• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.41 no.7
• /
• pp.547-551
• /
• 2013

Mass averaged and core enthalpy in the arc jet flow are obtained experimentally. The experiment is made for the 150kW Huels type arc-jet applying the test condition for the research of gasturbine engine injection cooling technique. The mass averaged enthalpy value determined by the sonic throat method is 5.5MJ/kg. The core enthalpy value determined by the heat transfer rate method is 14.3MJ/kg. Based on result of experiment, the ratio of the core to mass averaged enthalpies is 2.6.

• Journal of the Korean Chemical Society
• /
• v.43 no.6
• /
• pp.621-627
• /
• 1999

A new predictive scheme to calculate hydrocarbon enthalpies of formation from ab initio total energy calculations is described. The method improves a previous computation procedure (based on the total number of atoms) through the inclusion of bond parameters. Present results are good enough and the average absolute errors in the computed values of enthalpies of formation are lower than the experimental uncertainties. Some possible extensions are pointed out in order to reach definitive conclusions about the proposed methodology.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2011.11a
• /
• pp.224-227
• /
• 2011

In order to determine the enthalpy profile in the high temperature transpiration cooling test facility for the air-breating engine compartments, theoretical calculation and measurement for the flow of the test section are performed. The mass averaged enthalpy value determined by the heat balance and sonic throat methods is 10 MJ/kg. The centerline enthalpy value measured using the slug type copper calorimeter is 15 MJ/kg. Typically, the ratio of centerline and mass averaged enthalpy should be varies from 1.4 to 4. This facility has lower bound of enthalpy profile. It will be effective in testing of high temperature transpiration cooling.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.5 no.1
• /
• pp.35-43
• /
• 1993

A numerical model for the solidification of binary mixture is proposed. Numerical model, which employs enthalpy method, is modified from Continuum model, that is, improved relation is proposed for the Enthalpy - Temperature - Concentration - Liquid Mass Fraction. One dimensional example was selected to verify the proposed model. The results show that the new relation can be applied successfully to the solidification or melting of binary mixture.

• Korean Journal of Food Science and Technology
• /
• v.25 no.4
• /
• pp.400-403
• /
• 1993

Gelatinization degrees of torn and waxy corn starches in the low-moisture environment were determined by DSC thermogram and enzymatic analysis, the results were compared each other As the moisture content increased from 20% to 70%, the enthalpy of endothermic peak of starch increased linearly in DSC thermograms. When the moisture content exceeded above 70%, the DSC enthalpy of starch remained constant in DSC thermogram. The enthalpies for gelatinization of corn and waxy corn starches were 3.23 cal/g and 4.2 cal/g, respectively. When gelatinization degrees of starches were measured by enzymatic analysis, the gelatinization degree increased linearly as the moisture content increased from 20% to 80%. A linear correlation between DSC and enzymatic analysis was obtained only when the moisture content was under 70%.

• Proceedings of the Korean Radioactive Waste Society Conference
• /
• 2016.05a
• /
• pp.205-206
• /
• 2016

• Proceedings of the KSME Conference
• /
• 2007.05b
• /
• pp.2901-2906
• /
• 2007

A solver for icing and condensation of water has been developed. The phase change process was solved by the enthalpy method. For the code validation, the temperature and the phase change from water to ice of the driven cavity were calculated. Also, the melting process of the frost on the windshield glass of an automobile has been simulated. The calculation showed a good agreement with analytical solution and other numerical results. Using the present validated code, the condensation of water vapor has been first tried. The computed results provided some physical features of condensation phenomena even though experimental data and other numerical data were not available. For future work, it is recommended to throughly investigate the effects of boundary conditions on the solution.

• Resources Recycling
• /
• v.27 no.2
• /
• pp.63-67
• /
• 2018

Gibbs free energy is a measure of relative stability among substances. Since the nature of the ions in aqueous solution is diverse, their thermodynamic data at extensive experimental conditions is scarce. In this work, the calculation procedure was introduced to obtain the absolute and conventional standard molar enthalpies and entropies of hydration of ions from the standard enthalpies and entropies of formation of hydrated ions. The application of correspondence principle to estimate thermodynamic data at high temperature was explained.

• Proceedings of the Korean Nuclear Society Conference
• /
• 2002.10a
• /
• pp.61.2-61
• /
• 2002

• Korean Chemical Engineering Research
• /
• v.55 no.5
• /
• pp.660-667
• /
• 2017

Equilibrium data of the mixture is essential in the design and operation of separation equipment such as distillation or extraction in chemical processes. These equilibrium data can be obtained through experiments or by calculations using the known binary parameters and the thermodynamic models. Generally, to obtain these parameters, phase equilibrium experimental data such as gas-liquid and liquid-liquid are used. In this study, the excess enthalpy of the mixture was measured using the flow type microcalorimeter which is a simpler method than phase equilibria experiments, and the parameters of various theories were obtained by using this data. In order to investigate the relationship between carbon chain length, enthalpy and binary parameters in the alkane system, excess enthalpies for the n-hexane + alkane (n-pentane, n-heptane, n-octane and n-dodecane) were measured at 298.15 K and the banary interaction parameters of Wilson, NRTL, and UNIQUAC were obtained from the experimental data. In addition, we wanted to obtain basic information on the interaction and association phenomena of the system including electrolyte applicable to various fields by using the excess enthalpy experimental data and the existing theory. First, we investigated the excess enthalpy for the NaOH / Water / Ethanol system as a basic experiment and examined the applicability using the electrolyte-NRTL (eNRTL) theory.