• Title/Summary/Keyword: 에메랄드

Search Result 17, Processing Time 0.023 seconds

Spectroscopic Characteristics of synthetic and natural emerald by heat treatment (열처리에 따른 합성과 천연 에메랄드의 분광특성분석)

  • Hwoang, Hye-Kyung;Ahn, Yong-Kil;Seo, Jin-Gyo;Park, Jong-Wan
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.11 no.1
    • /
    • pp.29-36
    • /
    • 2010
  • The spectroscopic characteristics of synthetic and natural emeralds were investigated by UV-Vis and FTIR spectroscopy before and after heat treatment. The Mo and Co for synthetic flux and C1 for synthetic hydrothermal emeralds have been detected by X-ray fluorescence analysis. In the region of UV-Visible, the absorption of emerald from Colombia was generally increased after the heat treatment. The peak which related to C1 component in the $3000-2600cm^{-1}$ was shown in the hydrothermal synthetic emeralds by FTIR spectroscopy. The $2358cm^{-1}$ peak which originates from $CO_2$ was decreased after the heat treatment in the natural emerald. This was corresponded with the changes of gas element after heat treatment.

Growth of Synthetic Emerald Single Crystal by Flux Method (Flux법에 의한 합성 에메랄드 단결정 육성)

  • Park, Sun-Min;Lee, Chul-Tae;Kim, Ho-Kun
    • Applied Chemistry for Engineering
    • /
    • v.7 no.1
    • /
    • pp.34-42
    • /
    • 1996
  • Growth of synthetic emerald [($(BeO)_3(Al_{2-x}Cr_xO_3)(SiO_2)_6$] single crystals was carried out by flux method. In this study, the starting materials were prepared by stoichiometric mixing of BeO, $Al_2O_3$ and $SiO_2$ as reaching components. The conditions for the growth of synthetic emerald single crystals are as follows : temperature range ; $1150{\sim}900^{\circ}C$, cooling rate ; 2, 4, $10^{\circ}C/hr$, flux ; $Li_2CO_3$, $V_2O_5$, dopant ; $Cr_2O_3$. The sizes of $Cr_2O_3$emerald single crystals depending on 2, 4, $10^{\circ}C/hr$ cooling rates. The obtained emerald single crystal was characterized and the following results were obtained : lattice parameter : a=0.921nm, c=0.917nm, crystal system ; hexagonal, crystal size ; max. $0.80{\times}0.95mm^2(c{\times}m)$, orientation ; (1000), $m(10{\bar{1}}0)$.

  • PDF

Application of FTIR on the Study of Spectroscopic Characteristics on Emerald from Itabira, Brazile (FTIR을 이용한 브라질 Itabira 지역 에메랄드의 분광학적 특성 연구)

  • Lim, Ye-Won;Jang, Yun-Deuk;Kim, Jong-Rang;Kim, Hyeong-Soo;Kim, Jong-Gun;Kim, Jeong-Jin
    • Journal of the Mineralogical Society of Korea
    • /
    • v.21 no.4
    • /
    • pp.355-364
    • /
    • 2008
  • Emerald deposit located on Itabira, Brazil is one of the major one in the world. We applied three different analytical approaches on Itabira emerald samples, (1) perpendicular to the c-axis, (2) parallel to the c-axis, (3) emerald pallet mixed with KBr, using Fourier Transform Infrared (FTIR) spectroscopy, to understand and compare spectroscopic characteristics of three Itabira emerald samples. Occurrence of $5,271\;cm^{-l}$ and $1,638\;cm^{-l}$ absorption peaks within $H_2O$-related range indicates that the samples belong to Type-II emerald. These emerald samples also display strong absorption peak generated from Type-IIa emerald preserving $H_2O-Na-H_2O$ sequence. $CO_2$- and Cl-related absorption peaks observed within specific range except for $H_2O$-related range. These observations and results suggest that FTIR analysis can be used for not on1y classification of emerald types, but also prediction of $Na_2O$ content within the emerald through comparison of relative peak intensity.

Study on the Copper-Arsenic Green Pigments used on Shamanic Paintings in the 19~20th century (19~20세기 무신도 등에 사용된 구리-비소 녹색 안료에 대한 연구)

  • Oh, Joon Suk;Choi, Jung Eun;Choi, Yoon Hee
    • Journal of Conservation Science
    • /
    • v.31 no.3
    • /
    • pp.193-214
    • /
    • 2015
  • The green pigments of shamanic paintings (83 items) in the 19~20th century were analyzed with X-ray fluorescent spectrometer(XRF), scanning electron microscopy (SEM) and fourier transform infrared spectroscopy (ATR-FTIR). In 60 items, copper and arsenic were detected in green pigments of the paintings by XRF spectra. Cu $K{\alpha}$/As $K{\beta}$ (peak intensity ratio of copper and arsenic) of shamanic paintings of Bokgaedang (shrine), solemn paintings (romance of three kingdoms) of Donggwanwangmyo and unknown enshrined place were 5.93~12.04 and higher compared to 5.67-6.26 of standard emerald greens and 4.01~7.89 of remaining shamanic paintings. The SEM images of crystal forms of copper-arsenic green pigments were various. Crystal forms were divided into oval and round spherulite with intersecting plate crystals and spherulite with agglomerate plate crystals. The crystals of the latter were found in shamanic paintings of Bokgaedang (shrine), solemn paintings (romance of three kingdoms) of Donggwanwangmyo and unknown enshrined place and the former were found in the rest of shamanic paintings. Copper-arsenic green pigments of shamanic paintings were identified as Scheele's green from shamanic paintings of Bokgaedang (shrine) and romance of three kingdoms. Emerald green from the rest of shamanic paintings by ATR-FTIR. From analytical results, it is confirmed that Scheele's green of shamanic paintings of Bokgaedang and romance of three kingdoms was used in the 1850s~1870s and emerald green had been widely used from late 19th century to 1970 in the rest of shamanic paintings.

니스, 지중해의 바람과 파도로 '국제기업도시' 명성에 도전

  • Sin, Seon-Mi
    • 주택과사람들
    • /
    • s.192
    • /
    • pp.100-105
    • /
    • 2006
  • '낭만' 하면 떠오르는 나라 프랑스에서도 손꼽히는 지중해 최대의 휴양 도시, 니스! 리비에라의 여왕이란 말이 있을 정도로 니스는 유럽인들이 최고로 선호하는 휴양지 중 하나다. 에메랄드빛 바다와 청명한 하늘, 한겨울에도 영상 10℃를 넘는 기온, 양호한 자연 환경, 아름다운 경치로 인해 니스에는 사시사철 관광객이 몰려든다.

  • PDF

Geology and Mineral Resources of Colombia (콜롬비아 지질 및 광물자원 현황)

  • Koh, Sang-Mo;Lee, Gill-Gae;You, Byoung-Woon
    • Journal of the Mineralogical Society of Korea
    • /
    • v.24 no.3
    • /
    • pp.245-252
    • /
    • 2011
  • 콜롬비아는 안데스 산맥의 북단에 위치하며 NS 방향의 단층대를 기준으로 지질 환경의 차이가 크다. 단층대를 기준으로 동부지역은 원생대 변성암류와 이를 피복하는 고생대 변성퇴적암류가 주로 분포하며, 서부 지역은 고생대 퇴적암류, 중생대 화성암류, 제 3 기 화산양류 및 퇴적암류가 주로 분포한다. 지화학이상대는 6개 그룹으로 분류되며, 철 (Fe), 귀금속(Au, Ag, Pt), 기초금속(Cu, Pb, Zn), 희유금속(Sn, Cr, Co, Mn, Mo, Ni, Nb, W, V, Mg, Ti, Be, REE, Ga, Zr, Hf, Se, Te, Ta, Cd, In, Li 등) 빛 핵원료자원인 U 이상대로 구성된다. 콜롬비아의 주요 부존자원은 석탄, 니켈, 금 및 에메랄드이다. 에메랄드, 석탄 및 니켈은 세계적인 매장규모와 생산량을 보인다. 콜롬비아는 탐사가 거의 수행되지 않은 지역이 전 국토의 49%에 달해 광물부존 잠재성은 현재보다 크게 높을 것으로 보인다. 따라서 최근 콜롬비아와의 광물자원 협력이 강화되고 있는 시점에서 미탐사 지역을 대상한 공동탐사를 지화학 이상대가 확인된 지역을 중심으로 수행하여 신규광체를 확보하고, 광물자원 협력을 강화함으로써 공동개발 여건을 마련할 필요가 있다고 판단된다.