• Title/Summary/Keyword: 에너지 저하체

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Optimization of Preparation Conditions of Vanadium-Based Catalyst for Room Temperature Oxidation of Hydrogen Sulfide (황화수소 상온 산화를 위한 바나듐계 촉매의 제조 조건 최적화 연구)

  • Kang, Hyerin;Lee, Ye Hwan;Kim, Sung Chul;Chang, Soon Woong;Kim, Sung Su
    • Applied Chemistry for Engineering
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    • v.32 no.3
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    • pp.326-331
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    • 2021
  • In this study, the preparation conditions for a TiO2-based vanadium-based catalyst for oxidizing hydrogen sulfide at room temperature were optimized. Four types of commercial TiO2 were used as a catalyst support and the performance evaluation of hydrogen sulfide oxidation at room temperature of V/TiO2 by varying vanadium contents prepared using the impregnation method was performed. Among the types of TiO2 tested, it was confirmed that the catalyst with the vanadium content of 5% and based on TiO2(A) has the best hydrogen sulfide conversion rate of 58%. By comparing the physical and chemical properties of the catalyst, the specific surface area of the support and the species of dominant vanadium are the major factor in catalyst performance. In order to confirm the regeneration characteristics of the catalyst with reduced activity, heat treatment was performed at 400 ℃ for 2 h, and the amount of hydrogen sulfide oxidation decreased by 10% due to the partial deposition of sulfur in the regenerated catalyst, but it was confirmed that the initial performance was similar.

Seismic Behavior Evaluation of Embedded Kagome Damping Device (콘크리트에 매립된 카고메 감쇠시스템의 내진거동평가)

  • Hur, Moo-Won;Lee, Sang-Hyun;Kim, Jong-Ho;Hwang, Jae-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.2
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    • pp.84-91
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    • 2019
  • Recently, there has been a tendency to improve seismic performance of building structure by installing a steel hysteretic damping device which is economically efficient and easy to install and maintain. However, for a reinforced concrete building, a set of complicated connecting hardware and braces to fix the steel hysteretic damping device yields deteriorated reliability in damping performance. Therefore, this study presents a method of directly embedding a Kagome damper, which was investigated in previous researches, into a concrete structure without additional connecting hardware. Moreover, in this study, a series of experiments conducted to provide a basis of the Kagome damper by confirming the seismic behavior for various embedded lengths. As a result, in a group of the embedded length of $1.0l_d$, the dampers were pulled out, while concrete breakout occurs. In a group of $2.0l_d$, neither pull-out nor concrete breakout occurred, while the dampers show stable behavior. Moreover, the buried length of $2.0l_d$ has 1.3 times better energy dissipation capacity. The system presented in this study can reduce the cost and period for installing, omitting making additional hardware.

Effects of Varying the Concentration of Energy Yielding Nutrients on Nitrogen Balance and Body Composition of the Growing Rats (열량 영앙소의 수준이 흰쥐의 단백질 평형과 체조성에 미치는 영향)

  • Chang, Y.K.;Han, I.K.
    • Journal of Nutrition and Health
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    • v.13 no.3
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    • pp.117-125
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    • 1980
  • In order to investigate the utilization efficiency of dietary protein in the rat body and effects of dietary fat on its protein metabolism, 51 Sprague-Dawly rats of 6 weeks old weighing approximate)y 106g were subjected to feeding trials for 4 weeks and then subsequently to metabolic trials for 3 weeks using six different diets composed of three different levels of protein (10%, 20% and 30%) with low (20%) and high (40%) fat content for each protein level, total energy being fixed at 4000 Kcal/kg by addition of an appropriate amount of carbohydrate, and the following results were obtained. 1) The body weight gain increased in the low fat diets with increasing protein level whereas it decreased in the high fat diets. Food efficiency also increased in the low fat diets with increasing protein level, but no do deffinitive trend was observed in the high fat diets. The protein efficiency was generally higher at low protein level and tended to decrease as the protein level increased, regardless of the amount of fat intake. 2) As the protein level was increasing, digestibility of dry matters and carbohydrate were decreasing whereas that of protein was slightly increasing. On the other hand, digestibility of fat was always very high regardless of the amounts of dietary protein and fat. 3) The gross energy intake was affected both by protein and fat contents in the diets: The energy metabolism efficiency was decreasing with increasing protein level and at the same protein level the energy utilization was considerably higher in the low fat diets than in the high fat. 4) From the above-mentioned experimental results it may be concluded that the best formula of diet for growing rats is probably composed of 20% protein, 20% fat and 60% carbohydrate.

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Evaluation of Serviceability and Flexural Performance for RC Hollow Slab by Hollow Ratio and Damping Ratio (중공율과 감쇠율을 이용한 RC 중공 슬래브의 사용성 및 휨성능 평가)

  • Jong Hoon Kim;Dong Baek Kim;Yong Gon Kim;Jae Won Lee;Jeong Ho Choi
    • Journal of the Society of Disaster Information
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    • v.18 no.4
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    • pp.930-935
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    • 2022
  • Purpose: The purpose of this study is to evaluate the stiffness reduction and damping ratio of reinforced concrete hollow slabs and to analyze their performance, and to study the effect of the damping effect of hollow bodies and the stiffness reduction on the serviceability of slabs. Method: Test specimen was made in a size of 0.6m*0.21m*3.6m to evaluate the vibration effect of the slab, and the hollow ratio was set in six steps from 0.0% to 30% to measure the change in rigidity and damping according to the change in the hollow ratio. Result: As the hollow ratio increases, rigidity decreases and the natural frequency decreases, but as the mass decreases, the natural frequency increases gradually. Since energy is hardly dissipated up to the hollow ratio of 20%, the hollow ratio should be reduced by 30%. Conclusion: It was found that the bending strength degradation of the slab with a hollow ratio of about 30% is minimized, but an appropriate natural frequency can be maintained, and a certain damping effect can be obtained.

Behavior of Concrete Columns Confined by Carbon Fiber Sheets under a Constant Axial Force with Reversed Cyclic Lateral Loading (일정축력하의 탄소섬유쉬트 보강기둥의 횡가력시 거동특성에 관한 실험연구)

  • Chun, Sung-Chul;Park, Hyung-Chul;Ahn, Jae-Hyen;Park, Chil-Lim
    • Magazine of the Korea Concrete Institute
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    • v.11 no.2
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    • pp.147-156
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    • 1999
  • An investigation was conducted into the flexural behavior of earthquake damaged reinforced concrete columns repaired with carbon fiber sheets. Six column specimens were tested to failure under reversed cyclic loading. Two columns were specimens for control with no sheets and tested. These columns were repaired with carbon fiber sheets and retested to evaluate the effect of the confinement of the carbon fiber on the damaged column. Another two columns were repaired and tested with no pre-cyclic loading. The test specimens were designed to model single bent under a constant axial force with reversed cyclic lateral loading. Carbon fiber sheets were used to repair damaged concrete columns in the critically stressed areas near the column footing joint and the physical, mechanical properties of carbon fiber sheets are described. The performance of repaired columns in terms of their hysteretic response is evaluated and compared to those of the original columns. The results indicate that the repaire technique with carbon fiber sheets is highly effective. Both flexural strength and displacement ductility of repaired columns were higher than those of the original columns.

Study on the Characteristics of Far Infrared Ray Drying for Rough Rice(I) (벼의 원적외선 건조특성에 관한 연구(I))

  • 김유호;조영길;조광환;이선호;김영민;한충수;이호필
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2002.02a
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    • pp.355-361
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    • 2002
  • 본 연구에서는 원적외선.열풍 복합건조특성을 구명하기 위하여 건조용량 150-500kg이고, 승강기, 상.하부스크류, 건조실, 템퍼링실, 송풍기 및 가열장치로 구성된 시뮬레이터를 제작하여 건조특성시험을 실시하였다. 그 결과를 요약하면 다음과 같다. 가. 열풍온도에 따른 곡온변화를 시험한 결과 열풍온도 45$^{\circ}C$일 때 곡온 32-33$^{\circ}C$를 유지하였으며, 48, 51$^{\circ}C$일 때는 곡온이 35$^{\circ}C$가 넘어서는 현상을 나타났다. 건조중 곡온이 35$^{\circ}C$를 넘어서게 되면 동할미 발생량이 많아지고 품질저하가 급격히 일어난다. 나. 템퍼링실의 온도편차가 2,5$^{\circ}C$ 정도로 고른 온도분포를 나타내었고, 버너 입구쪽과 템퍼링실 중앙지점에서 온도가 약간 높게 나타났으며, 원적외선방사체 표면온도분포는 열풍온도가 45$^{\circ}C$일 때 평균 17$0^{\circ}C$를 유지하였고, 48$^{\circ}C$, 51$^{\circ}C$일 때 각각 22$0^{\circ}C$, 23$0^{\circ}C$에서 유지하는 것으로 나타났다. 다. 원적외선방사체 길이방향으로 온도편차는 버너를 기준으로 해서 버너쪽에서 멀수록 온도가 높았고, 중간, 근거리 순으로 나타났다. 버너의 원거리쪽에서 온도가 높게 나타난 것은 원적외선방사체를 통과하는 열풍이 빠져나가도록 되어있는 열풍 유동관이 버너 원거리에 위치하고 있어 버너에 불꽃이 점화되면서 열풍이 방사체 끝쪽으로 일시 머물렀다가 배출되기 때문으로 판단된다. 라. 건조기의 송풍량을 요인으로 하여 건조속도와 건조에너지를 비교한 결과 송풍량이 30cmm일 때가 25cmm에서보다 약 33%의 건조속도가 증가되어 송풍량이 많을수록 건조속도가 빨라졌으나, 건조에너지는 1,391kcal/kg.water로 나타나 약 4.2%정도가 더 소요 되었다. 곡물순환속도를 요인으로 하여 비교 시험한 결과 곡물순환속도가 33kg/min일때가 26kg/min보다 약 25%의 건조속도가 증가되어 곡물의 순환속도가 빠를수록 건조속도가 빨라졌으며, 건조에너지도 1,334kcal/kg.water로 비슷하게 소요되었다. 마. 시험구와 대비구의 건감률은 시험구에서 1.08~1.36w.b./h로 나타나 대비구보다 약 9.9~18.3%가 높게 나타났고, 건조에너지는 10.2~14.6%가 절감되었다. 발아율은 열풍온도가 낮을수록 높게 나타났고 시험구가 대비구보다 발아율이 낮게 나타났으며, 동할률 증가량도 원적외선.열풍 복합건조방법이 높게 나타나 이것은 곡물 표면에 원적외선 방사에의한 복사열이 전달되어 열장해를 받았기 때문으로 판단되며, 금후 더 연구하여 적정 열풍온도 및 방사체 크기를 구명해야 할 것이다.

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Experimental Test for Seismic Performance of PCS Structural System (PCS 구조 시스템의 내진 성능 분석)

  • Park, Soon-Kyu;Yeo, In-Seok
    • Journal of the Korea Concrete Institute
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    • v.19 no.3
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    • pp.313-322
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    • 2007
  • The PCS system, which consists of precast concrete column and steel beam, is a kind of composite structural systems. In this paper, experimental study has been conducted to analyze seismic performance of bolted beam-to-column connections for the PCS system. Based on experimental results from the seismic testing of eight interior PCS specimens, it shows that behavior of PCS system is satisfactory to seismic performance criteria of ACI such as strength deterioration, stiffness degradation and energy dissipation capacity except initial stiffness. All of the specimens maintain their strength at large levels of story drift without significant loss of stiffness and show high ductility level for inelastic behavior. The energy dissipation capacity is two times greater than requirement of ACI criterion. But the initial stiffness of all specimens does not satisfy ACI criterion, and this phenomenon is similar to the other composite structural systems such as RCS, CFT system.

A Study on the Ground Vibration Reduction Characteristics of Air-Deck Blasting Method Using Paraffin Waxed Paper Tube (파라핀 지관 구조체를 활용한 Air-Deck 발파공법의 지반진동 저감특성에 관한 연구)

  • Gyeong-Jo, Min;Young-Keun, Kim;Chan-Hwi, Shin;Sang-Ho, Cho
    • Explosives and Blasting
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    • v.41 no.1
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    • pp.32-45
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    • 2023
  • Environmental regulations in Korea for blasting at industrial sites have conservative standards, which often result in reduced efficiency and cost-effectiveness due to the consideration of environmental regulations and public complaints. Therefore, there is a need for blasting methods that can reduce environmental damage while improving construction efficiency and cost-effectiveness. In this study, we analyzed the effects of the PA-Deck (Paraffin Air-Deck) blasting method, which is a kind of Air Decoupled Charge method in principle utilizing a paraffin-infused paper tube as an air gap, on reducing blasting hazards and improving blasting efficiency. The analysis also evaluated the effectiveness of newly applied equipment for collecting blasting vibration data, and derived the relationship between the explosion velocity and vibration velocity of explosives, and performed frequency analysis of the vertical component. The results of the blasting vibration velocity analysis showed that the Paraffin Waxed Paper Tube-based blasting method exhibited significantly lower vibration velocities compared to conventional blasting methods, and it was judged that more uniformly small-sized fragmented rocks were generated.

The Electrochemical Properties of Sponge Type S@ZIF67/rGO as the Cathode Material for Lithium Sulfur Batteries (리튬 황 전지용 Sponge 형태의 S@ZIF 67/rGO 양극재의 전기화학 특성 분석)

  • Chaelin Seo;Sunghoon Kim;Wook Ahn
    • Journal of the Korean Electrochemical Society
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    • v.27 no.1
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    • pp.47-54
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    • 2024
  • In this study, ZIF67/rGO was used to minimize the battery life degradation due to the insulating properties of sulfur and the elution of lithium polysulfide. ZIF67 wrapped in rGO creates more space within the carbon sponge and can hold a large amount of sulfur. The sulfur@ZIF67/rGO composite was synthesized and prepared as a sponge to enhance the sulfur retention capacity. The result showed a high initial capacity, with a value of about 1093 mAh g-1 and a capacity retention rate of 84% after 100 cycles. The high interaction with sulfur through the complexation of cobalt and carbon confirmed that ZIF67/rGO exhibits high performance as a carrier for sulfur, the anode active material of lithium-sulfur batteries, and the high initial capacity and improved capacity retention rate were confirmed.

Effects of Bar Deformation Height on Bond Degradation Subject to Cyclic loading (반복하중시 철근 마디높이에 따른 부착 손상특성)

  • Lee, Jae-Yuel;Kim, Byong-Kook;Hong, Gi-Suop;Choi, Oan-Chul
    • Journal of the Korea Concrete Institute
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    • v.15 no.1
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    • pp.17-24
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    • 2003
  • One of the reasons for brittle failure in reinforced concrete structures subjected to severe earthquake is due to large local bond-slippage of bars resulting in fast bond degradation between reinforcing bars and concrete. This study aims to evaluate effects of bar deformation height on bond performance, specially, bond degradation under cyclic loading. Bond test specimens were constructed with machined bars with high relative rib areas. The degree of confinement by transverse bars is also another key parameters in this bond test. From test results, amounts of energy dissipation are calculated and compared for each parameter. Test results show that bond strength and stiffness drops significantly as cycles increases. The confinement and high relative rib area are effective to delay bond degradation, as the reduction of bond strength of cyclic loading compared to monotonic loading decreased for bars with large confinement and high relative rib areas. The energy dissipation also increases as the degree of confinement and relative rib area increases. However, tested bars with very high rib areas show that the bond may be damaged at relatively small slip because of high stiffness. The study will help to understand the bond degradation mechanism due to bar deformation height under cyclic loading and be useful to develop new deformed bars with high relative rib areas.