• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.1
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• pp.21-27
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• 2016

Global warming due to greenhouse gas emissions is considered as a major problem worldwide, and many countries are making great efforts to reduce carbon dioxide emissions. Many technologies in post-combustion, pre-combustion and oxy-fuel combustion $CO_2$ capture have been developed. Among them, a hybrid pre-combustion $CO_2$ capture system of a water gas shift (WGS) reactor and a membrane gas separation unit was investigated. The 2 stage WGS reactor integrated high temperature shift (HTS) with a low temperature shift (LTS) was used to obtain a higher CO conversion rate. A Pd/Cu dense metal membrane was used to separate $H_2$ from $CO_2$ selectively. The performance of the hybrid system in terms of CO conversion and $H_2$ separation was evaluated using a 65% CO, 30 % $H_2$ and 5% $CO_2$ gas mixture for applications to pre-combustion $CO_2$ capture. The experiments were carried out over the range of WGS temperatures ($200-400^{\circ}C$), WGS pressures (0-20bar), Steam/Carbon (S/C) ratios (2.5-5) in a feed gas flow rate of 1 L/min. A very high CO conversion rate of 99.5% was achieved with the HTS-LTS 2 stage water gas shift reactor, and 83% $CO_2$ was concentrated in the retentate using the Pd/Cu membrane.

• Journal of the Korean Institute of Gas
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• v.15 no.3
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• pp.39-46
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• 2011

This study investigates the effects of the DME and n-Butane mixture and of the stratification on combustion characteristics of HCCI engine by chemical reaction calculation. First, the existing DME reaction scheme and n-Butane is combined to make new chemical reaction model, then validating the effectiveness of new scheme. Furthermore, this study verify the HCCI combustion characteristics according to the changes of DME and n-Butane mixture ratio, which shows different auto ignition characteristics. Finally, it confirms the effects of stratification of mixture fuel on the reduction of pressure rise rate.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 1999.04a
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• pp.11-11
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• 1999

액체 램제트 연소기는 흡입공기와 분무, 혼합 그리고 이에 따른 연소 등 일련의 과정에 따라 다수의 복잡한 현상들이 상호 밀접하게 관련되어 있다. 본 연구에서는 액체 램제트 연소기내의 유동특성을 파악하기 위해서 2차원 및 3차원 연소기 형상에 대해서 수치적 실험을 수행하였으며, 격자구성은 연소기에 공기를 공급하고 연료를 분무하는 공기 유입관 영역과 연소실 영역, 그리고 출구 대기 영역으로 나누어 독자적으로 격자를 생성시켰다. 2차원과 3차원 유동해석을 비교하였고 분무모델의 적용에 따른 연소특성 및 분사위치에 따른 연소특성을 비교하였다. 유동해석 결과 2차원과 3차원의 유동특성은 달랐으며, 분무모델을 적용해야 정확한 연소 유동 현상을 예측할 수 있음을 알 수 있었다. 그리고 유입관의 안쪽에 연료의 분사위치를 준 경우가 연소의 안정화에 필요한 재순환영역으로의 연료의 혼합이 잘 되어 유입관 바깥쪽에 연료를 분사시키는 것보다 좋은 분사위치임을 알 수 있었다.

• Korean Chemical Engineering Research
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• v.47 no.6
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• pp.734-739
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• 2009

Characteristics of pyrolysis, partial oxidation, combustion of chlorella, which is one species of micro-algae, were determined by using thermobalance reactor(I.D. 5.5 cm, Height 1 m). Effect of reaction temperature($500{\sim}800^{\circ}C$), water content in chlorella(0~60%), and oxygen content(0~21vol%) on thermal decomposition of chlorella were also determined and analyzed to investigate the kinetic characteristics of pyrolysis, partial oxidation and combustion. As the temperature and partial pressure increases, the carbon conversion increases. In case of pyrolysis, carbon conversion and reactivity sharply decreased with increasing moisture content. However, carbon conversion and reactivity decreased at 60% water content in case of partial oxidation and combustion. As reaction temperature and oxygen content increased, carbon conversion increased and the combustion reaction rate equation for chlorella has been presented. $\frac{dX}{dt}=(7.41{\times}10^{-1})$exp$\left(-\frac{19600}{RT}\right)(P_{O_{2}})^{0.209}(1-X)^{2/3}$.

• 한국연소학회:학술대회논문집
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• 2006.10a
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• pp.20-26
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• 2006

This study investigated on the conversion of nitrogen component in ammonia gas to control fuel-NOx. Control conditions were found to suppress the production of NOx in the catalytic combustion of the gasified fuels. Also, the results would provide the basis of the theoretical study on fuel-NOx generation mechanism.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1997.10a
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• pp.93-98
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• 1997

도시폐기물의 효율적인 소각 처리를 위해서 폐기물 처리량 50 ton/day의 화격자 소각로를 대상으로 화학반응을 고려하여 연소실 내부의 열유동 현상을 전산모사하였다. 수치해석 프로그램으로 상용코드인 PHOENICS를 사용하여 3차원 모사를 하여 실험으로 파악할 수 없는 연소실 내부의 유동 및 폐기물과 산화제와의 반응을 계산하였다. 건조부, 주연소부, 후연소부에 1차연소용공기, 연료의 분포 및 폐기물의 발열량이 노내 열유동 현상에 미치는 영향을 조사하였다. 1차연소용 공기의 분포에 따라 노내 유동장의 형태에 변화가 있었으며, 벽면에서의 복사열전달을 고려한 경우 2차연소실과 출구근처에서 온도분포가 파일롯트 플랜트 실험결과와 잘 일치하는 r서으로 나타났다.

• Aerospace Engineering and Technology
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• v.11 no.1
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• pp.126-134
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• 2012

The Single Species, Unreacted Flow Model which is effectively applicable on the computational analysis of rocket exhaust flow is introduced in this paper. The basic concept of this model had been originated from chemically frozen analysis of hot air but it was complemented by compensating molecular weight and specific heat which was obtained CEA code analysis of exhaust plume. Comparing single species, unreacted model with the finite chemistry model, unreacted model can reduce calculation time to 1/5 while it makes similar simulation results.

• 한국연소학회:학술대회논문집
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• 2003.12a
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• pp.287-298
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• 2003

A numerical investigation of a catalytically stabilized thermal (CST) combustor was conducted for a multi-channel catalyst bed, and both the catalyst bed and thermal combustor were simultaneously modeled. The numerical model handled the coupling of the surface and gas reaction in the catalyst bed as well as the gas reaction in the thermal combustor. The behavior of the catalyst bed was investigated at a variety of operating conditions, and location of the flame in the CST combustor was investigated via an analysis of the distribution of CO concentration. Through parametric analyses of the flame position, it was possible to derive a criterion to determine whether the flame is present in the catalyst bed or the thermal combustor for a given inlet condition. The results showed that the maximum inlet temperature at which the flame is located in the thermal combustor increased with increasing inlet velocity.

• Proceedings of the KAIS Fall Conference
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• 2008.11a
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• pp.394-396
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• 2008

주요 온실가스인 이산화탄소를 회수 및 저장(Carbon Capture and Storage)하는 기술은 주로 적은 $CO_2$농도를 가지는 연소후 포집공정이 개발 및 적용되었으나, 최근에는 보다 적극적으로 이산화탄소를 분리하기 위하여 연소전 석탄가스화복합발전(IGCC)과 같은 공정에 적용하여 반응공정 중에 생성되는 높은 농도의 $CO_2$를 분리하는 공정이 선진국을 중심으로 활발히 연구가 진행되고 있다. 본 연구에서는 고압의 연소전 조건에서 아민계보다 흡수속도는 느리나 생성가스에 유입되는 $O_2$, SOx, NOx에 의한 부반응 현상, 휘발에 의한 손실, 열적 열화현상이 나타나지 않는 알칼리염계 흡수제의 $CO_2$ 흡수특성에 대하여 연구하였다.

• Journal of the Korean Society of Propulsion Engineers
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• v.22 no.6
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• pp.72-83
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• 2018

In this study, a series of CFD analyses were carried out for a hydrogen rocket combustor with a single shear coaxial injector. A hybrid RANS/LES approach was used for the turbulent combustion analysis with a two-dimensional axisymmetric configuration. Three reaction mechanisms, three spatial discretization methods, and three levels of grid resolution were compared to determine an appropriate CFD approach. The performance of the CFD prediction were investigated by comparing the wall heat flux with experimental data. Investigation of the flow field results provides an insight into the characteristics of the turbulent reacting flow of a rocket combustor with a shear coaxial injector.