• Title/Summary/Keyword: 액상함침법

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A Study of Catalysts for Decomposition of ADN-Based Liquid Monopropellant (ADN기반 단일액상추진제 분해용 촉매 제조 및 특성 연구)

  • Jeon, Jong-Ki;Heo, Sujeong;Jo, Young Min;Kim, Taegyu
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.412-415
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    • 2017
  • In this study, the decomposition performance of ammonia dinitramide (ADN) based liquid monopropellant was evaluated by using metal supported alumina bead catalyst. Alumina bead was calcined at $1200^{\circ}C$, and Pt and Cu were impregnated on alumina bead by excess water impregnation using a rotary evaporator. The decomposition temperature ($T_{dec}$) of ADN-based liquid monopropellant was measured in a home-made batch reactor. The decomposition temperature of Cu/$Al_2O_3$ catalyst was lower than that of Pt/$Al_2O_3$ catalyst, and $T_{dec}$ was about $130^{\circ}C$.

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Errects of the Length of Carbon Fiber on the Wear Properties of Carbon/Carbon Composites (탄소/탄소 복합재료의 마모특성에 대한 탄소섬유 길이의 영향)

  • Ha, Hun-Seung;Kim, Dong-Kyu;Park, In-Seo;Im, Yeon-Su;Yun, Byung-Il
    • Korean Journal of Materials Research
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    • v.3 no.3
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    • pp.292-299
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    • 1993
  • In this paper the effects of the length of carbon fiber on the wear properties of carboni carbon composites were investigated. Carbon/carbon composites were fabricated by the liquid impregnation method using the resol-type phenolic resin as a matrix precursor and PAN-based, non-surface treated carbon fiber as a reinforcement. The measured values of the friction coefficient of carbon/carbon composites against AlSl 304 stainless steel ranged from 0.2 to 0.3 under the operating condition used in this study. The effect of the length of carbon fiber on the friction coefficient of carbon/carbon composites were not found. But, it was realized that the wear rate of carbon/carbon composites tends to increase, as the length of carbon fiber increases.

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Characteristics of methane reforming with carbon dioxide using transition metal catalyts (전이금속 촉매를 이용한 이산화탄소와 메탄의 개질 특성)

  • Jang, Hyun Tae
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.2
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    • pp.644-650
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    • 2021
  • This study characterized the reforming of methane with carbon dioxide, which is a major cause of global warming. The methane decomposition reaction with carbon dioxide was carried out using transition metal catalysts. The reactivity of tin was lower than that of a transition metal, such as nickel and iron. Most of the decomposition reaction occurred in the solid state. The melting point of tin is 505.03 K. Tin reacts in a liquid phase at the reaction temperature and has the advantage of separating carbon produced by the decomposition of methane from the liquid tin catalyst. Therefore, deactivation due to the deposition of carbon in the liquid tin can be prevented. Methane decomposition with carbon dioxide produced carbon monoxide and hydrogen. Ni was used to promote the catalyst performance and enhance the activity of the catalyst and lifetime. In this study, catalysts were synthesized using the excess wet impregnation method. The effect of the reaction temperature, space velocity was measured to calculate the activity of catalysts, such as the activation energy and regeneration of catalysts. The carbon-deposited tin catalyst regeneration temperature was 1023 K. The reactivity was improved using a nickel co-catalyst and a water supply.

Synthesis and Characteristic Evaluation of Downward Conversion Phosphor for Improving Solar Cell Performance (태양전지 성능향상을 위한 하향변환 형광체의 합성 및 특성평가)

  • Jae-Ho Kim;Ga-Ram Kim;Jin-To Choi;Soo-Jong Kim
    • The Journal of the Convergence on Culture Technology
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    • v.9 no.5
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    • pp.523-528
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    • 2023
  • The applicability as a material to improve solar cell performance was reviewed by synthesizing a phosphor that emits red wavelengths by a liquid synthesis method using a metal salt aqueous solution and a polymer medium as a starting material. An aqueous solution was prepared using nitrate of metals such as Ca, Zn, Al, and Eu, and a precursor impregnated with starch, a natural polymer, was sintered to synthesize CaZnAlO:Eu phosphor powder. The surface structure and composition analysis of the synthesized CaZnAlO:Eu phosphor powder were analyzed by scanning electron microscope(SEM) and energy-dispersed X-ray spectroscopy(EDS). The crystal structure of CaZnAlO:Eu phosphor particles was analyzed by an X-ray diffraction analyzer (XRD). As a result of measuring the photoluminescence(PL) characteristics of the phosphor, it was confirmed that a red phosphor with a light emitting wavelength of 650-780nm was successfully synthesized. According to SEM and EDS analysis, the synthesized Ca14Zn6Al9.93O35:Eu3+0.07 phosphor powder has a uniform particle size, and Eu ions used as an activator are present. The synthesized CZA:Eu3+ phosphor can be used as a material that can increase the light absorption efficiency of the solar cell by converting ultraviolet or visible light down conversion into a wavelength in the near-infrared region.