• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.11a
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• pp.224-227
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• 2011

In order to determine the enthalpy profile in the high temperature transpiration cooling test facility for the air-breating engine compartments, theoretical calculation and measurement for the flow of the test section are performed. The mass averaged enthalpy value determined by the heat balance and sonic throat methods is 10 MJ/kg. The centerline enthalpy value measured using the slug type copper calorimeter is 15 MJ/kg. Typically, the ratio of centerline and mass averaged enthalpy should be varies from 1.4 to 4. This facility has lower bound of enthalpy profile. It will be effective in testing of high temperature transpiration cooling.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.41 no.7
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• pp.547-551
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• 2013

Mass averaged and core enthalpy in the arc jet flow are obtained experimentally. The experiment is made for the 150kW Huels type arc-jet applying the test condition for the research of gasturbine engine injection cooling technique. The mass averaged enthalpy value determined by the sonic throat method is 5.5MJ/kg. The core enthalpy value determined by the heat transfer rate method is 14.3MJ/kg. Based on result of experiment, the ratio of the core to mass averaged enthalpies is 2.6.

• Analytical Science and Technology
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• v.22 no.2
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• pp.159-165
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• 2009

The thermochromism of fluoran has been examined. The DCF exists as a colorless lactone in aprotic solvents. However, the DCF exists in the form of an equilibrium mixture of a colored zwitter-ion and a colorless lactone in protic solvents. When an acid is added to the solution, the DCF exists an equilibrium mixture as a colorless lactone and a colored cation even in aprotic solvents. In order to understand the interaction between the DCF and the solvent, absorption spectra of the DCF in various solvents were measured. The thermodynamic parameters of the DCF have also been investigated. From the variation of absorbance with temperature, the standard enthalpy changes ${\Delta}H^0$ of the equilibrium between the lactone and the zwitter-ion in various solvents have been determined. The standard enthalpy change ${\Delta}H^0$ is approximately -2.0 kJ/mol in protic solvents. In acidic solution, the standard enthalpy change is measured to be to zero in protic solvents within the experimental error. When the carboxylic group is protonated in acidic solution, a poor interaction between the dye and the solvent is expected.

• Korean Chemical Engineering Research
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• v.55 no.5
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• pp.660-667
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• 2017

Equilibrium data of the mixture is essential in the design and operation of separation equipment such as distillation or extraction in chemical processes. These equilibrium data can be obtained through experiments or by calculations using the known binary parameters and the thermodynamic models. Generally, to obtain these parameters, phase equilibrium experimental data such as gas-liquid and liquid-liquid are used. In this study, the excess enthalpy of the mixture was measured using the flow type microcalorimeter which is a simpler method than phase equilibria experiments, and the parameters of various theories were obtained by using this data. In order to investigate the relationship between carbon chain length, enthalpy and binary parameters in the alkane system, excess enthalpies for the n-hexane + alkane (n-pentane, n-heptane, n-octane and n-dodecane) were measured at 298.15 K and the banary interaction parameters of Wilson, NRTL, and UNIQUAC were obtained from the experimental data. In addition, we wanted to obtain basic information on the interaction and association phenomena of the system including electrolyte applicable to various fields by using the excess enthalpy experimental data and the existing theory. First, we investigated the excess enthalpy for the NaOH / Water / Ethanol system as a basic experiment and examined the applicability using the electrolyte-NRTL (eNRTL) theory.

• Proceedings of the Korean Society for Agricultural Machinery Conference
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• 2002.02a
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• pp.223-229
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• 2002

패드엔팬을 이용하여 물 공급량, 팬 회전속도의 변화에 따른 온실 냉방효과 시험한 결과를 요약하면 다음과 같다. 가. 패드에 흐르는 물 공급량별로 일중 11:00-16:00경에 물 공급량이 분당 60$\ell$이상 공급하면 8.0~9.5$^{\circ}C$의 온도차를 낼 수 있으며, 팬을 1170rpm으로 회전시킬 경우 6.0~9.$0^{\circ}C$의 온도차를 낼 수 있었다. 나. 온실과 팬출구 공기의 온도차는 일중 14:30~16:00 경에 60$\ell$이상의 물을 패드에 공급하는 경우 6.0~7.8$^{\circ}C$ 온도 강하 효과가 있고 팬을 1170rpm으로 회전시킬 경우에는 외기온 28$^{\circ}C$일 때 3$0^{\circ}C$이하로 온도를 강하시킬 수 있었다. 다. 패드에 흘리는 물의량을 60 $\ell$/min 이상을 공급하여 주면 30분당 20~28$\ell$의 물을 증발시킬 수 있다. 배출팬 회전속도가 1170rpm일 경우에 30분당 20~30$\ell$의 물을 증발시키는 것으로 나타났다. 라. 본시험에 사용된 패드엔팬의 흡.배기의 엔탈피변화는 8:30이전에는 흡기가 배기보다 온도가 낮아 엔탈피가 양(+)의 값을 나타났고, 8:30 이후에는 흡기가 배기 보다 온도가 높아 -2.0~-4.OkJ/kg의 엔탈피 차만큼 냉각효과가 있었으며, 냉방효율을 65~80% 수준으로 나타났다. 마. 본시험결과로 패드엔팬의 냉기 공급방식만 개선된다면 이동식인 박스형 패드엔팬도 냉방장치로 사용 가능할 것으로 판단된다.

• 한국전산유체공학회:학술대회논문집
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• 2009.04a
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• pp.277-282
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• 2009

A temperature equation which is derived from an enthalpy transport equation by using an assumption of a constant specific heat is very attractive for analyses of heat and fluid flows. It can be used for an analysis of a solid-fluid conjugate heat transfer, and it does not need a numerical method to find temperature from a temperature-enthalpy relation. But its application is limited because of the assumption. A new method is derived in this study, which is a temperature-explicit formulation of the energy equation. The enthalpy form of the energy equation is used in the method. But the final discrete form of the equation is expressed with temperature. It can be used for a solid-fluid conjugate heat transfer and multiphase flows. It is found by numerical tests that it is very efficient and as accurate as the standard enthalpy formulation.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.539-539
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• 2012

전북대학교 고온플라즈마 응용연구센터는 교육과학기술부 기초연구사업 중 고가연구장비 구축사업의 일환으로, 고 엔탈피, 초음속 유동 환경을 모사하여, 항공우주, 군사기기, 핵융합 분야 등의 고온 재료 개발을 위한 기초 연구 장치로써, 0.4MW급 플라즈마 풍동 장치를 구축하고 있다. 0.4MW 플라즈마 풍동 장치의 플라즈마 발생부는 DC 전원 공급장치와 디스크 형태의 양극과 음극 사이에 동일 형태의 간극을 삽입한 0.4MW급 분절형 아크 플라즈마 토치로 구성되었으며, 토치에서 발생된 아크 플라즈마는 노즐을 통과하며 마하 2~4의 초음속을 나타내도록 설계 제작되었다. 시험 챔버는 노즐에서 나온 초음속 플라즈마의 특성 및 재료 시험을 위한 3차원 이송식 기판이 장착되어 있으며, 고 엔탈피 유동을 관측하기 위한 광학창을 구비하였다. 시험 챔버 하류에는 유동 안정을 위한 디퓨저(diffuser)가 설치되어 있으며, 디퓨저(diffuser)로부터 배출되는 고온가스는 열교환기를 통해 냉각된 후 진공펌프를 통해 대기로 배출되게 된다. 장치의 압력조절을 위하여 $1,000m^3/min$의 용량의 진공펌프 시스템이 설치될 예정이며 가스공급장치, 냉각수 공급장치, 디퓨져, 열교환기는 1MW급 용량으로 설계 제작되었다. 본 장치는 400kW의 전원 공급, 15 g/s의 공기유량 주입 시 약 13 MJ/kg의 고엔탈피를 가진, mach 2~4의 초음속 유동을 나타내는 것을 특징으로 한다.

• Korean Chemical Engineering Research
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• v.50 no.4
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• pp.666-671
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• 2012

Gas hydrates are inclusion compounds formed when small-sized guest molecules are incorporated into the well defined cages made up of hydrogen bonded water molecules. Since large masses of natural gas hydrates exist in permafrost regions or beneath deep oceans, these naturally occurring gas hydrates in the earth containing mostly $CH_4$ are regarded as future energy resources. The heat of dissociation is one of the most important thermal properties in exploiting natural gas hydrates. The accurate and direct method to measure the dissociation enthalpies of gas hydrates is to use a calorimeter. In this study, the high pressure micro DSC (Differential Scanning Calorimeter) was used to measure the dissociation enthalpies of methane, ethane, and propane hydrates. The accuracy and repeatability of the data obtained from the DSC was confirmed by measuring the dissociation enthalpy of ice. The dissociation enthalpies of methane, ethane, and propane hydrates were found to be 54.2, 73.8, and 127.7 kJ/mol-gas, respectively. For each gas hydrate, at given pressures the dissociation temperatures which were obtained in the process of enthalpy measurement were compared with three-phase (hydrate (H) - liquid water (Lw) - vapor (V)) equilibrium data in the literature and found to be in good agreement with literature values.

• Journal of the Korean Chemical Society
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• v.48 no.2
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• pp.123-128
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• 2004

Quantum chemical quantities, enthalpy of formation(${\Delta}H_f$), HOMO and LUMO energy, and dipole moment(${\mu}_D$) were acquired by AM1, PM3, and ZINDO/1 methods for polyamines and imidazole derivatives. The investigation of the inhibitory activity on some Ni(II) complexes with polyamines and imidazole derivatives is performed by ZINDO/1 calculations. It was found that experimental inhibitory activity(IA) appeared when the value of net charge and enthalpy of formation were over 0.03 and -300 eV, respectively for Ni(II) complexes. These results showed that the Ni(II) complexes have exception on the following very unstable compounds: square pyramidal [Ni(dpt)(tn)])]$^{2+}$(dpt=3,3'-diaminodipropylamine)(tn=1,3-diaminopropane) and distorted tetrahedral [Ni(N-PropIm))$_2$(NCS))$_2$](N-PropIm=N-Propylimidazole).

• Korean Journal of Food Science and Technology
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• v.21 no.4
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• pp.556-561
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• 1989

Thermal properties of amylose-lysolecithin (AL) complex, amylose content and effect of lysolecithin on the gelatinization of rice starch were investigated by Differential Scanning Calorimetry (DSC). The melting temperature of AL complex was near to $108.5^{\circ}C$ and the melting enthalpy was about 1.0cal/g. The gelatinization temperature of rice starch was not affected by adding lysolecithin. However, the enthalpy of gelatinization was decreased. The amylose contents in rice varieties were calculated from melting enthalpy of AL complex. The amylose contents for Indica and Japonica types of rice were in the range of 16-19%, which were in good agreement with those determined by iodine binding method. Significant differences were not observed in the amylose contents between Indica and Japonica varieties.