• Polymer(Korea)
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• v.26 no.6
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• pp.737-744
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• 2002

Thermodynamic miscibility of the binary blends composed of semi-crystalline poly (butylene 2,6-naphthalate) (PBN) and amorphous poly (4-vinylphenol) (PVPh) was investigated using differential scanning calorimetry (DSC) and Fourier transform infrared (FTIR) spectroscopy. DSC scan results showed that there was a single glass transition temperature (T$\_$g/) for each blend. Crystalline melting temperature (T$\_$m/) depression of the PBN in the blends was also observed with the increase of PVPh content. Both results of the single T$\_$g/ and the depression of T$\_$m/ for the PBN/PVPh blends indicate that the blends are thermodynamically miscible at the molecular level. FTIR spectroscopic analysis confirmed that strong intermolecular hydrogen bonding interactions between the ester carbonyl groups of the PBN and the hydroxyl groups of the PVPh are occurred.

• KDI Journal of Economic Policy
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• v.14 no.1
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• pp.121-145
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• 1992

This paper examines characteristics of time series data related to the construction investment(stationarity and time series components such as secular trend, cyclical fluctuation, seasonal variation, and random change) and surveys predictibility, fitness, and explicability of independent variables of various models to build a short-term construction investment forecasting model suitable for current economic circumstances. Unit root test, autocorrelation coefficient and spectral density function analysis show that related time series data do not have unit roots, fluctuate cyclically, and are largely explicated by lagged variables. Moreover it is very important for the short-term construction investment forecasting to grasp time lag relation between construction investment series and leading indicators such as building construction permits and value of construction orders received. In chapter 3, we explicate 7 forecasting models; Univariate time series model (ARIMA and multiplicative linear trend model), multivariate time series model using leading indicators (1st order autoregressive model, vector autoregressive model and error correction model) and multivariate time series model using National Accounts data (simple reduced form model disconnected from simultaneous macroeconomic model and VAR model). These models are examined by 4 statistical tools that are average absolute error, root mean square error, adjusted coefficient of determination, and Durbin-Watson statistic. This analysis proves two facts. First, multivariate models are more suitable than univariate models in the point that forecasting error of multivariate models tend to decrease in contrast to the case of latter. Second, VAR model is superior than any other multivariate models; average absolute prediction error and root mean square error of VAR model are quitely low and adjusted coefficient of determination is higher. This conclusion is reasonable when we consider current construction investment has sustained overheating growth more than secular trend.

• Fire Science and Engineering
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• v.15 no.1
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• pp.108-115
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• 2001

In this paper, we analyzed the properties change of electric wire when the thermal stress was applied to 600V grade polyvinyl chloride insulated wire (IV). In the structure analysis, normal wire has the properties of direction on the surface, but in case of deteriorated wire at above $400^{\circ}c$, it formed the carbide, the crack and the crystal. The surface composition rate of normal wire was Cu : 100%, but the section composition of the deteriorated wire at $800^{\circ}c$ showed Cu : 78.89%, O : 21.11%. In result of analyzing the differential scanning calory of copper wire, the new reaction peak was observed on the deteriorated wire at above $700^{\circ}c$. In case of the deteriorated wire as $150^{\circ}c$ at the differential thermal analysis, an endothermic reaction appeared at $264^{\circ}c$ lower than the reactive point of normal wire. The occupation rate of oxygen according to the deterioration of copper wire is about 20% at $500^{\circ}c$.

• International Journal of Highway Engineering
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• v.4 no.3 s.13
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• pp.35-42
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• 2002

Many temperature-related problems are created in asphalt pavement due to the low temperature. In particular, loss of tensile strength due to low temperature is known to be responsible for thermal failure of pavements in cold regions under $-20^{\circ}C$. The objective of this study is to evaluate characteristics of resistance against low-temperature cracking of polymer asphalt concrete mixtures modified with LDPE and SBS. The test results showed that the mixtures had the maximum indirect tensile strength(ITS) at low temperature ranging from $-10^{\circ}C. It was proved through ITS test that the stress due to differential thermal contraction over the tensile strength did generate internal damage at the temperature below $-20^{\circ}C$. It was shown that the asphalt mixtures modified with polymer had better ITS than the normal asphalt mixture at the temperature below $-20^{\circ}C$. Thus the effect of modification was revealed as tensile strength improvement. From the results of this study, it was recommended that polymer-modified asphalt should be used in order to prevent low-temperature cracking in cold region.

• Environmental and Resource Economics Review
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• v.24 no.4
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• pp.629-655
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• 2015

Nuclear power generation is a major power source which accounts for more than 30% of domestic electricity generation. Electricity market needs to secure stability of base load. This study aimed at analyzing relationships between nuclear power generation and wholesale electricity price (SMP: System Marginal Price) in Korea. For this we conducted ARDL(Autoregressive Distributed Lag) approach and Granger causality test. We found that in terms of total effects nuclear power supply had a positive relationship with SMP while nuclear capacity had a negative relationship with SMP. There is a unidirectional Granger causality from nuclear power supply to SMP while the reverse was not. Nuclear power is closely related to SMP and provides useful information for decision making.

• Journal of the Korean Society of Propulsion Engineers
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• v.24 no.3
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• pp.41-46
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• 2020

In this study, measurement and analysis results from Differential scanning calorimetry(DSC) and Thermogravimetric analysis(TGA) on the newly developed high-energy thermoplastic elastomer(ETPE) propellant are described, followed by the previous study done under the same title as this paper [1]. The characteristics of high-energy thermoplastic propellant were also verified by conducting thermal analysis, and the LSGT, Shotgun & RQ Bomb test, was carried out as well. High energetic thermoplastic binders containing 45% of GAP(Glycidyl Azide Polymer), energetic plasticizer(DEGDN) and Oxidizer Aonium Perchlorate), RDX(reseach development explosive, cyclotrimethylenetrinitramine) were used to formulate the propellant.

• Journal of agriculture & life science
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• v.46 no.1
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• pp.207-215
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• 2012

In this study, we performed to select the high growth potential agri-products in Ulsan City, Korea. For this, we carried out the location quotient and the regional growth rate differential analyses using the cultivated area data and the agricultural output data in 2000, 2005 and 2007. The location quotient analysis revealed that rice, pear and persimmon were classified as specialized agri-products. These results would be useful to reflect on a short-term policy in support for the agricultural activities of the local farmers because the specialized agri-products occupy a relatively high proportion in the region. In addition, the regional growth rate differential analysis showed that strawberries, persimmon, potatoes, corn and sweet potato are classified as growing agri-products whereas pear is classified as a competitive agri-product in the analysis based on agricultural output from 2000 to 2007. Based on cultivated area, strawberries, potatoes and corn are classified as growing agri-products whereas sweet potato is classified as a competitive agri-product. These results would be beneficial to establish a long-term agricultural policy in Ulsan City because these agri-products are further supported by the time series analysis, considering the nationwide trends and the production activities reflecting the preferences of consumers and the willingness of producers.

• Journal of the Korean Chemical Society
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• v.39 no.8
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• pp.611-616
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• 1995

Oxovanadium(IV) complexes with salicylaldoxime, o-vanilline oxime, 2-hydroxy-4-methoxybenzaldoxime, 2-hydroxy-5-methoxybenzaldoxime and 2-hydroxy-5-nitrobenzaldoxime were synthesized. The complexes have been characterized by elemental analysis, electric conductivity measurement, infrared spectrometry, electronic spectrometry, mass spectrometry, and thermal analysis. The results of elemental analysis were well coincided with the theoretical values. The values of molar conductance of the complexes in DMF implicated that the complexes were non-electrolyte. The characteristic stretching frequency of V=O appeared strong band in the range of $980{\pm}20\;cm^{-1}.$ All the complexes showed two d-d transition in visible spectra and two charge transfer transitions in ultraviolet spectra. Results of mass spectrometry of $VO(sal)_2\;and\;VO(van)_2$ indicated two peaks corresponding to vanadium containing ion(I) of 1 : 2(metal to ligand) chelate and a fragment ion(II) of 1 : 1 chelate due to loss of ligand radical from ion(I). The thermal analysis showed the endothermic peak due to the thermal decomposition.

• Journal of Wetlands Research
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• v.13 no.2
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• pp.171-179
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• 2011

The main objective of this study is to estimate of the vegetation response induced by climate change to soil moisture. We investigated a relationship between vegetation activity and climate variables using Moderate Resolution Imaging Spectroradiometer (MODIS)-retrieved Normalized Difference Vegetation Index (NDVI) and soil moisture. NDVI which extracted from MODIS 13 Vegetation Indices Product was considered as an useful parameter to figure out a relationship with two types of soil moisture, which were observed at Rural Development Administration sites and estimated from Advanced Microwave Scanning Radiometer E (AMSR-E) satellite imagery. The correlation of MODIS-NDVI and ground measured soil moisture were observed, became much stronger when compared to soil moisture values with time lag (5days, 10days, 15days). The correlation patterns between NDVI and soil moisture with different time lag were related to soil texture. The results from this study will be useful to understand the role of vegetation in water balance control in various scales from regional to global climate change.

• Applied Chemistry for Engineering
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• v.30 no.2
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• pp.178-185
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• 2019

Three spherical quaternary composites composed of metal/metal oxide/high explosive/oxidizer were prepared by a crystallization/agglomeration process. From the characteristics of composites by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC), the shortening of the decomposition zone of high explosives in the quaternary composite was observed, which may be attributed to the autocatalytic reaction caused by $ClO_2$ or HCl which are ammonium perchlorate (AP) degradation products. The activation energy analysis showed that the activation energy abruptly decreases at the end of the decomposition zone of high explosives, and it was considered to be caused by $HNO_2$ which is common in decomposition products of high explosives. The activation energy predicted from complex pyrolysis results by the distributed activation energy model (DAEM) showed much better in accuracy than those by model-fitting methods such as Kissinger-Akahira-Sunose and Flynn-Wall-Ozawa models.