• Title/Summary/Keyword: 에너지 전달

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Application of Hierarchical ZnCo2O4 Hollow Nanofibers for Anode Materials in Lithium-ion Batteries (계층적 구조를 갖는 중공형 ZnCo2O4 나노 섬유의 리튬이온배터리 음극소재 적용)

  • Jeong, Sun Young;Cho, Jung Sang
    • Korean Chemical Engineering Research
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    • v.57 no.4
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    • pp.559-564
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    • 2019
  • Hierarchical $ZnCo_2O_4$ hollow nanofibers were prepared by electrospinning and subsequent heat-treatment process. The spinning solution containing polystyrene (PS) nanobeads was electrospun to nanofibers. During heat-treatment process, PS nanobeads in the composite were decomposed and therefore generated numerous pores uniformly in the structure, which facilitated the heat transfer and gas penetration into the structure. The resulting hierarchical $ZnCo_2O_4$ hollow nanofibers were applied as an anode material for lithium-ion batteries. The discharge capacity of the nanofibers was $815mA\;h\;g^{-1}$ ($646mA\;h\;cm^{-3}$) after the 300th cycle at a high current density of $1.0A\;g^{-1}$. However, $ZnCo_2O_4$ nanopowders showed the discharge capacity of $487mA\;h\;g^{-1}$ ($450mA\;h\;cm^{-3}$) after 300th cycle. The excellent lithium ion storage property of the hierarchical $ZnCo_2O_4$ hollow nanofibers was attributed to the synergetic effects of the hollow nanofiber structure and the $ZnCo_2O_4$ nanocrystals composing the shell. The hierarchical hollow nanofiber structure introduced in this study can be extended to various metal oxides for various applications, including energy storage.

Dye-sensitized Solar Cells Utilizing Core/Shell Structure Nanoparticle Fabrication and Deposition Process (코어/쉘 구조의 나노입자 제조 및 증착 공정을 활용한 염료감응 태양전지)

  • Jeong, Hongin;Yoo, Jhongryul;Park, Sungho
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.111-117
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    • 2019
  • This study proposed the fabrication and deposition of high purity crystalline $core-TiO_2/shell-Al_2O_3$ nanoparticles. Morphological properties of $core-TiO_2$ and coated $shell-Al_2O_3$ were confirmed by transmission electron microscope (TEM) and transmission electron microscope - energy dispersive spectroscopy (TEM-EDS). The electrical properties of the prepared $core-TiO_2/shell-Al_2O_3$ nanoparticles were evaluated by applying them to a working electrode of a Dye-Sensitized Solar Cell (DSSC). The particle size, growth rate and the main crystal structure of $core-TiO_2$ were analyzed through dynamic light scattering system (DLS), scanning electron microscope (SEM) and X-ray diffraction (XRD). The $core-TiO_2$, which has a particle size of 17.1 nm, a thin film thickness of $20.1{\mu}m$ and a main crystal structure of anatase, shows higher electrical efficiency than the conventional paste-based dye-sensitized solar cell (DSSC). In addition, the energy conversion efficiency (6.28%) of the dye-sensitized solar cell (DSSC) using the $core-TiO_2/shell-Al_2O_3$ nanoparticles selectively controlled to the working electrode is 26.1% higher than the energy conversion efficiency (4.99%) of the dye-sensitized solar cell (DSSC) using the conventional paste method.

A Study on the Confined Effects of Highly Moistured Soils Reinforced with Geosynthetics (토목섬유가 보강된 고함수비 흙의 구속효과에 관한 연구)

  • Yoo, Jae-Won;Im, Jong-Chul;Kang, Sang-Kyun;Lee, Hyung-Jun;Choi, Moon-Bong
    • Journal of the Korean Geosynthetics Society
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    • v.18 no.1
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    • pp.25-37
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    • 2019
  • This study confirms reinforcing effect of geosynthetics in the use of soil at higher water contents as a compaction material on compaction tests, field compaction tests, and numerical analysis. To verify a confined effect, a large mold(area ratio of rammer / mold = 0.19) larger than D compaction mold(area ratio of rammer / mold = 0.33) was performed for compaction. It showed that in the D compaction test, dry density were 0.5~0.6% increases and in the compaction test using the large mold, it were 2.4~3.7% increases at high water contents. It shows that when the area of compacted area is large enough, a confined effect could be arising from the reinforcement of geosynthetics even at high water contents. As a result of analyzing of compaction effects according to 'depth(z/B) from compacted surface' in the field, when not reinforced, the compaction state deteriorated due to the over-compaction and the compaction did not work well. However, when reinforcement of geosynthetics, restraint effect by geosynthetics occurs, it is confirmed that the compaction energy is effectively transferred to the compaction layer and the dry density is increased. Also, through the conceptual model of the behavior of geosynthetic and soil layer, the mechanism in the ground due to reinforcement of geosynthetics is presented and it is verified through finite element analysis.

An experimental study on the influence of undular bore on the hydraulic stability at Shinwol rainwater storage and drainage system (불규칙 단파가 신월저류배수시설의 수리적 안정성에 미치는 영향에 대한 실험 연구)

  • Oh, Jun Oh
    • Journal of Korea Water Resources Association
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    • v.52 no.5
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    • pp.313-323
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    • 2019
  • Deep Tunnel system is a large-scale urban flood control facility installed underground in order to reinforce the lack of drainage systems in developed cities. In a structure like a deep tunnel system, the undular bore generated in the downstream causes a problem in the hydraulic stability of the tunnel. In this study, to investigate the influence of the undular bore on the hydraulic stability at the "Shinwol rainwater storage and drainage system", under construction for the first time in the country, a hydraulic model experiment was conducted on various flooding inflow scenarios. As a result of the hydraulic model experiment carried out in this study, the undular bore generated downstream is trapped in the pipe while moving to upstream, pushes the compressed air. It is judged that overflow occurred by choking the vertical drop shaft in the process when this compressed air is being exhaust through the upstream vertical drop shaft and blocking flood inflow. In addition, the analysis of velocity of undular bore shows that the undular bore transfers energy, and at this time, the pressure rose in the pipe and the velocity increment occurred of the undular bore. Further studies are needed to predict the size and velocity of undular bore, which plays an important role in the hydraulic stability of the tunnel in the deep tunnel system.

Research of Cross-linked Hydrocarbon based Polymer Electrolyte Membranes for Polymer Electrolyte Membrane Fuel Cell Applications (고분자 전해질 막 연료전지 응용을 위한 탄화수소계 기반 가교 전해질 막의 연구동향)

  • Ko, Hansol;Kim, Mijeong;Nam, Sang Yong;Kim, Kihyun
    • Membrane Journal
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    • v.30 no.6
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    • pp.395-408
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    • 2020
  • Polymer electrolyte membrane fuel cells (PEMFCs) have gained much attention as eco-friendly energy conversion devices without emission of environmental pollutant. Polymer electrolyte membrane (PEM) that can transfer proton from anode to cathode and also prevent fuel cross-over has been regarded as a key component of PEMFCs. Although perfluorinated polymer membranes such as Nafion® were already commercialized in PEMFCs, their high cost and toxic byproduct generated by degradation have still limited the wide spread of PEMFCs. To overcome these issues, development of hydrocarbon based PEMs have been studied. Incorporation of cross-linked structure into the hydrocarbon based PEM system has been reported to fabricate the PEMs showing both high proton conductivity and outstanding physicochemical stability. This study focused on the various cross-linking strategies to the preparation of cross-linked PEMs based on hydrocarbon polymers with ion conducting groups for application in PEMFCs.

Active control of pump noise of dishwashers using FxLMS algorithm (FxLMS 알고리듬 기법을 이용한 식기 세척기의 펌프 소음 능동 제어)

  • Tark, Un-su;Oh, Han-Eum;Hong, Chinsuk;Jeong, Weui-Bong
    • The Journal of the Acoustical Society of Korea
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    • v.40 no.1
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    • pp.46-54
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    • 2021
  • In this paper, active noise control was performed to reduce radiated noise in the low frequency band of dishwashers. First, through an analysis of the noise environment of the dishwasher, it was confirmed that the pump noise contributed the most to the radiated noise in the low frequency band, From the result of the noise environment analysis, the reference signal was selected to be the vibration signal of the pump body. The reference signal was obtained by using the accelerometer on the pump body, which can prevent acoustic feedback. The error signal sensor was selected as a microphone located at 1 m in front of the dishwasher and 0.5 m in height. And to design the controller, the error signal and the reference signal were measured at the operational rpms of the dishwasher at 2,500 rpm, 2,600 rpm and 2,800 rpm, and the secondary path transfer function was measured. The designed controller was mounted on Digital Signal Processor (DSP) equipment, and the control performance was verified experimentally. As a result of the measurement at the 3 operational rpms, the 7th multiple component of pump operating frequency decreased by 1.93 dB, 4.43 dB, 5.15 dB per rpm, and the 12th multiple component decreased by 6.67 dB, 2.34 dB, 4.28 dB per rpm. And overall Sound Pressure Level (SPL) decreased by 0.84 dB, 2.58 dB, 1.48 dB by rpm.

Development of Synthetic Signal Generator and Simulator for Performance Evaluation in Multiple Sonobuoy System (다중 소노부이 체계의 신호합성기 및 성능검증용 시뮬레이터 개발)

  • Lee, Su Hyoung;Park, Sang Bae;Han, Sang-Gyu;Kown, Bum Soo
    • Journal of the Korea Society for Simulation
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    • v.30 no.2
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    • pp.11-22
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    • 2021
  • Sonobuoy is widely used as a very important sensor in combat management system using P-3 patrol aircraft due to its advantages of rapid searching into wide exploration range. It is necessary to verify the performance of developed sonobuoy system using various maritime test data in order to be successfully applied in combat management system. But it is difficult to acquire various real maritime data because it needs much time and effort. Therefore we have developed in this paper a synthetic signal generator and a simulator that they can verify the performance of sonobuoy system and evaluate its operational effectiveness without conducting maritime test. We have synthesized target signals based on the characteristics of underwater sound sources, and then developed the synthesized signal generator which consider to sound propagation etc. like as underwater environment. And in the simulator development we use a HMI technique to enhance the convenience of operator, and design to verify the performance of sonobuoy system. The developed signal generator and simulator can be used as useful tools to evaluate the operational effectiveness such as optimal deployment of sonobuoy in combat management system using P-3 patrol aircraft.

Determination of acoustic emission signal attenuation coefficient of concrete according to dry, saturation, and temperature condition (포화유무 및 온도조건에 따른 콘크리트 음향방출 신호 감쇠계수 결정)

  • Lee, Hang-Lo;Hong, Chang-Ho;Kim, Jin-Seop;Kim, Ji-Won
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.24 no.1
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    • pp.39-55
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    • 2022
  • This study carried out the laboratory tests for AE signal attenuation to determine the attenuation coefficient (α) of silo concrete in Gyeongju low and intermediate-level disposal environments. The concrete samples were prepared by satisfying the concrete mixing ratio used in the Gyeongju disposal silo, and these samples were additionally exposed depending on the temperature conditions and saturation and, dry condition. As a result of attenuation tests according to the transmission distance on three concrete specimens for each disposal condition, the AE amplitude and absolute energy measured on the saturated concrete were higher than that of the dry concrete in the initial range of the signal transmission distance, but the α of the saturated concrete was higher than that of the dry concrete. Regardless of the saturation and dry conditions, the α tended to decrease as the temperature increases. The α had a more major influence on the saturation and dry condition than the temperature condition, which means that the saturation and dry condition is the main consideration in measuring the signal attenuation of a concrete disposal structure. The α of concrete in the disposal environment expect to be used to predict the integrity of silos concrete in Gyeongju low and intermediate-level disposal environments by estimating the actual AE parameter values at the location of cracks and to determine the optimum location of sensors.

Model-based Design and Verification of High-lift Control System Using a Performance Analysis Model (성능해석 모델을 활용한 고양력 제어시스템의 모델기반 설계 및 검증)

  • Cho, Hyunjun;Kim, Taeju;Kim, Eunsoo;Kim, Sangbeom;Lee, Joonwon
    • Journal of Aerospace System Engineering
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    • v.16 no.2
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    • pp.49-62
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    • 2022
  • The purpose of this paper was to present a model analysis-based design process and verification results for the high-lift control system of aircraft. For this, we used Matlab/Simulink, one of the most widely-used physical modeling tools. The high-lift control system can be divided into three domains. (i.e., Electronic control domain, Hydraulic actuation domain, and Mechanical power transmission domain) Based on this division, we modeled each of the major domains and sub-components, and integrated them to complete the complicated system model. During the development process, each model block was tuned by referring to the results of pre-test and parts acceptance tests. As a result, the entire performance model and the developed system were completely verified, through unit components and system integrated performance tests. Finally, we summarize the process and results applied to the design process of high-lift control system and present future work.

An Efficient Routing Scheme based on Link Quality and Load Balancing for Wireless Sensor Networks (무선 센서 네트워크에서 링크 상태 및 트래픽 분산 정보를 이용한 효과적인 라우팅 방법)

  • Kim, Sun-Myeng;Yang, Yeon-Mo
    • Journal of the Korea Society for Simulation
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    • v.19 no.4
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    • pp.11-19
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    • 2010
  • ZigBee is a standard for wireless personal area networks(WPANs) based on the IEEE 802.15.4 standard. It has been developed for low cost and low power consumption. There are two alternative routing schemes that have been proposed for the ZigBee standard: Ad-hoc On-Demand Distance Vector(AODV) and tree routing. The tree routing forwards packets from sensors to a sink node based on the parent-child relationships established by the IEEE 802.15.4 MAC topology formation procedure. In order to join the network, a sensor node chooses an existing node with the strongest RSSI(Received signal strength indicator) signal as a parent node. Therefore, some nodes carry a large amount of traffic load and exhaust their energy rapidly. To overcome this problem, we introduce a new metric based on link quality and traffic load for load balancing. Instead of the strength of RSSI, the proposed scheme uses the new metric to choose a parent node during the topology formation procedure. Extensive simulation results using TOSSIM(TinyOS mote SIMulator) show that the CFR scheme outperforms well in comparison to the conventional tree routing scheme.