• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.47 no.8
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• pp.541-548
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• 2019

In this paper, the required amount of heat for an anti-icing system of a Flush Air Data Sensing(FADS) system is predicted. For an efficient prediction during the early stage of a design process, a handbook method is used. A program of which inputs are flight conditions is developed to predict the required amount of heat. A CFD analysis is conducted to compute the water catch efficiency which is one of the core parameters used in the handbook method. Kriging method, one of well-known regression mothods, is utilized to construct a surface contour database to evaluate impingements of droplets. To predict the trajectories of droplets, the database of a flow field around the surface is built using Kriging method as well.

• Journal of the Korean Institute of Gas
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• v.18 no.4
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• pp.27-34
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• 2014

In this study, we evaluated an effect of the tempered materials on the thermal runaway characteristics in the resol resin synthesis reaction using the adiabatic calorimetry of vent sizing package 2(VSP2). The kinetic parameters, such as an activation energy and heat of reaction, were estimated using the test results. As the results, the instantaneous characteristics to express the intensity of runaway reaction decreased at the low solid content. However, the sudden loss of the tempered materials triggered the second runaway reaction rapidly. In this condition, the heat of reaction and the activation energy of phenol and p-formaldehyde were about 157 kJ/mol and 60 kJ/mol, respectively.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.9 no.2
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• pp.257-263
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• 2008

We have examined explosion characteristics of bituminous coal dusts in cement manufacturing process. In order to find the thermal properties, we investigated weight loss and ignition temperature of coal materials using TGA and DSC. Also specific surface area of dust was investigated. Dust explosion experiments with Hartman's dust explosion apparatus have been conducted by varying concentration and size of coal dust for explosion probability and lower limit explosion concentration. According to the results for thermal properties, there is a little change by dust size. However, the specific surface area of dust is increased by decreasing dust size. The explosion test results show that small size and increasing concentration of dusts make dust explosion easier. And we find that the lower limit explosion concentration of bituminous coal is $0.3mg/cm^3$ and the probability is 100% on $0.9mg/cm^3$ in 170/200 mesh used in cement manufacturing process.

• Proceedings of the KIEE Conference
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• 2015.07a
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• pp.1130-1131
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• 2015

팰릿 형태의 XLPE (Cross-Linking Polyethylene)를 Hot Press로 시험편을 제작하여 열분석 데이터 처리장치를 이용하여 시차 주사 열량법 (differential scanning calorimetry, DSC)과 열 중량 분석 (Thermo gravimetric analysis, TGA) 등으로 열적 특성을 분석하였다. 분석 결과, XLPE의 전이온도 피크는 $61^{\circ}C$, 용융온도에 해당하는 피크는 $102^{\circ}C$에서 나타났으며 XLPE의 TG 분석 결과 $470^{\circ}C$ 근처에서 한 번의 급격한 열중량 감소를 보였으며 $800^{\circ}C$까지 측정 후 잔류물은 완전 분해되어 거의 존재하지 않았음을 알 수 있었다.

• Proceedings of the KIPE Conference
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• 2003.07b
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• pp.921-924
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• 2003

한전에서는 수요관리의 하나의 방법으로 심야전력요금제도를 운영하고, 심야축열기기를 보급하여 기저부하증대 및 부하율을 개선하기 위한 많은 노력을 기울이고 있다. 최근 유가상승 등의 원인으로 1999년과 2000년에 심야전력 난방기기의 급격한 보급증가로 인한 심야시간대 동계 최대 전력수요가 발생하여 22시 이후 단시간 부하급증으로 일부지역의 배전선로 회선용량부족 및 부하불평형으로 정전을 유발하게 되는 등 많은 어려움이 발생하였다. 본 논문은 심야수요급증으로 인한 대책의 일환으로 축열식 심야난방기기에 대하여 심야전력의 공급시간 자동제어장치를 개발하였다. 축열 잔열량을 측정하여 그 잉여량 만큼의 시간동안 심야전력의 공급을 지연하여 심야전력 공급초기에 집중되는 심야기기의 가동을 억제하여 심야부하를 분산하게 된다. 이로써 축열식 난방기기에 의한 동계 최대 전력수요 발생을 억제하여, 배전선로의 효율적인 운영에 기여할 것으로 기대된다

• Proceedings of the KIEE Conference
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• 2002.07d
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• pp.2334-2336
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• 2002

한전에서는 수요관리정책의 일환으로 심야전력요금제도를 운영하고, 심야축열기기를 보급하여 기저부하증대 및 부하율을 개선하여 전력공급 원가절감에 노력하여 왔으나, 최근 유가상승 등의 원인으로 1999년과 2000년에 심야전력 난방기기의 급격한 보급증가로 인한 심야시간대 동계 최대 전력수요가 발생하여 22시 이후 단신간 부하급증으로 일부지역의 배전선로 회선용량부족 및 부하불평형으로 정전을 유발하게 되는 등 많은 어려움이 발생하였다. 본 논문은 심야수요급증으로 인한 대책의 일환으로 축열식 심야난방기기의 하나인 축열식 전기온풍기에 대하여 심야전력의 공급시간 자동제어장치를 개발하였다. 축열 잔열량을 측정하여 그 잉여량 만큼의 시간동안 심야전력의 공급을 지연하여 심야전력 공급초기에 집중되는 심야기기의 가동을 억제하여 심야부하를 분산하게 된다. 이로써 축열식 난방기기에 의한 동계 최대 전력수요 발생을 억제하여, 배전선로의 효율적인 운영에 기여할 것으로 기대된다.

• Fire Science and Engineering
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• v.22 no.1
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• pp.99-104
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• 2008

It is important to understand thermal characteristic as a method to estimate the new materials, because spontaneous ignition characterized by causing combustion in the low temperature without ignition source. If can not find out the thermal characteristics of materials, it is frequent that causes of fires could not be found. The danger level of spontaneous ignition material should be estimated and by closely studying its thermal characteristic. However, RPF(Refuse Paper & Plastic Fuel) is a solid matter and getting increasesa year by year because it is an economy profit as alternative energy for limited fossil fuels. Some time RPF occur a fire in the cases of its production process and conservation. Therefore study for thermal stability and critical ignition temperature of RPF was so imperative that the experiment by means of Bombe Calorimeter, TG-DTA, MS80, SIT-II, and Wire Basket Test was implemented. As a result, RPF had a caloric value 26.4-28.3 MJ/kg, and its initial pyrolysis temperature was $192^{\circ}C$ at heating rate 2 K/min. With the result of analysis by MS 80 which is an instrument measuring microscopic calory, pure RPF not containing water has higher caloric value than RPF containing 20% water. Also, SIT-II which is an instrument of insulated auto-ignition was ignited by $118.5^{\circ}C$. This temperature is lower than that of Wire Basket Test. The critical ignition temperature was calculated by Frank-Kamenetskii equation can cause ignition at $80^{\circ}C$ when conserved in the height of 10 m by the standard of infinity slab.

• Journal of the Korean Institute of Gas
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• v.18 no.3
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• pp.31-37
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• 2014

The aim of this work is to provide new experimental data on the pyrolysis characteristics and the minimum ignition energy (MIE) by using the same high-density polyethylene (HDPE) powder in domestic HDPE dust explosion accident. To evaluate the explosion sensitivity of HDPE, thermo-gravimetric analysis (TGA), differential scanning calorimeter (DSC) and MIE apparatus (MIKE-3, K$\ddot{u}$hner) was conducted. The measurements showed the volume median diameter of $61.6{\mu}m$ but the particle number density of 98 % in the range $0.4{\sim}4{\mu}m$. The ignition temperature from the results of TGA and DSC in HDPE dust layers was observed in the range of $380{\sim}490^{\circ}C$. MIE was measured under 1 mJ in the HDPE dust concentration of $1200{\sim}1800g/m^3$, it was found that the ratio of particle number density in the range $0.4{\sim}4{\mu}m$ was very high (98%).

• Korean Chemical Engineering Research
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• v.55 no.5
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• pp.660-667
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• 2017

Equilibrium data of the mixture is essential in the design and operation of separation equipment such as distillation or extraction in chemical processes. These equilibrium data can be obtained through experiments or by calculations using the known binary parameters and the thermodynamic models. Generally, to obtain these parameters, phase equilibrium experimental data such as gas-liquid and liquid-liquid are used. In this study, the excess enthalpy of the mixture was measured using the flow type microcalorimeter which is a simpler method than phase equilibria experiments, and the parameters of various theories were obtained by using this data. In order to investigate the relationship between carbon chain length, enthalpy and binary parameters in the alkane system, excess enthalpies for the n-hexane + alkane (n-pentane, n-heptane, n-octane and n-dodecane) were measured at 298.15 K and the banary interaction parameters of Wilson, NRTL, and UNIQUAC were obtained from the experimental data. In addition, we wanted to obtain basic information on the interaction and association phenomena of the system including electrolyte applicable to various fields by using the excess enthalpy experimental data and the existing theory. First, we investigated the excess enthalpy for the NaOH / Water / Ethanol system as a basic experiment and examined the applicability using the electrolyte-NRTL (eNRTL) theory.

• Composites Research
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• v.28 no.6
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• pp.395-401
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• 2015

This study investigated the thermal stability of Grubbs' catalyst and its reactivity with self-healing agents for self-healing damage repair. Four types of Grubbs' catalyst supplied by manufacturers were considered and each catalyst was tested in as-received and grinded conditions. Four types of self-healing agents were prepared by varying the mixing ratio of dicyclopentadiene (DCPD) and 5-ethylidene-2-norbonene (ENB). Heat flows as a function of temperature were measured through a differential scanning calorimetry (DSC) to determine the thermal stability of catalysts. Reaction heats of self-healing agents with the catalyst were measured to evaluate the reactivity of the catalyst. For this evaluation, Fluka Chemika Grubbs' catalyst was used based on the maximum temperature and the time to reach the maximum temperature. According to the results, catalysts had different shapes depending on the manufacturer and the results showed that the smaller the size of the catalyst the higher the reactivity with self-healing agents. As the ENB ratio in self-healing agents increased, the maximum temperature increased, and the time to reach the maximum temperature decreased. As the amount of the catalyst increased, the maximum temperature increased, and the time to reach the maximum temperature decreased. Considering the thermal stability of the catalyst and its reactivity with the self-healing agent, combination of 0.5 wt% catalyst and the D3E1 self-healing agent was optimal for self-healing damage repair. Finally, as the thermal decomposition may occur depending on the environmental temperature, the catalyst must not be exposed to temperature higher than that is necessary to maintain the thermal stability of the catalyst.