 정도를 비교하였다. 파형입계 시편의 경우, 일반직선형 시편에 비해 결정립계에 보론편석 저항성이 우수함을 확인할 수 있었다. 재현 HAZ 열사이클 시험을 통해 미세조직을 정량적으로 분석하였다. 파형입계 시편 및 일반직선형 시편 모두 최고온도 $1060^{\circ}C$이상부터 입계 탄화물이 기지내로 완전 용해되고 입계가 액화되기 시작하였다. 최고온도별로 입계액화비율을 정량적으로 비교한 결과, 파형입계가 직선입계 대비 훨씬 낮음을 확인할 수 있었으며, 때때로 액화된 필름이 입계를 따라 전파되지 않고 부분적으로 단락되어 있음이 관찰되었다. 액화시험 후 투과전자현미경을 이용한 EDS (energy dispersive spectrometry) 분석을 통해 결정립계 액화의 주요원인은 입계 $M_{23}C_6$의 조성적 액화반응 보다는 보론 편석 (원자 및 $M_{23}(CB)_6$)으로 인한 결정립계 국부용융이 더 유력함을 유추할 수 있었다. 따라서 상기 결과로부터 입계구조가 안정되어 계면에너지가 낮은 파형입계가 보론편석에 대한 저항성이 우수하였으며, 이러한 결과는 액화 저항성에 대응되어 영향을 미침을 알 수 있었다. 게다가 파형입계에 액상 필름이 생성되더라도 낮은 계면에너지에 의해 비롯된 상대적으로 낮은 적심성 (wettability)에 의해 필름이 쉽게 전파되지 않음을 'Smith 입계 wetting 이론'을 이용하여 해석할 수 있었다.

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Evaluation of Properties of 80, 130, 180 MPa High Strength Concrete at High Temperature with Heating and Loading (고온가열 및 하중재하에 따른 80, 130, 180 MPa 초고강도콘크리트의 역학적특성평가)

  • Choe, Gyeong-Cheol;Yoon, Min-Ho;Lee, Tae-Gyu;Lee, Seong-Hun;Kim, Gyu-Yong
    • Journal of the Korea Concrete Institute
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    • v.25 no.6
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    • pp.613-620
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    • 2013
  • Concrete has been recognized as a material which is resistant to high temperatures, but chemicophysical property of concrete is changed by the high temperature. So, mechanical properties of concrete may be reduced. Because of this, standards and researches on the degradation of the mechanical properties of concrete at high temperatures have been presented. However, research data about the state that considering the loading condition and high-strength concrete is not much. Therefore, this study evaluated the high-temperature properties of high-strength concrete by loading condition and elevated temperature. The stress-strain, strain at peak stress, compressive strength, elastic modulus, thermal strain and the transient creep are evaluated under the non-loading and $0.25f_{cu}$ loading conditions on high strength concrete of W/B 12.5%, 14.5% and 20%. Result of the experiment, decrease in compressive strength due to high temperature becomes larger as the compressive strength increases, and residual rate of elastic modulus and compressive strength is high by the shrinkage caused by loading and thermal expansion due to high temperature are offset from each other, at a temperature above $500^{\circ}C$.

Behavior of Shear Strength of Coarse Grained Materials Based on Large Scale Direct Shear Test (I) (대형직접전단시험을 이용한 조립재료의 전단거동 특성 (I))

  • Lee Dae-Soo;Kim Kyoung-Yul;Hong Sung-Yun;Jo Hwa-Kyung;Whang Sung-Chun
    • Journal of the Korean Geotechnical Society
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    • v.21 no.6
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    • pp.81-91
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    • 2005
  • 'Coarse grained material' refers to crushed stones or gravels, and the behaviour of soil containing coarse grained material is not easily defined using the conventional soil mechanics theory due to the influences of large particles, therefore large scale test is essential to investigate their effects. Previous studies have identified the major factors affecting the properties of coarse grained materials by using large scale shear testing apparatus, such as maximum particle size, water content, density and uniformity coefficients. In this paper, the effect of variation of maximum particle size and water content on shear strength was analyzed from the results of large scale shear test. In addition, the fiction coefficient at critical state per vertical load was estimated using the equation proposed by Wood (1998). The sample for the test was obtained from the local quarry sites. Tests results show that the shear strength for 50.8 m maximum particle size is relatively larger than that of 76.3 m and air-dry sample has larger shear strength than saturated sample. In the meantime, the friction coefficient at critical state shows $1.0\sim1.6$ according to the test conditions.

Anti-amnesic Effect of Eriobotrya japonica Leaf Extract on Scopolamine-induced Memory Impairment in Rats (Scopolamine으로 유도된 기억력 손상 동물모델에서 비파엽 추출물의 학습 및 기억력 개선 효과)

  • Bae, Donghyuck;Kim, Jihye;Na, Ju-Ryun;Kim, Yujin;Lee, Joon-Yeol;Kim, Sunoh
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.43 no.6
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    • pp.799-806
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    • 2014
  • The present study was conducted to evaluate the effects of extract from Eriobotrya japonica leaves (EJE) on cognitive impairment induced by scopolamine, a muscarinic antagonist, in rats. Scopolamine injection (1 mg/kg, i.p.) impaired performance in rats in the passive avoidance test as well as in water maze test and severely reduced cholinergic system reactivity, as indicated by reduced acetylcholine levels and increased acetylcholinesterase activity. Daily administration of EJE significantly increased step-through latency in the passive avoidance test, reduced escape latency, and increased time spent in the platform quadrant in the Morris water maze test. EJE protected against scopolamine-induced cholinergic system deficit, including reduced acetylcholine levels and increased acetylcholinesterase activity in whole brain homogenates. These results suggest that EJE provides a significant anti-amnesic effect against scopolamine-induced cholinergic system deficits and cognitive impairment.

Assessment of the Damage in High Performance Fiber-Reinforced Cement Composite under Compressive Loading Using Acoustic Emission (AE기법에 의한 압축력을 받는 고인성 섬유보강 시멘트 복합체의 손상 평가)

  • Kim, Sun-Woo;Yun, Hyun-Do
    • Journal of the Korea Concrete Institute
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    • v.21 no.5
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    • pp.589-597
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    • 2009
  • High Performance Fiber-reinforced Cement Composite (HPFRCC) shows the multiple crack and damage tolerance capacity due to the interfacial bonding of the fibers to the cement matrix. For practical application, it is needed to investigate the fractural behavior of HPFRCC and understand the micro-mechanism of cement matrix with reinforcing fiber. This study is devoted to the investigation of the AE signals in HPFRCC under monotonic and cyclic uniaxial compressive loading, and total four series were tested. The major experimental parameters include the type and volume fraction of fiber (PE, PVA, SC), the hybrid type and loading pattern. The test results showed that the damage progress by compressive behavior of the HPFRCC is a characteristic for the hybrid fiber type and volume fraction. It is found from acoustic emission (AE) parameter value, that the second and third compressive load cycles resulted in successive decrease of the amplitude as compared with the first compressive load cycle. Also, the AE Kaiser effect existed in HPFRCC specimens up to 80% of its ultimate strength. These observations suggested that the AE Kaiser effect has good potential to be used as a new tool to monitor the loading history of HPFRCC.