• Title/Summary/Keyword: 연소법

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Synthesis of nanoporous $TiO_2$ films for dye-sensitized solar cells application (염료태양전지용 다공질 구조 $TiO_2$ 박막 제작 및 특성 평가)

  • Han, Deok-Woo;Park, Byung-Wook;Kwak, Dong-Joo;Sung, Youl-Moon;Lee, Don-Kyu
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2008.10a
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    • pp.197-200
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    • 2008
  • 본 연구에서는 Ketjen black을 이용한 DSCs (Dye-sensitized solar cells)용 다공질의 $TiO_2$ nano-powder 제작기술을 제안한다. $TiO_2$ powder는 sol-gel연소법에 의해 Ti-isopropoxide와 2-propanol을 사용하여 제작되었으며, Ketjen black의 함량($0g{\sim}2g$)을 달리하여 제작된 $TiO_2$ nano-powder의 다공성과 입자의 크기 결정성등의 특성을 고찰하였다. 또한 이러한 $TiO_2$ powder를 paste로 만들어 다른 열처리 온도($100^{\circ}C{\sim}600^{\circ}C$)에서 $TiO_2$ 박막을 이용한 DSCs를 제작한 후 그 효율을 측정하였다. 그 결과 Ketjen black 1g을 함유시켜 만들어진 $TiO_2$ powder의 다공성과 입자 크기가 가장 우수한 것으로 FE-SEM의 측정결과 나타났으며 또한 이 때의 $TiO_2$ powder는 FT-IR의 측정 결과, Ti-O-Ti의 결합구조를 가진 성분과 $H_2O$ 성분으로 구성되어 있음을 알 수 있었다. 그리고 여러 온도에서 제작된 DSCs 실험 셀 중 $500^{\circ}C$의 열처리 공정을 거적 제작된 셀의 효율이 가장 높은 효율이 5.46%를 나타내고 있음을 확인할 수 있었다.

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A Study on the Safety Management of High Pressure Underground Pipeline in Industrial estate (산업단지 고압매설배관 안전관리 고찰)

  • Choi, Hyun-Woong;Chung, Se-Kwang;Kim, Jin-Jun
    • Journal of the Korean Institute of Gas
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    • v.21 no.6
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    • pp.30-38
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    • 2017
  • Established in the 1960s, high pressure underground pipelines in Ulsan and Yeosu industrial estate are underground as toxic gas as well as combustible gas that is heavier than city gas and low combustion range. Especially, industrial pipelines occupy more than 20 years old pipes. In this way, the industrial estate pipeline was installed before the introduction of the supervision of construction, However, unlike the city gas pipeline, the pipeline is managed without any legal obligation. In this study, the safety management status of high pressure underground pipelines and urban gas underground pipelines in the industrial estate is analyzed and comparison of laws, extent of damage impact, using the pipe inspection model for pipe inspection of high pressure piping system with the existing piping system. it is intended to cuntribute to improving the safety of industrial estate are underground pipeline.

Influence of Surrounding Gas and Coal Characteristics on Flame Propagation in Oxy-Fuel Combustion of Pulverized Coal (미분탄 순산소 연소에서 주위 기체와 석탄 특성이 화염전파에 미치는 영향)

  • Kang, Young-Min;Shim, Young-Sam;Moon, Cheor-Eon;Sung, Yon-Mo;Seo, Sang-Il;Kim, Tae-Hyung;Choi, Gyung-Min;Kim, Duck-Jool
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.1
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    • pp.38-45
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    • 2009
  • Oxy-fuel combustion of pulverized coal is one of the promising new technologies to reduce $CO_2$ and NOx from coal combustion. However, the stability of pulverized coal flame is reduced in the oxy-fuel combustion. This flame stability is concerned with the flame propagation that is affected by surrounding gas and coal characteristics, such as gas temperature, gas composition, coal volatile, coal activation energy and coal size. In this paper, a study on the influence of surrounding gas and coal characteristics on the flame propagation velocity in oxy-fuel combustion of pulverized coal was preformed. One dimensional model was used to calculate the flame propagation velocity of pulverized coal clouds. In this model, the radiation is considered to be the main source of heat exchange, and Monte Carlo method was adopted for accurate calculation of radiation heat flux. It was found that the flame propagation velocity become higher with the decrease of coal activation energy and the increase of coal volatile. Also, according to the increase of gas temperature and $O_2$ concentration, flame propagation velocity increased.

Radiation Shielding Analysis of CANDU Spent Fuel Transport Cask (CANDU 사용후핵연료 수송용기 방사선차폐 영향평가)

  • Choi, Jong-Rak;Yoon, Jung-Hyun;Kang, Hee-Young;Lee, Heung-Young;Chung, Sung-Whan
    • Journal of Radiation Protection and Research
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    • v.18 no.2
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    • pp.27-35
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    • 1993
  • A shielding analysis of the shipping cask for transporting the CANDU spent fuel bundles has been studied. Radiation source term has been calculated on spent fuel with burn-up of 7,800 MWD/MTU and 5 years cooling time by ORIGEN2 code. The shielding calculation for the cask capable of transporting 378 bundles of CANDU spent fuel has been made by use of 1-D ANISN and 2-D DOT 4.2 codes. As a result of analysis, the optimum shield thickness of cask was obtained. And it is proved that the safety in radiation shielding under normal transport and hypothetical accident conditions is confirmed to satisfy the allowable values specified in IAEA Safety Series No. 6 and the Korean Atomic Law.

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Change of Ammonia Consumption with Gas Turbine Output in DeNOx System for a 580 MW Combined Cycle Power Plant (580 MW급 복합발전소 탈질설비에서 가스터빈 출력에 따른 암모니아 소모량 변화)

  • Jang, Yong-Woo;Yoo, Ho-Seon
    • Plant Journal
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    • v.15 no.3
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    • pp.23-28
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    • 2019
  • In this study, ammonia consumption by gas turbine output was adjusted to find out the amount of ammonia consumption that complies with the enhanced Air Quality Preservation Act and internal regulation emission standards in SCR type DeNOx System for a 580 MW Sejong Combined Cycle Power Plant. For measurements, the gas turbine output was varied to 50, 99, 149, 198 MW and ammonia consumption was adjusted with the combustion gas and ammonia supply conditions fixed at each stage. When the emission limit were change from 10 ppm to 8 ppm, ammonia consumption was increased from 78, 93, 105, 133 kg/h to 89, 113, 132, 176 kg/h. The increase rate of ammonia consumption was 14, 22, 26, 32% per output category compared to the 10 ppm emission limit, which was shown to increase as output increased.

An experimental study of particle deposition from high temperature gas-particle flows (고온의 기체 입자 유동으로부터 입자부착 현상에 관한 실험적 연구)

  • 김상수;김용진
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.11 no.3
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    • pp.501-508
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    • 1987
  • Experimental studies of particle (TiO$\_$2/) deposition from the laminar hot gas particle flow (about 1565K) onto the cold wall surface (about 1215K-1530K) were carried out by the 'real time' laser light reflectivity method (LLRM) and the photographs of scanning electron microscope(SEM). The LLRM was used for the measurement of thermophoretic deposition rates of small particles (d$\_$p/<3.mu.m), and the photographs of SEM were used for determining what factors control the collection of particles having diameters ranging from 0.2 to 30 microns. Two phenomena are primarily responsible for transport of the particles across the laminar boundary layers and deposition: (1) particle thermophoresis (i.e. particles migration down a temperature gradient), and (2) particle inertial impaction, the former effect being especially larger factor of the particle deposition in its size over the range of 0.2 to 1 microns. And also, this study indicates that thermophoresis can be important for particles as large as 15 microns. Beyond d$\_$p/=16.mu.m, this effect diminishes and the inertial impaction is taken into account as a dominant mechanism of particle deposition. The results of present experiments found to be in close agreement with existing theories.

The Hazard Assessment of Release and Dispersion of CNG Service Station (CNG 충전소의 누출$\cdot$확산에 대한 위험성 평가)

  • Choi Jong-Woon;Lee Su-Kyung
    • Journal of the Korean Institute of Gas
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    • v.4 no.3 s.11
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    • pp.53-58
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    • 2000
  • It was carried out consequence analysis(CA) of CNG (compressed natural gas) service station and we compared the results of CA of CNG service station with LPG service station which was installed by high Pressure gas law. The results of CA were that distance of CNG LFL was 1.5 times than the length of LPG LFL. Thermal radiation effect about CNG may not be showed damage of process facilities, but in the case of LPG, it was enough to have an large damage effect on a downtown. The thermal radiation of 37.5 $kw/m^2$ extended 12.6 m. Also, in the case of 12.5 $kw/m^2$ which was able to burn wood, the radiation effect of LPG is 3 times than CNG.

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The spectroscopic study of chemical reaction of laser-ablated aluminum-oxygen by high power laser (분광분석을 활용한 고에너지 레이저 환경에서의 알루미늄-산소 화학반응 연구)

  • Kim, Chang-hwan
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.44 no.9
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    • pp.789-795
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    • 2016
  • Laser-induced combustions and explosions generated by high laser irradiances were explored by Laser-Induced Breakdown Spectroscopy (LIBS). The laser used for target ablation is a Q-switched Nd:YAG laser with 7 ns pulse duration at wavelength of 1064 nm laser energies from 40 mJ to 2500 mJ ($6.88{\times}10^{10}-6.53{\times}10^{11}W/cm^2$). The plasma light source from aluminum detected by the echelle grating spectrometer and coupled to the gated ICCD(a resolution (${\lambda}/{\Delta}{\lambda}$) of 5000). This spectroscopic study has been investigated for obtaining both the atomic/molecular signals of aluminum-oxygen and the calculated ambient condition such as plasma temperature and electron density. The essence of the paper is observing specific electron density ratio which can support the processes of chemical reaction and combustion between ablated aluminum plume and oxygen from air by inducing high laser energy.

Estimation for output correction of internal combustion engine (내연기관의 출력수정에 관한 평가)

  • 김문헌
    • Journal of the korean Society of Automotive Engineers
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    • v.8 no.1
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    • pp.22-28
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    • 1986
  • 기관의 성능에 영향을 주는 인자로서는 외적인자(outside factor), 작동인자(operating factor) 및 설계인자(design factor)의 3가지로 나눌 수 있다. 작동인자로서는 기관회전수, 공기연료비, 점화 시기 또는 분사시기 등이면 설계인자로서는 행정체적, 압축비, 흡배기계통의 구조 및 치수, 냉각 방식 등으로 기관에 따라 고유한 값을 가지는 인자이다. 그러나 외적인자인 대기조건 즉 대기 압력, 대기온도 및 대기습도는 계절, 지역 및 기상조건에 따라 달라지므로 이것에 따라 기관이 흡입하는 공기의 압력, 온도 및 습도는 변화하게 된다. 그러므로 대기조건의 변화에 따라서는 기관작동인자인 공기연료비에도 영향을 미치게 할 것이고 또한 연소상태의 변화로 유효압축비 에도 영향을 미치게 할 것이므로 대기상태의 변화는 곧 바로 기관 출력의 변화를 초래하게 될 것이다. 그러므로 같은 운전조건에서의 기관출력도 대기상태의 변화에 따라 변화하게 되므로 임의의 대기 상태에서 측정한 기관출력을 표준대기상태의 기관출력으로 환산해서 평가할 필요가 생긴다. 이것을 일반으로 출력수정(output correction)이라 하고 있으며 각 나라마다 공업규격 또는 기타규격으로 출력정식을 제정하고 있다. 예를 들면 K.S.B 9102, SAE J816B, B.S. 765, DIN 70020, JIS B 8013등이다. 이들 출력수정식들은 많은 문제점을 가지고 있으므로 종래의 출 력수정식으로 출력수정을 하여도 정확하게 맞지 않은 경우가 많다. 출력수정에 관한 문제는 수 10년전부터 많은 연구자에 의하여 연구되고 거론되어 왔으나 과거의 연구자들이 제안하고 거론 되어 왔으나 과거의 연구자들이 제안하고 있는 출력수정식, 또는 규격으로 정하고 있는 출력수 정방법은 어느 것이나 실용상 만족스러운 것이 아직 없다. 그러므로 본 자료는 스파아크 점화 기관의 흡기습도에 관한 출력수정의 문제를 실험적으로 수행한 실험적 출력수정방법에 의한 것과 종래의 출력수정방법에 의한 것과를 비교 검토하였다.

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Preparation of ZrB2 by Self-propagating Synthesis and Its Characteristics (자전연소합성법에 의한 ZrB2 세라믹분말합성 및 NaCl의 영향)

  • Kim, Jinsung;Nersisyan, Hayk;Won, Changwhan
    • Korean Journal of Materials Research
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    • v.24 no.5
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    • pp.255-258
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    • 2014
  • Zirconium boride is an artificial or which is rarely found in the nature. $ZrB_2$ is popular in the hard material industry because it has a high melting point, excellent mechanical properties and chemical stability. There are two known methods to synthesize $ZrB_2$. The first involves direct reaction between Zr and B, and the second is by reduction of the metal halogen. However, these two methods are known to be unsuitable for mass production. SHS(Self-propagating High-temperature Synthesis) is an efficient and economic method for synthesizing hard materials because it uses exothermic reactions. In this study, $ZrB_2$ was successfully synthesized by subjecting $ZrO_2$, Mg and $B_2O_3$ to SHS. Because of the high combustion temperature and rapid combustion, in conjunction with the stoichiometric ratio of $ZrO_2$, Mg and $B_2O_3$; single phase $ZrB_2$ was not synthesized. In order to solve the temperature problem, Mg and NaCl additives were investigated as diluents. From the experiments it was found that both diluents effectively stabilized the reaction and combustion regime. The final product, made under optimum conditions, was single-phase $ZrB_2$ of $0.1-0.9{\mu}m$ particle size.