• Title/Summary/Keyword: 열역학적 상태량

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A Comparative Study of Single Component Thermophysical Properties using the Real Gas Equation of State at Supercritical Conditions (초임계 영역에서 실제 기체 상태 방정식에 따른 단일 성분의 열역학적 상태량 비교 연구)

  • Kim, Kuk-Jin;Heo, Jun-Young;Kim, Jong-Chan;Koo, Ja-Ye;Sung, Hong-Gye
    • Journal of the Korean Society of Propulsion Engineers
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    • v.14 no.3
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    • pp.39-51
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    • 2010
  • Theoritical principles about the real gas equation of state are investigated and comparisons for the thermophysical properties of oxygen, hydrogen, and methane as the propellants of liquid rocket engine are carried out for the various conditions of pressure and temperature including supercritical conditions. The properties obtained using the real gas equation of state(Soave modification of Redlich-Kwong, Peng-Robinson equation of state, and extended corresponding states principle) have been compared with the results of applying the ideal gas equation of state. Differences of thermophysical properties among the models specifically at the liquid phase regime and their error ranges are addressed.

Investigation of Thermophysical Properties of the Kerosene Using the Surrogate Model Fuel at Supercritical Conditions (초임계 영역에서 대체 모델 연료를 이용한 케로신의 열역학적 상태량 연구)

  • Kim, Kuk-Jin;Heo, Jun-Young;Sung, Hong-Gye
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.38 no.8
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    • pp.823-833
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    • 2010
  • For the study of thermophysical properties of kerosene for the liquid rocket and aviation fuels, the surrogate models are investigated. The density distributions based on the real gas equations of state(Soave modification of Redlich-Kwong and Peng-Robinson equation of state) and NIST SUPERTRAPP(extended corresponding state principle) are compared with the previous experimental results at supercritical conditions. The error range of thermophysical properties analyzed for the surrogate models as well. Peng-Robinson equation of state and extended corresponding state principle are especially accurate for the hydrocarbon fuels but the appropriate surrogate models need to be chosen to the operation conditions such as pressure and temperature.

Estimation of Thermodynamic/Transport Properties of Kerosene using a 3-Species Surrogate Mixture (3-화학종 대체 혼합물을 이용한 케로신의 열역학적·전달 상태량 예측)

  • Joh, Miok;Kim, Seong-Ku;Choi, Hwan-Seok
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.41 no.11
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    • pp.874-882
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    • 2013
  • Kerosene(Jet A-1), one of the propellants for each stage's engine of the Korea Space Launch Vehicle-II(KSLV-II), functions as coolant at the same time as it flows inside the cooling jacket of the combustion chambers and is injected through the film cooling holes. A physical surrogate mixture model to reproduce the thermophysical characteristics of Jet A-1 has been selected and the thermodynamic/transport properties of the model fuel under high pressure including supercritical conditions have been estimated using SUPERTRAPP(NIST SRD4). Comparisons with the measured properties suggest that proposed database can be used to extract properties of Jet A-1 for conjugate heat transfer analysis of liquid propellant rocket engine thrust chambers. Predicted combustion/cooling performance of regeneratively cooled thrust chambers shall be validated through comparisons with upcoming firing test results.

Application of Procedures to Calculate Thermodynamic Properties of Carbon Dioxide, HFC-l34a and HCFC-22 (이산화탄소, HFC-l34a, HCFC-22의 열역학적 상태량 계산 절차의 응용)

  • 박형준;박경근
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.5
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    • pp.389-396
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    • 2003
  • Systematic methods to calculate thermodynamic properties of carbon dioxide, HFC-l34a and HCFC-22 are presented. First, application of a basic method to identify the saturation state with given temperature or pressure is attempted and the feasibility of auxiliary equations is tested. Next, detailed procedures are suggested to tell a phase when temperature/pressure and another property are specified. Finally Newton-Raphson method is applied to calculate unknown thermodynamic properties fixing the state with the two independent properties specified. The procedures described here are utilized to develop a computer program, which is used to find the relation between temperature and pressure with maximum isobaric heat capacity for super-critical carbon dioxide.

Development of a Computer Program to Calculate Thermodynamic Properties of Nitrogen (질소의 열역학 상태량 계산을 위한 전산 프로그램 개발)

  • Park, Kyoung-Kyhn
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.1667-1671
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    • 2003
  • A computer program to calculate properties of nitrogen is developed. Procedures for the calculation is briefly discussed. The program calculates unknown thermodynamic properties fixing the state with two independent input properties. If input value by user is inappropriate, it displays an error message and replaces the input value with an appropriate one. In addition user can change units with easy. The program developed in this work can be utilized to calculate parameters required for the simulation and design of an equipment using nitrogen.

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Development of a Computer Program to Calculate Thermodynamic Properties of Oxygen (산소의 열역학 상태량 계산을 위한 전산 프로그램 개발)

  • Park, Kyoung-Kuhn
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.256-260
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    • 2003
  • A computer program to calculate thermodynamic properties of oxygen is developed. Procedures for the calculation is briefly discussed. The program calculates unknown thermodynamic properties fixing the state with two independent input properties. If input value by user is inappropriate, it displays an error message. In addition user can change units with easy. The program developed in this work can be utilized to calculate parameters required for the simulation and design of an equipment using oxygen.

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Die Anwendung Elektronischer Rechenanlagen in der Kaltetechnik (냉동공학에 있어서의 전자계산기의 응용)

  • Scholten Dipl.-Ing. W.
    • The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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    • v.1 no.1
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    • pp.47-50
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    • 1972
  • Farbwerke Hoechst 주식회사는 냉매 11, 12, 13 및 13B1의 열역학적 상태량(Thermodynamic Properties)을 결정하는 컴퓨터 프로그램밍을 가능케 하였다. 이들 프로그램밍은 냉동계산의 체계안에서 서브루우틴으로써 사용될 수 있다.

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Transient State Theory of Significant Liquid Structure applied to Cyclohexane (액체구조에 관한 천이상태이론의 싸이클로 핵산에 대한 적용)

  • Lee, Hai-Bang;Chang, Sei-Hun
    • Journal of the Korean Chemical Society
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    • v.10 no.3
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    • pp.129-132
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    • 1966
  • It is known that almost all cyclohexane molecules are chair form in liquid state. Therefore, only chair form is considered in formulating the partition function for liquid cyclohexane, according to the Transient State Theory of Significant Liquid Structure proposed by Pak, Ahn and Chang. The thermodynamic quantities such as molar volume, vapor pressure, entropy of vaporization and compressibility of the liquid are calculated. The results are in good agreement with experimental values.

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An Equation of State for the PVT Behavior of Gaseous Refrigerants (기체냉매의 PVT 거동을 나타내기 위한 상태방정식)

  • Park, K.;Sonntag, R.E.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.7 no.1
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    • pp.98-111
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    • 1995
  • The objective of this work is to investigate the form of equations of state for specific refrigerants. In particular, equations of the extended van der Waals form have been studied. As a result, a new equation of state has been developed and tested over ranges of pressure and density up to 5 and 1.5 times critical, respectively. The equation of state separates the compressibility factor into two parts. One is the repulsive compressibility factor and the other is attractive. The former is in the same form of Carnahan-Starling's repulsive term with constant hard-sphere volume. The latter is based on a combination of two different functions linear to density. The equation of state developed here has 12 adjustable parameters and correlates PVT data successfully. All properties are in reduced forms.

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Study on the safety analysis method based on thermodynamic characteristics analysis for high capacity and high power lithium battery (고용량/고출력 리튬 이차 전지의 열역학적 특성 분석 기반의 안전성 분석 방법에 대한 연구)

  • Kang, Deokhun;Kim, Kyungjin;Kim, Sungkeun;Kim, Jonghoon
    • Proceedings of the KIPE Conference
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    • 2020.08a
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    • pp.37-39
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    • 2020
  • 리튬이온 배터리는 동작하는 과정에서 필연적으로 열이 발생하기 때문에 적절한 열 관리에 대한 전략이 필요하다. 배터리에서의 발열은 가역적인 발열과 비가역적인 발열로 분류될 수 있으며 배터리의 용도별, 동작 조건 별 발열 특성이 상이하기 때문에, 배터리의 열적 안전성 확보를 위해서는 열적 특성에 대한 분석이 필수적이다. 본 연구에서는 고용량/고출력 리튬이온 배터리의 전기적 특성 실험을 수행하고 열적 안전성 분석을 위하여 발열 특성 분석을 수행하였다. 고용량/고출력 배터리 특성에 따라 가역적 발열과 비가역적 발열이 나타나는 특성이 상이한 것으로 확인되었으며, 또한 온도 측정 정보로부터 배터리의 내부 상태 특성을 추정하고 고장 진단 및 수명 특성에 활용될 수 있음을 확인하였다.

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