• Resources Recycling
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• v.16 no.6
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• pp.28-33
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• 2007

Coal is the most abundant energy source and deposited in every area of world. Combustion process with lower efficiency has been mainly used. Therefore, implementation of more efficient technologies, involving gasification, combined cycles and fuel cells, would be a key issue in the plans for more efficient power generation. In these technologies, gasification has been studied for decades. However, coal gasification to high value combustible gas such as hydrogen and carbon monoxide is focused again due to high oil price. The gaseous product, called syngas, can be effectively utilized in a variety of ways ranging from electricity production to chemical industry (as feedstock). In this study, coal gasification with ultra high temperature steam has been performed. The effect of steam/carbon ratio on the produced gas concentrations, gasification rate and additional products like tar, ammonia and cyan compounds has been determined.

• Korean Chemical Engineering Research
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• v.50 no.6
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• pp.1034-1042
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• 2012

This study was performed by using an LFR (laminar flow reactor), which can be used to carry out different types of research on coal. In this study, an LFR was used to analyze coal flames, tar and soot yields, and structures of chars for two coals depending on their volatile content. The results show that the volatile content and oxygen concentration have a significant effect on the length and width of the soot cloud and that the length and width of the cloud under combustion conditions are less than those under a pyrolysis atmosphere. At sampling heights until 50 mm, the tar and soot yields of Berau (sub-bituminous) coal, which contains a large amount of volatile matter, are less than those of Glencore A.P. (bituminous) coal because tar is oxidized by the intrinsic oxygen component of coal and by radicals such as OH-. On the other hand, at sampling heights above 50 mm, the tar and soot yields of Berau coal are higher than those of Glencore A.P. coal by reacted residual volatile matter, tar and light gas in char and flame. With above results, it is confirmed that the volatile matter content and the intrinsic oxygen component in a coal are significant parameters for length and width of the soot cloud and yields of the soot. In addition, the B.E.T. results and the images of samples (SEM) obtained from the particle separation system of the sampling probe support the above results pertaining to the yields; the results also confirm the pore development on the char surface caused by devolatilization.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.10
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• pp.1065-1073
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• 2006

The unturned carbon in fly ash, recently occurred in the coal-fired Yong Hung power station, caused some problems in ash utilization and boiler efficiency. This paper describes the analysis of unburned carbon and six coals, some tests performed at Yong Hung Boiler, and the results of combustion modification for the reduction of unburned carbon in fly ash. From the physical and chemical analysis of unburned carbon in fly ash, most particles were turned out to be hollow cenosphere and agglomerated soot particles. The sooting potential from six coals used in the plant were investigated with CPD(Chemical Percolation Devolatilization) model. The results showed that the higher potential was presented to Peabody, Arthur, Shenhua coals rather than other coals. It was necessary to measure the coal flow rates at each coal feeding pipe for four burner levels since they affect the extent of mixing of soot with oxidant, in turn, the oxidation rate of soot particles. The unbalance in coal flow rate was found in several coal pipes. We successfully reduced unturned carbon in ash by increasing the excess air and changing the SOFA's yaw angle.

• Bulletin of the Korean Institute for Industrial Safety
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• v.1 no.1
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• pp.1-6
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• 2001

생활양식의 변화와 정밀산업의 발달로 고체 덩어리나 입자를 분쇄하여 분체의 형태로 사용, 취급, 저장하는 빈도가 증가하고 있으며, 이들 중 분체가 가연성인 경우에는 공기 또는 산소와의 접촉면적이 커서 비교적 쉽게 착화할 뿐 아니라 급격한 연소를 일으켜 화재·폭발의 위험성이 항상 존재하고 있다고 할 수 있다. 이와 같은 위험성을 가지는 가연성 분진에는 소맥분, 전분, 사탕 등의 식료품을 비롯하여 가축용 사료분진, 각종금속, 플라스틱 및 화학제품 등의 가공용 분진, 약품, 연료로 사용되는 석탄 뿐 아니라 섬유부스러기, 연마시의 분진 등을 들 수 있다. 특히 최근에는 신소재로서의 기능성 물질과 전자재료의 개발이 활발하게 진행되어 이 분야에서 분체를 취급하는 공정도 증가하고 있는 실정이다.(중략)

• Clean Technology
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• v.19 no.1
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• pp.30-37
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• 2013

Low-rank coal with high water content (32.3 wt%) was dried by fry drying, and the fuel characteristics of the dried coal from which the oil was separated by using a high-speed centrifugal separator were analyzed. After fry drying for 6 min and 10 min, the water content decreased to 5.0 wt% and 4.2 wt% respectively. The higher calorific value (HCV) of the coal increased remarkably after fry drying, from 11,442.0 kJ/kg-wet. The oil content of the fry-dried coal was 15.0 wt% and it decreased with an increase in the reheating temperature: 9.7 wt% at $80^{\circ}C$ to 9.3 wt% at $100^{\circ}C$, and then to 8.5 wt% at $120^{\circ}C$. The recovered oil could then be reused. According to of thermogravimetric analysis (TGA), there was no difference in the weight loss patterns of the coal samples with different coal diameters at a reheating temperature of $120^{\circ}C$. This was because the amount of oil separated by the centrifugal separator was affected by the reheating temperature rather than the coal diameter. And derivative thermogravimetry (DTG) curves of raw coal before the fry-drying process, a peak is formed at $400^{\circ}C$ in which the volatile matter is gasified. In case of the fry-dried coal, the first peak is generated at $350^{\circ}C$, and the second peak is generated at $400^{\circ}C$. The first peak is caused by the oil that is replaced with the water contained in the coal during the fry-drying process. Further, the peaks of the coal samples in which the oil is separated at a reheating temperature of $80^{\circ}C$, $100^{\circ}C$, $120^{\circ}C$, respectively are smaller than that of the coal in which the oil is not separated, and this is caused by that the oil is separated by the centrifugal separator.

• Resources Recycling
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• v.20 no.1
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• pp.54-60
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• 2011

The spherical artificial aggregates (AAs) with a diameter of 8 mm, which contains fly ashes discharged from the fluidized bed combustion in a thermal power plant and clay were manufactured by direct sintering method at $1050{\sim}1250^{\circ}C$ for 10 minutes. The effect of fly ash contents on the bloating phenomenon in the AAs was analyzed. The AAs containing fly ash of the amount under 50 wt% showed the black-coring and bloating phenomena. The AAs containing fly ash of the amount over 5Owt%, however, the specific gravity was increased and the color of specimens fully changed to black. These color change phenomena were caused from the formation of FeO by the reduction reaction of almost $Fe_2O_3$ component by the excessive reducing atmosphere formed simultaneously with the rapid emission of the gases generated from the high contents of unburned carbon of with increasing the added fly ash amount. Specific gravity was decreased as fly ash contents increased in the case of sintering at the same temperature condition. Water absorption of all specimens except of the specimens containing 10 wt% fly ashes decreased with increasing sintering temperature. These were because a liquid phase was formed as the increasing the sintering temperature. In the case of the specimens manufactured in this study containing fly ashes discharged from the fluidized bed combustor in a the thermal power plant and 10~90 wt% of clay, the specific gravity was 0.9~1.8 and the water absorptivity was 8~60%, therefore it is considered that those results can be applied to the light or heavy aggregates.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.4
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• pp.272-277
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• 2009

Three dimensional numerical analysis for the coal fired boiler has been performed to investigate the effect of yaw angle variation of the secondary air nozzles on the combustion characteristics and NOx emission. It was found that the prediction gives a good agreement with plant data. The increase in yaw angle up to $20^{\circ}$ have results in the decrease in NOx emission at furnace exit and recirculation flow intensity, together with the increase of unburned carbon in ash. It also has been recognized the remarkably change in configuration of fire ball with increase in yaw angle. The results from this study would be valuable in the case of the combustion modification of the corner firing coal-fired utility boiler.

• Korean Chemical Engineering Research
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• v.47 no.5
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• pp.580-586
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• 2009

In this study, co-combustion characteristics of Chinese bituminous coal and North Korean anthracite were investigated using a 2 MWe scale circulating fluidized bed power plant. At first, the combustion efficiency of bituminous coal of China and Australia as a function of excess air ratio and temperature were observed. The results showed that the combustion efficiency was influenced by particle size and volatile content of coal, the combustion efficiency of Chinese bituminous coal was over 99.5%. The unburned carbon particles from fly ash and bottom ash were a content 5~7% and 0.3%, respectively. The combustion efficiency with the mixture ratio 20% of bituminous coal and anthracite decreased over 5% because of the increase of entrained particles by a small average particle size of anthracite in the combustor. However, the outlet concentration of $SO_2$ and $NO_x$ was not changed remarkably. The concentrations of the typical air pollutants such as $NO_x$ and $SO_2$ were 200~250 ppm($O_2$ 6%), 100~320 ppm($O_2$ 6%) respectively. The outlet concentration of $NO_x$ was decreased to 30~65% with $NH_3$ supplying rate of 2~13 l/min in SCR process. The $SO_x$ removal efficiency was up to 70% by in-furnace desulfurization using limestone with Ca/S molar of approximately 6.5. With wet scrubbing using $Mg(OH)_2$ as absorbent, the $SO_x$ removal efficiency reached 100% under near pH 5.0 of scrubbing liquid.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.6
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• pp.587-597
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• 2010

Air-staged combustion is known to be one of the techniques of NOx reduction. The objective of this study is to determine the optimal ratio of air flow distributed for CCOFA and SOFA; at this optimal ratio, the combustion and exhaust emission characteristics of a pulverized coal-fired boiler are maintained at a satisfactory level. A numerical investigation was performed at various airflow ratios of 16.7/83.3%, 25/75%, 50/50%, 75/25%, and 83.3/16.7%. An inert gas was considered as a substitute for air to isolate the effects of the cooling process and chemical reaction on NOx reduction; during NOx reduction in air-staged combustion, both the effects typically occur simultaneously. The results of our study show that the optimum condition, under which the maximum NOx reduction and highest boiler efficiency can be obtained, corresponds to the equal splitting of the over-fire air between CCOFA and SOFA.

• Applied Chemistry for Engineering
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• v.21 no.5
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• pp.553-558
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• 2010

To solve the problems of the low combustion activity of Korean anthracite and the abundant loss of unburned carbon in fly ash, pellet coal was fabricated from coal fines and fly ash, and the mixed combustion of coarse coal with the pellet coal was examined in the circulating fluidized bed combustor of a 0.1 MW scale test unit. In the combustion of the raw coal only, the significant amount of coal fines was entrained, resulting in overheat at the top of the combustor. With the coarse coal that most fines were eliminated, however, the combustion temperature was maintained stable. The mixed combustion of coarse and raw coals was also feasible even though it often went unstable. The mixed combustion of the coarse coal with the pellet coal was as stable as the coarse coal combustion, showing a promise that the combustion of the Korean anthracite in commercial circulating fluidized bed boilers could be further enhanced.