• Journal of the Korean Society of Combustion
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• v.1 no.2
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• pp.21-29
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• 1996

Flame propagation characteristics of propane-air mixtures were experimentally investigated in constant-volume combustion chambers. Flame propagation process was observed as a function of mixture strength, initial mixture temperature and initial mixture pressure in quiescent mixtures. A cylindrical combustion chamber and a spherical combustion chamber contain a pair of parallel windows through which optical access into the chamber can be provided. Laser two beam deflection method was adopted to measure the local flame propagation, which gave information on the flame size and flame propagation speed. Pressure development was also measured by a piezoelectric pressure transducer to characterize combustion in quiescent mixtures. Burning velocity was calculated from flame propagation and pressure measurements. The effect of flow on flame propagation was also investigated under flowing mixture conditions. Laser two beam method was found to be feasible in measuring flame propagation of quiescent mixtures. Flame was observed to propagate faster with higher initial mixture temperature and lower initial pressure. Combustion duration was shortened in the highly turbulent flowing mixtures.

• Journal of ILASS-Korea
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• v.27 no.1
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• pp.36-41
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• 2022

In this study, the combustion instability characteristics according to the change in the hydrogen ratio in the fuel in the single nozzle system of the hydrogen-natural gas mixed gas turbine for power generation was analyzed using a three-dimensional finite element analysis-based Helmholtz solver. This combustor shows the instability characteristics in which mode transition occurs from a mode having a low amplitude near 70 Hz to a mode having a high amplitude of 250 Hz or higher as the hydrogen fraction in the fuel increases. The current modeling results are found to reasonably predict the main characteristics of the change in measured instability frequency and growth rate with the change in fuel composition.

• Analytical Science and Technology
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• v.30 no.5
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• pp.234-239
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• 2017

Identifying the components of residues that are not completely burned at the sites of fires site can provide valuable information for tracing the causes of fires. In order to clarify the types of plastic combustion residues found at the scenes of fires, we studied the residue formed after the combustion of polyethylene (PE) and acrylonitrile butadiene styrene (ABS). Plastic samples were burned at 200, 300, 350, 400, and $500^{\circ}C$ for 3 min using a cone calorimeter, and the changes in weight and combustion products were observed. The powder products obtained by lyophilization and pulverization of the combustion products obtained at each temperature were analyzed by a Fourier transform-near infrared (FT-NIR) spectrometer. When the PE samples were burned, the weight did not change up to $350^{\circ}C$, however a significant change in the weight could be measured above $400^{\circ}C$. The principal component analysis (PCA) of the FT-NIR spectra of the PE and ABS samples obtained at each temperature confirmed that the combustion residues at each temperature were PE and ABS, respectively. Therefore, the types of unburned plastics found at the sites of fires can be confirmed rapidly by near infrared spectroscopy.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.215.2-215.2
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• 2010

지구온난화의 주범으로 알려진 $CO_2$의 대기 중 농도는 산업혁명 이전 280ppm에서 산업 혁명 이후 375ppm으로 증가하였다. 정부 간 기후변화패널(IPCC)의 기후변화 시나리오에 의하면, 지금부터 다양한 감축노력을 한다 할지라도 $CO_2$ 증가추세는 계속되어 2100년경에는 대기 중 $CO_2$농도가 600~950ppm에 이를 것으로 예측하고 있다. 현재까지 화력발전부분은 온실가스($CO_2$)의 최대 배출 원으로 알려져 있으며 이 분야의 $CO_2$ 회수기술은 연소 후 포집(Post-combustion), 순산소 연소(Oxy-fuel combustion), 연소 전 탈탄소화(Pre-combustion) 3가지로 크게 구분된다. 이중 석탄가스화복합발전(IGCC)기술과 연계하여 $CO_2$를 회수할 수 있는 방법이 연소 전 탈탄소화 기술이다. 핵심기술은 $CO_2$ 분리공정으로 적용 될 수 있는 기술로서는 흡착 흡수법, 막분리법 그리고 가스 하이드레이트가 있으나 아직까지 우리나라의 가스 하이드레이트 기술은 전무한 형편이다. 본 연구에서는 가스 하이드레이트 형성원리를 이용하여 정온 정압 조건에서 $CO_2/H_2$ 하이드레이트를 제조하였으며 특히, 하이드레이트 형성 촉진제인 TBAB(Tetra-n-butyl ammonium bromide)를 첨가하여 TBAB 농도에 따른 상평형 및 속도론 실험을 수행 하였다. 또한 라만 분석을 통하여 $CO_2$ 회수 분리에 대한 연구도 병행하였다.

• Journal of the korean Society of Automotive Engineers
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• v.6 no.2
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• pp.14-19
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• 1984

종래에 많이 사용된 각양의 계측 방법을 일일이 설명하는 것은 본 해설의 목적이 아니기 때문에 개략적으로 분류하여 설명하면 다음과 같다. 1) 시간 평균유속은 주로 프로브(probe)를 경유하여 동압과 정압의 측정에 의하여 수행되어 왔다. 연소반응이 있으면 밀도의 변화가 있게 되는데 밀도는 후술하는 농도의 계측과 온도의 계측에 의하여 정해져 동압과 정압으로부터 유속으로 변환된다. 시간분해능이 높은 비접촉식(직접 프 로브를 측정부에 삽입하지 않는 방법) 유속측정이 가능한 방법으로는 레이저 도플러 유속계 (Laser Doppler Velocimetry, 이하 LDV로 표현)를 들 수 있다. LDV는 압력측정에 의한 유속 산출법에서와 같은 온도 및 농도 등의 부수적인 계측이 필요없이, 직접 유속을 검출할 수 있으며 또한 검정이 필요없는 절대유속 측정이 가능하며 현재 연소반응이 있는 흐름에 대한 대부분의 연구에 적용되고 있는 실정이다. 2) 시간평균 화학종 농도측정에 가장 많이 쓰이는 방법은, 연소가스를 채취하여 가스 크로마토 그라프(Gas Chromatograph)로 분석하는 것을 들 수 있다. 한편, 시간 분해능이 높은 화학종 농 도의 계측은 레이저를 사용하여 각 화학종의 발광, 산란 및 흡수성을 이용, 측정한다. 3) 온도측정은 대부분 열전대를 사용하고 있다. 그러나 이 방법은 직접 프로브를 삽입해야 하므로 사용한계의 범위가 지극히 좁으며, 연소반응이 일어나므로 프로브 자체의 촉매반응 및 복사 열전달에 의한 보정 등이 사용상 큰 문제로 제기된다. 그러나 최근 레이저 이용기술의 발달로 (2)항에서의 농도 계측과 같이 반응기체의 온도 및 성분의 동시측정이 가능한 방법도 점차 현 실화 되어가고 있다. 그 대표적인 예로 CARS법(Coherent Anti-Stokes Raman Spectroscopy)을 들 수 있다. 이상으로부터 연소반응이 일어나는 흐름에서의 각종 계측에서는, 비접촉 측정의 가능성과 시간 공간 분해능의 특징으로 미루어 앞으로는 레이저를 이용한 계측 방법이 그 주류를 이룰 것으로 사료된다. 우선 본 해설은 기체의 온도 및 농도의 광학적 측정방법중 Raman산란광 검출법에 대하여 실제로 측정하는 입장에서 간단히 소개한다.

• Proceedings of the KIEE Conference
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• 1999.11d
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• pp.882-884
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• 1999

금속 다층박막과 미세입상 합금박막에서 발견된 Giant Magnetoresistance(GMR)현상에 고무되어 최근에는 50년대에 밝혀졌던 산화물 자기저항 재료에 관하여 새롭게 연구하고 있다. Perovskite 구조를 가지는 $La_{1-x}Ca_{x}MnO_{3}$ 박막에서 큰 자기저항을 얻었으며 이를 Colossal Magentoresistance (CMR)이라 한다. 본 연구에서는 $La_{1-x}Ca_{x}MnO_{3}$ 분말을 고상반응법과 자발착화연소 합성법(Glycine-Nitrate Process)으로 각각 제조하였으며 비교 분석하였다. TGA을 이용하여 불순물과 미반응 물질을 확인하여 적당한 하소온도를 결정하였고 XRD를 이용하여 결정상을 분석하였다. Dilatometer를 이용해 $1400^{\circ}C$까지의 열팽창율을 측정하였다. BET로 비 표면적을 비교하였으며, 주사전자현미경(SEM)으로 각각 제조된 분말의 입자상태와 입자성장을 확인하였다. GNP법으로 합성한 경우가 고상반응법을 이용한 경우보다 입자의 크기가 submicron 단위로 미세하고 비표면적도 수배 컸으며, 고순도의 perovskite 구조를 갖는 $La_{1-x}Ca_{x}MnO_{3}$ 분말을 얻을 수 있었다.

• Proceedings of the Materials Research Society of Korea Conference
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• 2001.05a
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• pp.20-20
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• 2001

• Analytical Science and Technology
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• v.33 no.6
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• pp.262-273
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• 2020

A fluorine content analysis method for krill oils, which is a representative oil formulation in foods, was developed in compliance with the Korea Food and Drug Ministry's "Guidelines for Validation of Testing Methods Related to Food". Using this method for krill oils, the presence of impurities was evaluated via combustion-ion chromatography (C-IC). A review of published technical data on fluorine in krill oils showed that while the traditional wet potentiometric method was typically used, it was not reliable. Moreover, there was no food testing/analysis laboratory in Korea to perform a fluorine test analysis on such an oil matrix. Therefore, we identified halogen (fluorine) tests, developed to national and international standards, and developed a test method suitable for krill oils by selecting a C-IC method that is sufficiently applicable to the oil matrix. Based on the characteristics of the oil matrix, the optimal test method was established through various experiments by reviewing the concerns related to loss and interference in the preparation and introduction of samples. The fluorine content test was carried out on 11 krill oil products that were purchased online. Most products (with the exception of only one) were found to contain less than the reporting limit obtained by the test method. Furthermore, after additional testing, a high fluorine content of approximately 2,000 ~ 3,000 mg/kg was detected on the krill surface, although the concentration varied depending on the area of the krill. A comparison with samples from two ISO/IEC 17025 testing laboratories confirmed that there was no significant difference in the statistical analysis results obtained by ANOVA among the three laboratories. A testing guide for fluorine content analysis was completed.

• Journal of the Korean Institute of Gas
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• v.24 no.5
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• pp.29-38
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• 2020

It is practically difficult to accurately measure the temperature and concentration of a large combustion systems at industrial sites in real time. Temperature measurement using thermocouple, which are mainly used, is a point-measuring method that is less accurate and less reliable to analyze the wide area range of inner combustion system, and has limitations to internal accessibility. In terms of concentration analysis, most measurement methods use sampling method, which are limited by the difficulty of real-time measurement. As a way to overcome these limitations, laser-based measurement methods have been developed continuously. Laser-based measurement are line-average measurement methods with high representation and precision, which are beneficial for the application of large combustion systems. In this study the temperature and concentration were measured in real time by water vapor and oxygen generated during combustion using Tunable Diode Laser Absorption Spectroscopy (TDLAS). The results showed that the average temperature inside the combustion system was 1330℃ and the mean oxygen concentration was 3.3 %, which showed similar tendency with plant monitoring data.

• Clean Technology
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• v.19 no.2
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• pp.128-133
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• 2013

Catalytic combustion of benzene over $CeO_2$-supported copper oxides has been investigated. The supported copper oxides catalysts were prepared using ball mill method and characterized by XRD, FT-IR, TEM and TPR. In the CuO/$CeO_2$ catalysts prepared using ball mill method, highly dispersed copper oxide species were shown at high loading ratio. The CuO/$CeO_2$ prepared using ball mill method showed the higher activity than those prepared using impregnation method. The catalytic activity increased with an increase in the CuO loading ratio, 10 wt% loaded CuO/$CeO_2$ catalyst giving the highest activity. In addition, the promoting of 10 wt% loaded CuO/$CeO_2$ catalyst with $Fe_2O_3$ and CoO enhanced the dispersion of CuO and then increased the catalytic activity.