• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2002.05a
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• pp.69-72
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• 2002

저발열량 가스(LCVG : low calorific value gases)는 석탄 가스, coke oven gas, carbon black waste gas, 화학공정 폐가스, 휘발성 유기화합물(VOC) 등 다양하다. 발열량 150~2,000㎉/m$^3$정도의 가스를 말하며 주요 조성은 H$_2$, CO, CH$_4$ 등이다. 화학공정 폐가스나 휘발성 유기물질 배출공정에서는 저농도(LEL 25% 이하)의 유기물질이 주 조성이다.(중략)

• Journal of Korean Society for Atmospheric Environment
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• v.9 no.1
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• pp.33-43
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• 1993

대기오염은 지구의 생성과 함께 화산폭발의 가스 배출에서 부터 작게는 가정내 연료사용의 연소과정에 이르기까지 각종 형태로 배출되어 우리 건강 뿐 아니라 생활복지면에 이르기까지 영향을 끼쳐오고 있다.

• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.642-645
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• 2007

석탄, 폐기물 등 다양한 시료의 가스화 반응을 통해서 발생되는 합성가스는 CO, $H_2$, $CO_2$가 주성분으로 가스엔진, 가스터빈 등의 연료로 사용하여 발전하거나 합성반응을 통해 다양한 화학원료로의 전환이 가능하다. 합성가스를 가스엔진, 가스터빈, 연료전지등의 연료로 사용하는 경우는 고효율 발전이 가능하여 기존 연소방식의 발전과 비교하여 단위 전력 생산량 당 $CO_2$의 배출량이 감소 되며, 여기에 $CO_2$ 분리공정을 적용하면 $CO_2$ 배출량 감소효과를 극대화 할 수 있다. 화석연료의 연소 및 가스화 반응을 통해서 발생하는 이산화탄소의 분리에 대한 많은 연구가 진행되고 있으나, 본 연구에서는 흡착방식을 이용한 합성가스 내의 이산화탄소 분리를 위하여 흡착제를 이용한 이산화탄소의 흡착, 탈착 성능 분석 연구를 수행하였다. 합성가스내의 이산화탄소를 분리하기 위한 흡착제로는 NaX 계열의 zeolite를 이용하였으며, 가스화 반응을 통해 발생한 합성가스를 흡착제에 통과시켜 이산화탄소의 선택적 흡착 여부를 확인하였다. 또한 TPD(Temperature Programmed Desorption)방법을 이용하여 흡착제의 이산화탄소 흡착 성능을 분석하였다.

• Applied Chemistry for Engineering
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• v.23 no.5
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• pp.456-461
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• 2012

To verify the utilization of biomass as energy, the combustion characteristic has been studied by an experimental combustion furnace under an isothermal and non-isothermal combustion. The wood pellet, rice straw and rice husk were used as biomass samples in this work. The characteristics of emission gases, dusts and residues from biomass combustion have been analyzed and compared with those of reuse derived fuel (RDF). From isothermal combustion experiments, it was found that the incomplete combustion of rice straw was greater that that of rice husk, wood pellet and RDF. This is due to the fact that the combustion reaction rate of the rice straw was faster than that of other samples, and the oxygen concentration in rice straw combustion was rapidly decreasing. It was also found that $NO_{X}$ concentration of emission gas from wood pellet combustion was the lowest. From non-isothermal combustion experiments, it was found that all samples were burned before $900^{\circ}C$. Also, the temperature range of $NO_{X}$ emission was similar to that of CO emission, on the other hand, $SO_{2}$ was emitted at a higher temperature than that of CO emission.

• Proceedings of the Korean Society of Disaster Information Conference
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• 2022.10a
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• pp.290-291
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• 2022

본 논문에서는 우리나라 2030년 국가 온실가스 감축목표(NDC*, 291백만톤 감축)달성 및 2050년 탄소중립 목표 달성을 위해 필연적으로 수반되는 천연가스 내 수소 혼입에 따른 안전성확보 방안과 수소혼입에 따른 국민 불안감 해소 및 수용성 제고를 위한 대안을 제시하고, 해외 사례를 연구 하였다. 탄소중립은 온실가스(이산화탄소 등)의 배출량을 최대한 줄이고, 남은 온실가스를 흡수, 제거해서 실질적인 배출량이 "0"이 되는 것을 의미하고, 수소혼입은 도시가스의 주성분인 메탄 연소시 발생하는 CO₂를 최소화하기 위해 수소(H₂)를 도시가스에 일정비율 혼합하는 것을 말한다. 본 연구에서는 수소 혼입 시 우려되는 수소취성 및 배관내구성 문제와 수소 특성인 작은 입자로 인한 누출 위험성, 고층에서 메탄과 수소가 분리되는 현상 등에 따른 문제를 도출하고 이에 대한 안전관리 방안도 함께 제시하였다. 또한, 도시가스 배관에 수소 혼입시 천연가스 대체를 통한 온실가스 감축 및 기존 배관망 사용을 통한 경제성 분석결과와 국가 온실가스 감축에 어느 정도 기영할 수 있는지도 함께 기술하였다.

• Journal of Climate Change Research
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• v.4 no.2
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• pp.115-126
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• 2013

Recently Korea considers the source of biomass burning emissions reflecting national characteristic, so that includes the inventory of emission source but preceding research is rarely implemented in Korea. Therefore, a study on characteristics of greenhouse gas emissions from biomass burning is necessary and it also makes the source management effectively when the climate-atmospheric management system takes effect. In this study, using the manufactured charcoal kiln and the number of experiment was three times to get a reliable experiment result. The sampling time was decided by changing degree in charcoal kiln and charcoal manufacturing process. The results of calculation greenhouse gas emission factor from charcoal kiln were $668g\;CO_2/kg$, $20g\;CH_4/kg$, $0.01g\;N_2O/kg$. Using the emission factor developed in this study, estimate the emissions from charcoal kiln in Korea. The results of calculation were $46,040ton\;CO_2/yr$, $1,378ton\;CH_4/yr$, $0.69ton\;N_2O/yr$ and greenhouse gas emissions applying GWP are as follows. $CH_4$ emissions was $28,947ton\;CO_2eq./yr$, $N_2O$ emissions was $214ton\;CO_2eq./yr$. As a results, Gross emissions of charcoal kiln in Korea was $75,201ton\;CO_2eq./yr$, but the oak used in this study is included to the biomass so emissions of $CO_2$ are excluded. Therefore the net emissions of charcoal kiln in Korea was $29,161ton\;CO_2eq./yr$.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.12
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• pp.1121-1126
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• 2010

This study is to investigate the effects of aromatics and T90 for low cetane number (CN) fuels on combustion and exhaust emissions in low-temperature diesel combustion. We use a 1.9-L common rail direct injection diesel engine at 1500 rpm and 2.6 bar BMEP. Low temperature diesel combustion was achieved via a high external EGR rate and strategic injection control. The tested fuels four sets: the aromatic content was 20% (A20) or 45% (A45) and the T90 temperature was $270^{\circ}C$ (T270) or $340^{\circ}C$ (T340) with CN 30. Given the engine operating conditions, the T90 was the stronger factor on the ignition delay time, resulting in a longer ignition delay time for higher T90 fuels. All the fuels produced nearly zero PM because of the extension of the ignition delay time induced by the low cetane number. The aromatic content was the main factor that affected the NOx and the NOx increased with the aromatic content.

• Journal of the Korean Institute of Gas
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• v.24 no.4
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• pp.25-31
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• 2020

Experimental investigations were conducted to examine the combustion characteristics of a swirl-stabilized double cone premixed burner nozzle used for industrial gas turbines for power generation. Several variants with different fuel injection patterns are tested to compare the combustion characteristics such as NOx and CO emissions, stability, and wall temperature distributions. Main results show that NOx emissions and stability are decreased either when the fuel hole diameter is decreased with the same number of fuel holes, or when the number of fuel holes is reduced with the same total area of fuel holes, both of which are due to a higher penetration of fuel into the air stream. Not only is NOx reduced but also stability is enhanced when the fuel hole diameter varies in an alternating manner with the same total area of fuel holes, showing that NOx reduction is due to a higher penetration of mean fuel injection path while stability enhancement is due to a lowered penetration of minimum fuel injection path.

• Korean Journal of Agricultural and Forest Meteorology
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• v.10 no.1
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• pp.17-24
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• 2008

This study was performed to estimate non-$CO_2$ greenhouse gases (i.e., GHGs) emission from biomass burning at a local scale. Estimation of non-$CO_2$ GHGs emission was conducted using Landsat TM satellite imagery in order to assess the damage degree in burnt area and its effect on non-$CO_2$ GHGs emission. This approach of estimation was based on the protocol of the 2003 IPCC Guidelines. In this study, we used one of the most severe fire cases occurred Samcheock in April, 2004. Landsat TM satellite imageries of pre- and post-fire were used 1) to calculate delta normalized burn ratio (dNBR) for analyzing burnt area and burn severity of the Samcheok large-fire and 2) to quantify non-$CO_2$ GHGs emission from different size of the burnt area and the damage degree. The analysis of dNBR of the Samcheok large-fire indicated that the total burnt area was 16,200ha and the size of the burnt area differed with the burn severity: out of the total burnt area, the burn severities of Low (dNBR < 152), Moderate (dNBR = 153-190), and High (dNBR = 191-255) were 35%, 33%, and 32%, respectively. It was estimated that the burnt areas of coniferous forest, deciduous forest, and mixed forest were about 11,506ha (77%), 453ha (3%), and 2,978ha (20%), respectively. The magnitude of non-$CO_2$ GHGs emissions from the Samcheok large-fire differed significantly, showing 93% of CO (44.100Gg), 6.4% of CH4 (3.053Gg), 0.5% of $NO_x$ (0.238Gg), and 0.1% of $N_2O$ (0.038Gg). Although there were little changes in the total burnt area by the burn severity, there were differences in the emission of non-$CO_2$ GHGs with the degree of the burn severity. The maximum emission of non-$CO_2$ GHGs occurred in moderate burn severity, indicating 47% of the total emission.

• Analytical Science and Technology
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• v.28 no.3
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• pp.236-245
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• 2015

Recently, candles have been widely used to create a romantic atmosphere and to heat tea. In this study, a small combustion chamber for candle was designed using an 0.008 m³ bell jar. The emission factors of combustion products were then measured. The combustion chamber includes a glass dish, which prevents candle flame from affecting the composition of the gas emitted through the exhaust outlet. The outlet in the combustion chamber was designed as a cone shape, and it was lengthened to prevent flow from the outside, which could affect the homogeneous composition of the exhaust gas. The temperature at the outlet of the chamber was 34 ℃~41℃. The major combustion products of the candle, such as such aldehydes and acids, contained oxygen. The mass specific emission rates of benzene, toluene, ethylbenzene, and TVOC were 0.04 μg/g, 0.01 μg/g, 0.02 μg/g, and 3.81, respectively. The mass specific emission rates of formaldehyde, acetaldehyde and benzaldehyde were 4.48 μg/g, 1.09 μg/g, and 0.67 μg/g, respectively. Considering the different compositions of the candle samples, their mass specific emission rates were similar to those obtained by using a large chamber 0.17 m³~50 m³ in size.