• Journal of the Korean Solar Energy Society
• /
• v.30 no.5
• /
• pp.17-24
• /
• 2010

태양열 제습냉방은 액체흡수제를 이용한 냉각효과로 기존의 전기에너지를 가능케 하는 해결책중 하나이다. 따라서 태양열을 거의 활용하지 않는 여름에 가열온수를 열원으로 활용하여 쾌적조건을 구현하는 본 연구의 대상인 태양열냉방시스템은 제습기와 재생기로 크게 이루어져 있다. 본 논문은 제습기의 유량 변화에 따른 열전달 및 물질전달의 변화를 실험과 이론적 해석으로 규명하고 있는데, 흐름의 양상은 병렬형과 대향류형을 대상으로 하고 있다. 실험결과와 이론해석이 비교적 잘 일치하였으며, 대향류형이 병렬형보다도 물질전달 면에서 유리하게 나타났으며, 입 출구의 엔탈피 차이에서도 크서 열전달에서도 우수한 것으로 나타났다. 또한 그 차이를 본 논문에서는 나타내었으며, 일정한 높이나 길이 이상에서는 항상 일정함을 알 수 있었다. 따라서 본 논문의 결과들은 제습기의 유동흐름을 통한 태양열냉방시스템 중 제습기의 설계 및 성능 향상에 도움을 줄 것이다.

• Analytical Science and Technology
• /
• v.12 no.3
• /
• pp.224-229
• /
• 1999

Recently, many studies for the supported liquid membrane (SLM) using a carrier have been actively reported. Polymeric cation exchange membrane was synthsized by dissolving monensin carrier of antibiotic material in organic solvent. Then the SLM was applied to the Nernst-Planck and Fick equations and membrane potential and membrane permeability were measured respectively. The results showed the high selectivity towards alkali metal ions and the SLM showed linear relationship with low concentration. However, linear relationship did not appear at high concentration. This is explained by means of the new theory of the stagnant layer and the slop of logarithm value was linear for the up-hill transport phenomena of membrane transport.

• Proceedings of the Korean Radioactive Waste Society Conference
• /
• 2003.11a
• /
• pp.220-225
• /
• 2003

Generally, liquid radioactive wastes generated in nuclear power plant exist in powder form which do not contain moisture through the evaporating process of the Liquid Waste Management System and drying process of the Concentrated Waste Drying System. This powder form wastes are blended homogeneously with paraffin solidification agent and packed in metal drum to ensure its stability during handling and disposal. However, it was experienced that the powder form wastes were not blended homogeneously and separated into two layers in metal drum, on the other hand, a Portion of powder was adhered and solidified to the Inside parts of facility during the blending process. And the flaw of blending process above would come in case the mole ratio of Boron to Sodium in liquid radioactive wastes exceeds 0.2.

• Journal of the Korean Chemical Society
• /
• v.35 no.3
• /
• pp.204-210
• /
• 1991

Multilayer adsorption isotherms of nitrogen and argon on the perovskite-type mixed oxides, synthesized by a citrate coprecipitation method, are determined at the liquid nitrogen temperature using a gravimetric adsorption apparatus. The volume of the adsorbed gas are plotted against the statistical thickness of the adsorbed layer, calculated from several universal adsorption isotherms one after another. The t-method area obtained from this plot is compared with the BET area and finally the appropriateness of universal adsorption isotherms is then discussed on the basis of the plot.

• Journal of the Korean Chemical Society
• /
• v.14 no.1
• /
• pp.97-107
• /
• 1970

The grand canonical ensemble partition function for the adsorbed phase of gases on solid surfaces is derived according to the transient state theory of significant liquid structure. The derived adsorption isotherms from the partition function for argon, nitrogen and benzene adsorbed on various adsorbents are in good agreement with the observed values. The surface pressure, the molar entropy, the molar internal energy and the molar heat of adsorption are calculated for benzene adsorbed on graphite. The molar entropy is minimum at near the pressure where a close packed monolayer is formed. The method of parameter determination is illustrated.

• Korean Journal of Materials Research
• /
• v.18 no.3
• /
• pp.128-136
• /
• 2008

Evaluation of the solid surface properties by an analysis of the liquid penetration rate into powder beds is very important in applications of powder products. The penetration rate is related the surface property in powder beds. In order to analyze the surface property of powders, the contact angle values of several powders were obtained using the Washbun equation and the Wicking method. The surface free energy value ${\gamma}S$ was divided into a polar component ${\gamma}S^p$ and a dispersion component ${\gamma}S^d$. Inorganic powders such as calcite were used as test samples. The effects of the particle size and the type of experimental liquid on the penetration rate were measured. It was confirmed that the surface free energy of the grinding sample is smaller than that of the classification sample.

• Journal of Hydrogen and New Energy
• /
• v.27 no.2
• /
• pp.176-181
• /
• 2016

Recent years, supercapacitors have been attracting a growing attention as an efficient energy storage, due to their long-lifetime, device reliability, simple device structure and operation mechanism and, most importantly, high power density. Along with the increasing interest in flexible/stretchable electronics, the supercapacitors with compatible mechanical properties have been also required. A eutectic gallium-indium (EGaIn) liquid metal could be a strong candidate as a soft electrode material of the supercapacitors because of its insulating surface oxide layer for electric double layer formation. Here, we report the electrochemical study on the charging/reaction process at the interface of EGaIn liquid metal and electrolyte. Numerical fitting of the charging current curves provides the capacitance of EGaIn/insulating layer/electrolyte (${\sim}38F/m^2$). This value is two orders of magnitude higher than a capacitance of a general metal electrode/electrolyte interface.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2010.02a
• /
• pp.330-330
• /
• 2010

하나로 노심에서 발생하는 열중성자를 감속재인 액체수소층을 통과시켜 냉중성자를 생산 하는 설비인 냉중성자원 시설은 초경량 합금, 신소재 및 DNA 구조연구 등의 첨단기술연구에 유용한 도구로 활용될 계획이며, 현재 원자력연구원에서는 냉중성자원 시설을 개발하여 제작 설치하였고, 이 장치들에 대해 기능시험을 수행하였다. 냉중성자원 시설계통에서 가스블랭킷계통은 수소의 외부누출을 방지하고, 진공용기를 포함한 수조내기기 내부로 공기 및 경수가 유입되지 않도록 하여 냉중성자원을 보호하기 위한 역할을 수행한다. 또한 가스블랭킷계통의 구성은 가스공급장치($N_2$ 및 He 가스 실린더로부터 가스공급 기능), 질소충압탱크, 진공박스, 수소박스, 밸브박스 및 각 구역별 독립 배관 등으로 되어있다. 이동식 진공배기장치는 가스블랭킷계통에서 사용하기 위해 특수하게 제작된 장치로서 진공계통과 수소계통의 초기충진 시 또는 계통배기 시 잔류가스를 제거하거나, 블랭킷가스의 오염검사를 위한 시료채취 기능 등을 수행할 수 있도록 되어있다. 본 논문에서는 냉중성자원장치 내의 수소계통 및 진공계통의 배관과 기기를 외기와 경수로부터 안전하게 격리시키기 위해서 제작설치 적용된 가스블랭킷계통에서 이동식 진공배기장치를 이용하여 잔류가스 제거방법과 각 가스블랭킷 영역으로부터 시료를 채취하여 수행된 산소농도 분석에 대해 기술하였다.

• Korean Chemical Engineering Research
• /
• v.46 no.3
• /
• pp.451-464
• /
• 2008

Three-phase inverse fluidized bed has been widely adopted with its increasing demand in the fields of bioreactor, fermentation process, wastewater treatment process, absorption and adsorption processes, where the fluidized or suspended particles are small or lower density comparing with that of continuous liquid phase, since the particles are frequently substrate, contacting medium or catalyst carrier. However, there has been little attention on the three-phase inverse fluidized beds even on the hydrodynamics. Needless to say, the information on the hydrodynamics and transport phenomena such as heat and mass transfer in the inverse fluidized beds has been essential for the operation, design and scale-up of various reactors and processes which are employing the three-phase inverse beds. In the present article, thus, the information on the three-phase inverse fluidized beds has been summarized and reorganized to suggest a pre-requisite knowledge for the field work in a sense of engineering point of view. The article is composed of three parts; hydrodynamics, heat and mass transfer characteristics of three-phase inverse fluidized beds. Effects of operating variables on the phase holdup, bubble properties and particle fluctuating frequency and dispersion were discussed in the section of hydrodynamics; effects of operating variables on the heat transfer coefficient and on the heat transfer model were discussed in the section of heat transfer characteristics ; and in the section of mass transfer characteristics, effects of operating variables on the liquid axial dispersion and volumetric liquid phase mass transfer coefficient were examined. In each section, correlations to predict the hydrodynamic characteristics such as minimum fluidization velocity, phase holdup, bubble properties and particle fluctuating frequency and dispersion and heat and mass transfer coefficients were suggested. And finally suggestions have been made for the future study for the application of three-phase inverse fluidized bed in several available fields to meet the increasing demands of this system.

• Journal of the Korean Institute of Gas
• /
• v.25 no.4
• /
• pp.10-18
• /
• 2021

CO₂ storage technology in an aquifer is one of the most effective way to decrease global warming due to a high storage capacity and economics. A demonstration-scale offshore CO₂ storage project was performed in a geological deep aquifer in the Pohang Basin, Korea for a technological development of large-scale CO₂ storage. A challenging issue in the early design stage of the project was to establish the proper injectivity during CO₂ injection. To solve this issue, injection conditions were calculated by calculating injection rate, pressure, temperature, CO₂ phase change, and thermodynamic properties. For this study, we simulated and numerically analyzed CO₂ phase change from gas to supercritical phase and flow behavior in transport piping and injection tubing using OLGA program. Our results provide the injectivity conditions of CO₂ injection system combined with a bottomhole pressure of an aquifer.