• Proceedings of the Korea Water Resources Association Conference
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• 2023.05a
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• pp.44-44
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• 2023

지표면 위 에너지 수지, 즉 순 복사에너지가 어떤 비율로 지열, 현열, 잠열로 분할되는지를 이해하는 것은 매우 중요한 문제이지만, 에너지 분할과 주변 환경 변수 사이의 인과관계를 역학적으로 설명하는 것은 난제로 남아있다. 이 연구에서는 지표면 에너지 분할에서 어떠한 조건에서라도 보편적으로 발견되는 특성을 찾아서 다양한 식생 조건에서 관측된 복사에너지 및 열 플럭스 관측소의 자료를 토대로 각 에너지 항의 시간 변동성을 분석했다. 시계열 분석을 위해 공분산 기법을 통해 관측한 현열 및 잠열 자료를 제공하는 Fluxnet 자료를 사용했으며, International Geosphere-Biosphere Programme (IGBP) 구분법에 따라 낙엽수림, 상록수림, 농지 및 사바나에 위치한 관측소의 자료를 비교 분석했다. 모든 관측소에서 에너지 수지에서 현열과 잠열의 합이 전체 순 복사에너지에서 차지하는 비중은 시간에 따라 큰 변화를 보이지 않는다는 특성을 발견했다. 하지만, 현열 또는 잠열이 차지하는 비중은 큰 계절성을 보여주고 있었다. 이를 종합하면 현열과 잠열이 상호보완적으로 발생한다는 것을 의미한다. 한편 시간에 따른 두 열 플럭스의 움직임은 해당 관측소 근처에서 서식하는 식생 특성과 깊게 관련됐음을 확인했다.

• The Korean Journal of Rheology
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• v.11 no.2
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• pp.135-142
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• 1999

The effects of 1 wt.% N-benzylpyrazinium hexafluoroantimonate (BPH) as a thermal latent initiator and blend compositions composed of 0, 5, 10, 20 and 40 wt.% of phenol-novolac resin to epoxy resin were investigated in terms of cure kinetics, thermal stabilities and rheological properties. Thermal latent properties of BPH were measured from the conversion as a function of reaction temperature on a dynamic DSC. This cationic BPH system turned out to be an effective thermal latent initiator in the epoxy-phenol curing system. And the increase of phenol-novolac resin concentration led to the decrease in the latent temperature and to the increase of cure activation energy ($E_a$) of the blend system. The thermal stability and activation energy ($E_t$) for decomposition, gel-time and activation energy ($E_c$) for cross-linking from rheometer increased within the composition range of 20~40 wt.% of phenol-novolac resin. This implies that the three-dimensional cross-linking may take place among hydroxyl group within phenol resin, epoxide ring within epoxy resin and BPH.

• The Magazine for Energy Service Companies
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• s.25
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• pp.26-27
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• 2003

국가 에너지절약의 차원에서 단 $1\%$의 절약이라도 이뤄낼 수 있다면 수주금액에 상관없이 착수하는 것이 저희의 기본방침입니다. 수지가 맞지 않아 적은 액수의 사업에는 손대지 않는 업체가 다수이지만, 저희는 에너지절약의 확산이라는 차원에서 작은 규모의 ESCO사업에도 최선을 다하고 있습니다.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.518-521
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• 2008

수소에너지는 다양한 원료로부터의 수소생산을 위한 반응기술 및 생산물로부터 수소 정제를 위한 분리기술의 확립과 더불어, 대형화 시스템부터 소형 시스템에 이르는 공정기술을 확보하는 것이 다가오는 청정 대체에너지 체제에 대비하기 위하여 필요하다. 이를 위해서는 생산된 수소 혼합물에서부터 수소를 분리 정제하는pressure swing adsorption (PSA) 의 개발이 필수적이다. 이 기술은 이미 다양한 분야에 성공적으로 상용화 적용되어 기술의 타당성을 제시하고 있으나, 국내의 경우 수입에 의존하고 있어 이를 설계 할 수 있는 공정모사기 (simulator)의 개발이 우선되어야 한다. 따라서 효율적으로 PSA 공정 및 scale-up기술을 확보하기 위해서는 전산모사기 개발의 선행이 필수적이다. PSA 공정의 전산모사기는 물질수지, 에너지수지, 모멘텀수지와 더불어 흡착평형과 속도식이 결합되어 개발되어야 한다. 특히 공정에 다양한 단계가 적용되기 때문에 복잡한 boundary condition이 적용되며, 연속순환공정이라 하더라도 각 단계가 discrete 하게 해석되어야 한다. 따라서 공정모사는dynamic simulator로 개발되어야 정확도를 확보할 수 있다. 본 연구에서는 제철소에서 발생하는 수소혼합물이 WGSR 반응기를 거쳐 수소의 농도를 향상 시키고, 이를 유입가스로 사용하는 $H_2$ PSA 공정 모사기를 개발하고자 한다. 수소 생산을 위한 PSA 공정 모사기 개발을 통하여 95% $H_2$ 순도와 90% 회수율 규모의 수소를 생산할 수 있는 PSA 공정의 설계 기술기반을 확보하고자 한다.

• Tunnel and Underground Space
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• v.21 no.4
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• pp.297-306
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• 2011

In this paper, we performed thermodynamic energy balance analysis of the underground lined rock cavern for compressed air energy storage (CAES) using the results of multi-phase heat flow analysis to simulate complex groundwater-compressed air flow around the cavern as well as heat transfer to concrete linings and surrounding rock mass. Our energy balance analysis demonstrated that the energy loss for a daily compression and decompression cycle predominantly depends on the energy loss by heat conduction to the concrete linings and surrounding rock mass for a sufficiently air-tight system with low permeability of the concrete linings. Overall energy efficiency of the underground lined rock caverns for CAES was sensitive to air injection temperature, and the energy loss by heat conduction can be minimized by keeping the air injection temperature closer to the ambient temperature of the surroundings. In such a case, almost all the heat loss during compression phase was gained back in a subsequent decompression phase. Meanwhile, the influence of heat conductivity of the concrete linings to energy efficiency was negligible.

• Journal of Energy Engineering
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• v.12 no.4
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• pp.289-301
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• 2003

To develop a chemical-looping combustion technology, conceptual design of 50 kW thermal chemical-looping combustor, which is composed of two interconnected pressurized circulating fluidized beds, was performed by means of mass and energy balance calculations. A riser type fast fluidized bed was selected as an oxidizer and a bubbling fluidized bed was selected as a reducer by mass balance for the chemical-looping combustor. Calculated values of bed mass, solid circulation flux, and reactor dimension by mass and energy balance calculations were suitable for construction and operation of chemical-looping combustor. It is concluded from the comparison of the design results and operating values of commercial circulating fluidized bed that the process outline is realistic. Moreover, the previous results support that oxygen carrier particle, NiO/bentonite, fulfills the conversion rates needed for the proposed design. The effects of system capacity, metal oxide content in a oxygen carrier particle, amount of steam input, gas velocity, and solid depth on design values were investigated and the changes in the system performance can be estimated by proposed design tool.

• Journal of the Korean Chemical Society
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• v.34 no.3
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• pp.267-279
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• 1990

The adsorption mechanisms of phenols on XAD-2 and XAD-7 resins were studied by using the distribution coefficient(log Kd) measured in the optimum adsorption conditions. It was observed that the Langmuir adsorption isotherm, indicating a molecular size-dependent adsorption, was appropriate for characterizing the adsorption behaviors of phenols on XAD-2 and XAD-7 resins. The adsorption energies of phenols on XAD resins were calculated by Lennard-Jones potential equation. In the calculation of the adsorption energy, the molecular radii and dipole moments of the resins and phenols were calculated by their van der Waals volumes and Debye equation, respectively. The stacking factor (F) were determined from the radio of the equilibrium distance to the stacking distance of molecules. In order to explain the adsorption energy calculated from the stacking factor it was compared with the adsorption enthalpy for each of phenols which was experimentally determined by batch adsorption shake method. It was observed that the adsorption enthalpy of phenolate ions on the XAD resins was likely to be more seriously affected by dispersion interaction than by a dipole or a charge interaction.

• Composites Research
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• v.35 no.4
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• pp.288-297
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• 2022

This study investigated the effect of addition of zirconia(zirconium oxide) powder on the curing behavior of phenolic resins. The heating rate controlled curing and isothermal curing behaviors of the phenol resin according to the content of the zirconia powder were analyzed. The viscosity and thermal decomposition characteristics of the phenolic resin with the zirconia content were also examind. From the DSC analysis, the degree of cure and the rate of cure were obtained. Finally, the activation energy for the cure reaction were calculated from the DSC data of the zirconia added phenolic resin. As a found, the higher the zirconia content, the longer the curing was delayed and the greater the activation energy required for curing. Additionally, the TGA result that as the content of zirconia increased, less weight loss was observed. The surface tackiness of the Carbon/Phenol prepreg was partially changed according to the zirconia content, but had no significant effect.

• Electric Engineers Magazine
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• v.175 no.3
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• pp.20-23
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• 1997

금년도 통상산업부에 3대 과제는 무역수지적자의 획기적 개선, 산업경쟁력 10% 이상 높이기의 강력한 추진, 그리고 에너지소비의 과감한 절약과 수급안정이다. 종래 에너지분야의 주요과제는 수급안정과 안전사고 예방이었으나 이번에는 에너지 절약이 선정되었다.

• NEWSLETTER 전기공업
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• no.97-15 s.184
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• pp.3-8
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• 1997