• Title/Summary/Keyword: 양태성

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The performance evaluation of the separator for PEMFCs (고분자 전해질막 연료전지 분리판 성능평가)

  • Hwang Ho-Jung;Yang Tae-Hyun;Yoon Young-Gi;Lee Won-Yong;Shul Yong-Gun;Kim Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.288-290
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    • 2005
  • 고분자전해질 연료전지는 자동차, 분산전원 및 이동전원 등에 대한 차세대 에너지원으로 채택 가능성이 높아지고 있다. 고분자전해질 연료전지 시스템의 상용화를 위한 가장 큰 걸림돌 중 한 가지로 가격문제를 들 수 있는데, 연료전지 스택이 전체 가격의 약 $50\%$를 차지하고 있다. 또한 스택을 구성하는 요소 중 분리판의 가격 비중은 약 $30\%$를 차지하고 있어, 분리판의 생산단가 저감은 연료전지의 상용화를 위해 반드시 해결해야 될 문제이다. 본 연구에서는 탄소를 재료로 하는 분리판에 대한 연구를 수행하였으며, 압축성형방식으로 제작된 다양한 복합재료 분리판 및 흑연 분리판에 대한 기계적 강도, 물리적 특성, 화학적 안정성을 조사하였으며, 가흑 운전 시 분리판내에 함유되어있는 고분자 성분의 침출에 의한 연료전지의 성능변화가 발생하는지 확인하였으며 이에 대한 단위전지의 성능평가를 수행하였다. 이러한 결과를 토대로 최적의 압축성형 복합체 분리판 제작 방향을 제시하고, 보다 신뢰성 있는 분리판 성능평가 기준을 확립하고자 하였다.

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Characteristics of hydrogen adsorption peaks of electrodes containing ionic liquid for high temperature polymer electrolyte fuel cells (고온 연료전지용 이온성 액체를 함유한 전극의 수소 흡착피크의 특성)

  • Ryu, Sung-Kwan;Park, Jin-Soo;Yang, Tae-Hyun;Park, Seung-Hee;Park, S.H.;Yoon, Y.G.;Kim, Han-Sung;Kim, Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.382-382
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    • 2009
  • In this study, we prepared electrodes containing ionic liquid for high temperature polymer electrolyte fuel cells. Effects of ILs on electrochemical properties of the electrodes were investigated carrying out measurement of cyclic voltammograms of the various electrodes with the content of IL in a strong supporting electrolyte. As the ILs content increased in electrodes, electrochemical surface area(ESA) decreased due to the leakage of ILs from Nafion ionomer. In addition, two case of cyclic voltammograms under two simulated environment, i.e. IL leakage from Nafion ionomer in I) electrode and ii) polymer electrolyte, were investigated. As a result, IL leakage from polymer electrolyte showed worse results in electrochemical properties of the electrode.

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Effect of the gas diffusion layer on freeze/thaw durability in polymer electrolyte fuel cells (동결/해동 조건에서 기체확산층의 물성이 고분자전해질연료전지의 내구성에 미치는 영향)

  • Park, Gu-Gon;Lim, Soo-Jin;Park, Jin-Soo;Sohn, Young-Jun;Yim, Sung-Dae;Kim, Chang-Soo;Yang, Tae-Hyun
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.640-643
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    • 2009
  • The effect of the kind of gas diffusion layers (GDLs) on the freeze/thaw condition durability in polymer electrolyte fuel cells (PEFCs) were investigated. For this purpose, three kinds of GDLs, i.e., felt, paper and cloth types with different basic properties have been first prepared, then the changes in the properties and performance of cells was observed during the freeze/thaw cycles ranging from -30 to 70 $^{\circ}C$. The single cells consisting of different GDLs were evaluated for performance. The performance degradation and the cell resistance increase could be directly correlated. The physical destruction of electrode was shown by SEM analysis. It was presented that mechanical supporting force of interface between materials can help enhancing the durability of PEFCs in the freeze/thaw condition.

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Preparation and characterization of proton exchange membranes in non-aqueous conduction (무수 전도성 양성자 교환막 제조 및 특성평가)

  • Park, Jin-Soo;Sekhon, S.S.;Baek, Ji-Suk;Yang, Tae-Hyun;Kim, Chang-Soo;Yim, Sung-Dae;Park, Gu-Gon
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.282-285
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    • 2009
  • This study presents preparation and characterization of composite membranes based on ionic liquids. The ionic liquids act as water in sulfonated membranes. On the behalf of ionic conduction through ionic liquid inside the membranes, non-aqueous membranes showed Arrenhius dependence on temperature with no external humidification. It was implied that hopping mechanism of proton was dominant in the ionic liquid based membranes. In addition, small angle X-ray (SAXS) studies provided the information on morphology of ionic clusters formed by the interaction between sulfonic acid groups of the polymers and ionic liquids. The SAXS spectra showed matrix peaks, ionomer peaks and Prodo's law for Nafion based composite membranes and only matrix peaks for hydrocarbon based ones. However, ionic conductivity and atomic force microscopy (AFM) images showed the clear formation of ionic clusters of the hydrocarbon based composite membranes. It implies for ionic liquid based high temperature membranes that it is important to use sulfonated polymers as solid matrix of ionic liquid which can form clear ionic clusters in SAXS spectra.

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Integrity Assessment on the Nuclear Transport Cask under the Ballistic Impact (발사 충격을 받는 방사성 물질 운반용기의 건전성 평가)

  • Yang, Tae-Ho;Lee, Young-Shin;Lee, Hyun-Seung
    • Journal of the Korean Society of Safety
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    • v.29 no.4
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    • pp.15-22
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    • 2014
  • As the risk of the various external risk was increased, a study on the integrity assessment of the nuclear transport cask was needed. In this paper, an integrity assessment of the nuclear transport cask under the ballistic impact was studied. The projectile with L/D = 5 was used in simulation. The applied head shapes of the projectile were five types such as flat shape, conical shape, hemispherical shape, truncated conical and sliced flat shape, respectively. The range on the velocity of the projectile was 85 m/s to 680 m/s. The cask body of the nuclear transport cask was not penetrated by the projectile speed up to Vprojectile = 510 m/s. As the cask body was penetrated by the all types projectile with Vprojectile = 680 m/s and the cask lead in the nuclear transport cask was collided with the projectile. As the projectile moved to 31.3 mm in the cask lead, the cask lead was not penetrated by the projectile with Vprojectile = 680 m/s. The integrity assessment on the nuclear transport cask under ballistic impact up to Vprojectile = 680 m/s was obtained.

집광형 고효율 화합물반도체 태양전지 기술 및 시장 동향

  • O, Dae-Gon;Han, Won-Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.25-25
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    • 2010
  • 태양광 에너지는 인류의 미래 에너지로서 이미 그 효용성을 전 세계에 드러내고 있다. 각 나라마다 자국의 에너지 전략 및 일조량등 환경적 여건 또는 경제적 수준에 따라 다양한 에너지 수급의 양태를 띠고 있지만 향 후 한세대 내에 전세계 에너지의 30% 정도를 태양에너지로 공급받게 될 것으로 기대하고 있다. 이러한 추세 속에서 태양광 에너지의 방식도 여건에 따라 다양한 형태들이 상호 경쟁과 보완의 과정을 거치며 꾸준히 연구 개발되어오고 있다. 집광형 태양전지는 그 중에서 광전변환효율의 관점에서 41%라는 경이적인 기록을 가지고 있으며 매년 평균 1% 씩의 발전을 꾸준히 달성해 오고 있다. 특히 화합물반도체 태양전지의 경우 1900년대 후반부터 인공위성등의 에너지 모듈로 독자적인 시장을 형성하고 있었지만 경제성등의 이유로 지상 에너지의 대안으로 고려되지 못하고 있었으나 집광시 효율이 높아지는 특이현상과 다중접합을 통한 태양에너지 스펙트럼의 흡수영역 확대등을 통하여 총체적인 효율이 30%를 넘어서면서부터 서서히 대전력 에너지원으로 주목을 받기 시작하였다. 이러한 기술적 경쟁력에도 불구하고 전세계 태양전지 시장의 대부분은 단결정 실리콘 태양전지가 차지하고 있으며 박막형 태양전지 혹은 유기태양전지등 차세대 태양전지 또한 기존의 단결정 실리콘 태양전지를 기준으로 상대적인 가격경쟁력을 높이므로서 기존시장을 잠식하거나 신규시장을 통하여 점유율을 높이는 전략을 고려하고 있다. 본 세미나를 통하여 현재 화합물반도체 집광형 태양전지 시장을 살펴보고 시장 진입의 걸림돌에 대한 분석과 향 후 동향에 대하여 논의하도록 한다.

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A Study on Prioritization of Regional Development Strategies According to Industrial Varieties and Innovation Competency (산업 다양성과 혁신역량에 따른 지역 발전전략의 우선순위 설정에 관한 연구)

  • Han, Jaepil
    • Journal of the Economic Geographical Society of Korea
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    • v.25 no.3
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    • pp.357-379
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    • 2022
  • This study diagnoses the industrial varieties and innovation capacity of the Korean regional economy and discusses how the priority for autonomous regional development can be set. Since the late 1990s, regional development policies in Korea have been attempted from various angles to reduce the economic gap between the metropolitan area and non-metropolitan areas, but the establishment of a development strategy in consideration of regional industrial characteristics and innovation capabilities has been insufficient. With the advancement and diversification of technologies and industries, regions must seek strategic diversification to prepare for economic shocks, away from strategies that specialize in specific industries. In this study, industrial varieties in regional basis is characterized using unrelated and related varieties. Variety indices show different patterns between the metropolitan area and non-metropolitan areas and between manufacturing and service sectors, which raises the need to consider industrial characteristics in regional development. Lastly, using the variety index and the innovation capacity index as two dimensions, the regional economic status at the municipal level is categorized into four types, and proper regional development policy priorities are suggested for each type.

Seasonal Variation of the Pelagic Fish Egg Community in the Mid-east Coastal Waters of the Yellow Sea (황해(黃海) 중동부(中東部) 연안역(沿岸域)의 부유성(浮游性) 어란(魚卵) 군집(群集)의 계절(季節) 변동(變動))

  • Cha, Seong Sig;Shim, Jae Hyung
    • 한국해양학회지
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    • v.23 no.4
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    • pp.184-193
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    • 1989
  • To study the pelagic fish egg community in the mid-east coastal waters of the Yellow Sea, pelagic eggs were sampled with Bongo net at 13 stations from Chonsu Bay to Keum Estuary from July, 1985 to June, 1986. Nineteen taxa of pelagic eggs were collected. Among them, 7 taxa were identified to the species level, and 2 taxa to the family level. Engraulis japonica was the most abundant species with 89.5% of the total eggs; Sillago japonica was 2.5%; Clupanodon punctatus, 2.4%; Herklotsichthys zunasi, 1.7%; Callionymidae spp., 1.6%. These 5 taxa occupied 97.7% of the total eggs. Pelagic eggs occurred from April to October. In June and July, their abundances were high, but the species diversities were low as E. japonica eggs were predominant. The range of spawning temperature for each taxa were estimated from the occurence pattern of the pelagic eggs.

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Synthesis and Characterization of Multi-Block Sulfonated Poly (Arylene Ether Sulfone) Polymer Membrane with Different Hydrophilic Moieties for PEMFC (서로 다른 친수성구조를 가지는 고분자전해질 연료전지용 멀티블록형 술폰산화 폴리아릴렌에테르술폰 전해질막의 합성 및 특성 분석)

  • Yuk, Jinok;Lee, Sojeong;Yang, Tae-Hyun;Bae, Byungchan
    • Journal of the Korean Electrochemical Society
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    • v.18 no.2
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    • pp.75-80
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    • 2015
  • Multi-block sulfonated poly(arylene ether sulfone) (SPAES) copolymer was synthesized via nucleophilic aromatic substitution reaction for proton exchange membrane fuel cell application. After synthesizing the hydrophilic and hydrophobic precursor oligomers having different end-groups (F-terminated or OH-terminated), the effect of end group on the molecular weight was investigated. Hydrophilic oligomers with hydroquinone showed better performance as fuel cell membranes. SPAES membranes showed comparable proton conductivity to that of Nafion at $80^{\circ}C$ and above 70% RH. In particular, SPAES 9 with hydroquinone showed higher proton conductivity than SPAES 10 in the whole RH range studied. Increased local concentration of sulfonic acids within hydrophilic block might develop the hydrophilic-hydrophobic phase separation in the block copolymers.

A Literature Review on Trauma from Occlusion (교합성 외상에 관한 논쟁의 고찰)

  • Park, Go-Woon;Kim, Dae-Gon;Park, Chan-Jin;Cho, Lee-Ra
    • Journal of Dental Rehabilitation and Applied Science
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    • v.27 no.4
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    • pp.423-436
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    • 2011
  • Trauma from occlusion (TFO) is a pathologic alterations which develop in the periodontium as a result of undue masticatory force. The purpose of this article is to review the controversies about TFO. There are evidences that TFO is a risk factor in the progression of periodontitis. Tooth mobility should be reduced by selective occlusal adjustment. TFO can be developed dependent on the masticatory pattern, occlusion and anterior overbite in sound periodontal conditions. Secondary TFO may aggravate unstable occlusion. If "loss of posterior support" was occur, the problems were worsen. Extrusion, migration, rotation and pathologic deviation can be resulted. Opposite contention is the "shortened dental arch" concept. However, these two concepts persue the occlusal stability together. To treat TFO adequately, exact diagnosis and multi-disciplinary treatment should be needed.