• Korean Chemical Engineering Research
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• v.54 no.1
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• pp.52-56
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• 2016

As an effective method for extraction of succinic acid, aqueous two-phase systems based on piperidinium ionic liquids were used in this study. Effects of the alkyl chain length of cation in piperinidium ionic liquids on phase diagram and extraction efficiencies were investigated. Experimental results show that aqueous two phase systems can be formed by adding appropriate amount of piperidinium ionic liquids to aqueous $K_2HPO_4$ solutions. It can be found that the ability of piperidinium ionic liquids for phase separation followed the order [OMPip][Br]>[HMPip][Br]>[BMPip][Br]>[EMPip][Br]. The biphase-forming ability of piperidinium ionic liquids was higher than that of imidazolium and pyrrolidinium ionic liquids in the presence of $K_2HPO_4$. 75~95% of the succinic acid could be extracted into the ionic liquid-rich phase in a single-step extraction. There was little difference in the extraction efficiency of succinic acid by piperidinium ionic liquids comparing to other ionic liquids such as imidazolium and pyrrolonidium ionic liquids. This aqueous two phase system by piperidinium ionic liquid is suggested to have effective application for the separation of succinic acid.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.3
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• pp.763-769
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• 2021

In this study, ionic liquids were synthesized to remove carbon dioxide (CO2) on a laboratory scale. The vapor-liquid absorption equilibrium device (VLE) was used to investigate the carbon dioxide absorption capacity. In the regeneration study, the absorption capacity after regeneration was reduced by approximately 7% for all ionic liquids, in which the anion was sulfite-based, showing excellent regeneration. Ethyl sulfite showed the highest absorption capacity of CO2 among the ionic liquids based on the sulfite anion. In particular, the absorption capacity of [beim] ethyl sulfite was 1.1 mol CO2 / mol IL at an absorption equilibrium pressure of 22 bar. In the regeneration study, the absorption capacity after regeneration was reduced by approximately 7% for all ionic liquids, in which the anion was sulfite-based, from which regeneration is outstanding. After the absorption experiment, the viscosity of the sample tended to decrease by approximately 8% compared to that before the absorption experiment. On the other hand, the absorbent was synthesized in the first step. Moreover, the raw material used is also inexpensive and has excellent reproducibility and highly stable absorbent capacity.

• Korean Chemical Engineering Research
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• v.48 no.5
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• pp.621-626
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• 2010

In this study, imidazole-based ionic liquid on polystyrene was prepared and its catalytic performance in the cycloaddition of $CO_2$ with allyl glycidyl ether(AGE) to produce allyl glycidyl carbonate was investigated. The ionic liquid was generated on the polystyrene-based polymer through the immobilization of imidazole. The prepared catalyst was characterized using a number of instrumental analysis including EA, FT-IR, TGA and SEM. The immobilized ionic liquid showed very good catalytic activity for the cycloaddition of $CO_2$ with AGE, having 80% of AGE conversion with over 96% of the carbonate selectivity at $120^{\circ}C$ under 1.48 MPa $CO_2$ pressure. The immobilized ionic liquid can be used for the reaction up to four consecutive runs without significant loss of its catalytic activity.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.29 no.6
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• pp.513-519
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• 2016

In this study, dynamic vertical displacement of liquid in the tuned liquid column damper(TLCD) is measured by a laser Doppler vibrometer(LDV) to overcome limitations of existing sensors and to leverage noncontact sensing. Addressing advantages of noncontact measurements, operational principles of the LDV to measure velocity and displacement of a target object in motion is explained. The feasibility of application of the LDV to measurement of liquid motion in the TLCD is experimentally explored. A series of shake table tests with the TLCD are performed to determine requirements of application of the LDV. Based on the experimental results, it is proved that the LDV works under the condition of adding dye to the liquid by increasing the intensity of reflected laser and thus validity is verified by comparison with a conventional wave height meter.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.11a
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• pp.85-88
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• 2010

This study has been mainly motivated to numerically model the supercritical mixing and combustion processes encountered in the liquid propellant rocket engines. In the present approach, turbulence is represented by the extended $k-{\varepsilon}$ turbulence model. To account for the real fluid effects, the propellant mixture properties are calculated by using SRK (Souve-Redlich-Kwong) equation of state. In order to realistically represent the turbulence-chemistry interaction in the turbulent nonpremixed flames, the flamelet approach based on the real fluid flamelet library has been adopted. Based on numerical results, the detailed discussions are made for the real fluid effects and the precise structure of gaseous methane/liquid oxygen coaxial jet flame.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.04a
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• pp.89-92
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• 2011

The modeling of thermodynamic non-idealities and transport anomalies is a crucial prerequisite to realistically simulate the mixing and combustion processes of liquid propellants injected above critical pressures. This study has developed a specific set of subroutines to calculate the thermodynamic and transport properties based on the generalized cubic equation of state (EoS) in a coupled manner with the standard chemical kinetics packages (Chemkin). The existing flamelet analysis code is extended with the real-fluid package and applied to numerical investigation of local flame structures of kerosene and liquid oxygen at high pressure conditions relevant to the actual rocket engines.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2006.11a
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• pp.329-330
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• 2006

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2007.04a
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• pp.322-325
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• 2007

This paper shows the development procedure of the low pressure LOX feed system which is used in the liquid rocket with a turbopump. Korean Air has cooperated with KARI in developing the LOX feed system to turbopump. The LOX feed system is characterized with cryogenic temperature and the thin-thickness tube for weight saving. The system in this project is composed with a main feed line and a recirculation line for the LOX temperature conditioning. Each piping system has many components, namely, bellows, filter, orifice, valves, flange and support. In this paper, system design & manufacturing, structural & thermal analyses, and component tests are explained. Finally, the system was assembled to the KARI's PTF test facility and functioned well to meet its required performance.

• Journal of the Korean Society of Propulsion Engineers
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• v.22 no.1
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• pp.1-6
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• 2018

Temperatures of cryogenic nitrogen jet inside an injector and at three different downstream positions (0.9, 10.6, and 28.1d) were measured with thermocouples in sub- and supercritical states. The jet temperature decreased while cooling the supply line and injector. The jet experienced from flash boiling, boiling and then no boiling according to decreasing temperature. As an analogy to flash-boiling at the subcritical state, pseudo-flash boiling has been assumed considering the existence of pseudo-boiling at the supercritical state. By showing an area where the temperature did not increase downstream, the plausibility of pseudo-flash boiling is proposed.

• KSBB Journal
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• v.25 no.4
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• pp.337-343
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• 2010

It has been well known that organic solvents like t-butanol and n-hexane can protect lipases from the inhibition by short-chain alcohols in the enzymatic transesterification. However, use of the organic solvents should be minimized considering their negative effects on environment and human health. Therefore, use of the greener solvents has been pursued in various are as including the enzymatic biotranformation. In this study, the liquid carbon dioxide ($LCO_2$) was employed as an alternative media for the enzymatic transesterification of canola oil. The conversion in the $LCO_2$ was comparable with those in organic solvents and the supercritical carbon dioxide, and under optimum conditions, the value reached 99.7%. It is expected that this method can provide a new type of biodiesel production process with higher energy efficiency and lower environmental impact.