• Applied Chemistry for Engineering
• /
• v.8 no.5
• /
• pp.763-770
• /
• 1997

The separation of benzene-cyclohexane mixture using (O/W)/O emulsion liquid membrane was studied. The operating parameters which can affect the selectivity, benzene yield, and emulsion size distribution were examined and determined by the batch type operation. The unsteady state and steady state extraction behavior in continuous pulse stirred reactor(CPSR) were verified. The optimum conditions for benzene selectivity and yield in batch operation were as follows; emulsion mixing intensity 4000 rpm, Tween 80 concentration 0.4%, volume ratio of membrane phase to internal phase 0.75, volume ratio of dispersed phase to continuous phase 0.5, and permeation time 10 minutes, As impeller speed increased and the microdrop holdup decreased, the Sauter mean diameter decreased. Turbulence damping parameter of modified Calabrease correlation considering microdrop holdup was 2.28. The optimum conditions of continuous operation were as follows; agitation speed 300 rpm, pulse frequence 2 times/sec, flow rate of continuous phase 30ml/min, and flow rate of emulsion phase 12.0ml/min.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.8 no.2
• /
• pp.39-45
• /
• 2004

Experiments were performed in a two-phase swirling spray facility that has been described elsewhere. Measurements of spray transport and drop size distribution are analyzed over wide ranges of air to liquid mass flow ratios, utilizing four different internal mixing pneumatic nozzles. The spatial distributions of mean velocities. fluctuating velocities, and velocity-diameter correlation were quantitatively analyzed. Also, the exponential correlation curves were obtained with ALR along the spray centerline, which indicated an approximately identical formulation regardless of ALR. It indicated that the atomization characteristics were remarkably superior in the case of 30o of swirl angle with higher ALR. Among other things. nozzle configuration is one of the significant parameters affecting spray phenomena from an internal mixing nozzle. Turbulence intensities are increasingly degenerated with an increase of nozzle configuration, allowing a rapid increment of drop size distribution.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.11 no.3
• /
• pp.50-57
• /
• 2007

Spray characteristics of an injector in a small liquid rocket engine (LRE) is characterized by Particle Image Velocimetry (PIV) and Dual-mode Phase Doppler Anemometry (DPDA). Instantaneous plane images captured by PIV are examined for the qualitative prediction of spray breakup with the setup of evaluation technique for effect of spray angles on injector performance. DPDA is also applied in order to quantify the average velocity, turbulent intensity, SMD, and number density of spray droplets along the spray stream distance leading to precise observation of spray atomization behavior. An objective of the study is the derivation of design parameters of new injectors and the establishment of performance criteria through the clear understanding of spray characteristics.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2007.11a
• /
• pp.359-364
• /
• 2007

Spray characteristics of the APU gas turbine engine were investigated. In order to understand blow out phenomena of the APU engine, we performed fuel spray test. In the test, four operating conditions such as sea level idle, sea level max power, 20,000 feet idle, 20,000 feet max power were used as spray experimental conditions. PDPA(phase Doppler Particle Analyzer) was used for measuring the particle diameter and velocity. Also spray visualization was performed by using ND-YAG sheet laser beam. From the test result, in the case of 20,000 feet idle condition, SMD is about 100 ${\mu}m$ and maximum particle velocity is about 10 m/s. For the flame stability, spray quality should be improved at 20,000 feet idle condition.

• Journal of ILASS-Korea
• /
• v.5 no.1
• /
• pp.30-40
• /
• 2000

The characteristics of liquefied butane spray are expected to be different from conventional diesel fuel spray, because a kind of flash boiling spray is expected when the back pressure is below the saturated vapor pressure of the butane(0.23MPa at 298K). The ambient pressure was held at a pressure above(0.37MPa) and below(0.15MPa) the fuel vapor pressure. The axial velocities, radial velocities, and size distributions in butane sprays were measured with PDPA(Phase Doppler Particle Analyzer) system. The PDPA measurement showed a smaller SMD at the 0.15MPa chamber pressure, compared to the 0.37MPa case. Log-hyperbolic density function for the droplets size distribution can be fitted to the experimental results of a liquefied butane spray.

• Proceedings of the Korean Institute of Resources Recycling Conference
• /
• 2005.10a
• /
• pp.308-313
• /
• 2005

실리콘 잉고트의 절단공정에서 발생하는 폐실리콘 슬러지는 실리콘과 실리콘카바이드 등의 유가자원이 함유되어 있으며, 이 중 실리콘 분말은 실리콘 화합물인 알콕시실란 등을 제조하는데 원료로 사용이 가능하다. 본 연구에서는 폐실리콘 슬러지로부터 분리, 합성된 사에 톡시실란(TEOS)을 원료로 이용하여 실리카 나노분말을 합성하였다. TEOS 원료물질을 외부 혼합형 이류체 노즐을 이용하여 미세액적으로 분무하고 화염 속으로 도입시키고 화염열분해 반응을 진행시켜 실리카 나노분말을 합성하였다. 합성된 실리카 나노입자의 특성은 투과형 전자현미경 및 BET에 의하여 입자형상 및 평균 입자크기가 분석되었다. 주요 공정변수인 분산공기의 압력, 반응가스의 조성을 변화시켜 실험한 결과 평균크기가 $9{\sim}68nm$인 실리카 나노분말을 제조하였다.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2003.10a
• /
• pp.168-172
• /
• 2003

The effects of injection conditions on the droplet sizes resulting from the disintegration of a liquid jet by a fast annular gas stream have been investigated using PDPA. The gas/liquid momentum ratio M = $\rho$$_{g}$ $U_{g}$$^2$/$\rho$$_1$ $U_1$$^2$ and Weber number We = $\rho$$_{g}$ $g^2$ $D_1$/$\sigma$ are selected as key parameters in atomization of shear coaxial spray from the fluid mechanics standpoint. It is revealed that SMD( $D_{32}$) varies inversely with gas/liquid momentum ratio(M), whereas Weber number(We) has little effect on the droplet sizes as gas velocities increase. It is found that gas/liquid momentum ratio is more dominant factor controlling the breakup and atomization process of shear coaxial spray. Finally, an empirical correlation between SMD and injection conditions(i.e. gas/liquid momentum ratio M and Weber number We) is proposed based on the experimental results.

• Fire Science and Engineering
• /
• v.19 no.3 s.59
• /
• pp.13-19
• /
• 2005

An experimental study is presented for extinguishing characteristics of liquid fuel fire by water mist containing sodium acetate trihydrate. To evaluate the extinguishing performance of water mist containing an additive, the evaporation characteristics of a water droplet on a heated surface was examined. The evaporation process was recorded by a charge-coupled-device camera. Also, small-scale extinguishing tests were conducted for n-heptane pool fire in ventilated space to measure flame temperature variation. The average evaporation rate of a water droplet containing an additive was lower than that of a pure water droplet at a given surface temperature due to the precipitation of salt in the liquid-film and change of surface tension. In case of using an additive, the flame temperature was lower than that of pure water at a given discharge pressure and it was because the momentum of a water droplet containing an additive was increased reducing flame size. And also dissociated metal atoms, sodium, were reacted as a scavenger of the major radical species OH^-,\;H^+$ which were generated for combustion process. Moreover, at a high pressure of 4MPa, the fire was extinguished through blowing effect as well as primary extinguishing mechanisms.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.15 no.8
• /
• pp.4809-4814
• /
• 2014

The aim of the present study was to estimate the prediction performance of a FDS (Fire Dynamic Simulator) to simulate the fire behaviors and suppression characteristics by operating a water-mist. Rosin-Rammler/log-normal distribution function was used to determine the initial droplet distribution of water-mist and the effects of its model constant were considered. In addition, the simulation models were validated by a comparison of the predicted fire suppression characteristics with water-mist injection pressures to the previous experiments, and the thermal flow behaviors and gaseous concentration variations were analyzed. The results showed that water-mists with the same mean diameter were affected by the characteristics of the droplet size distribution, which have different size and velocity distributions at the downstream location. The fire simulations conducted in this study determine the initial droplet size distribution tuned to the base of the spray characteristics measured by previous experiments. The simulation results showed good agreement with the previous measurements for temperature variations and fire suppression characteristics. In addition, it was confirmed that the FDS simulation with a water-mist operation supplies useful details on estimations of the thermal flow fields and gaseous concentration under water mist operation conditions.

• Applied Chemistry for Engineering
• /
• v.30 no.5
• /
• pp.606-614
• /
• 2019

A mixing ratio of the oil in water (O/W) emulsion of palm oil and the non-ionic surfactant (Tween-Span type) possessing different hydrophile-lipophilie balance (HLB) values was evaluated in this work. An optimum condition was determined through analysis of main and interaction effects of each quantitative factor using central composite design model-response surface methodology (CCD-RSM). Quantitative factors used by CCD-RSM were an emulsification time, emulsification speed, HLB value and amount of surfactant. On the other hand, the reaction parameters were the viscosity and mean droplet size of O/W emersion. Optimized conditions obtained from CCD-RSM were the emulsification time of 12.7 min, emulsification speed of 5,551 rpm, HLB value of 8.0 and amount of surfactant of 5.7 wt.%. Ideal experimental results under the optimized experimental condition were the viscosity of 1,551 cP and mean droplet size of 432 nm which satisfy the targeted values. The average error value from our actual experiment for verifying the conclusions was below to 2.5%. Therefore, a high favorable level could be obtained when the CCD-RSM was applied to the optimized palm oil to water emulsification.