• Korean Chemical Engineering Research
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• v.56 no.1
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• pp.119-124
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• 2018

The production of methyl N-phenyl carbamate by an oxidative carbonylation method of aniline and methanol is of great interest as an environmentally friendly process that can replace the monomer production process of a polymer produce using conventional phosgene. In this study, heterogeneous catalysts were prepared by using Y-zeolite, $SiO_2$, $Al_2O_3$ as support, and oxidative carbonylation continuous operation from aniline and methanol was attempted using the prepared heterogeneous catalyst. Batch reactor was used to determine the support, and various reaction conditions such as reaction temperature, reaction pressure, and effect of promoter were established using palladium catalyst. A reaction kinetics study was conducted under optimum reaction conditions. The basic data for carbamate process development were obtained by performing continuous operation for a long time under established reaction condition.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.1
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• pp.42-48
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• 2012

In this study, experiment on phosphorus removal was performed by using microbubble liquid film flotation tank with microbubble module. After dissolving gas and liquid in dissolving tank, microbubble liquid film system created microbubbles in equal size under fixed low pressure. After being passed through $A_2O$ and m-$O_3$ process, secondary treatment wastewater was used as influent in phosphorus removal process. When the T-P concentration of influent was 2.89 mg/L, alum(8%, 30 mg/L) was injected into a microbubble flotation tank, the treatment resulted 94% of T-P removal rate. Remaining T-P concentration was less than 0.2 mg/L, which is in accord with the effluent quality standard. Seasonal variations in water temperature showed no differences in T-P removal property. When the inflow concentration of SS was 1.0 mg/L or more, it served as coagulation nuclei in the coagulation process. In that condition, average T-P removal rate was higher than 97%. When 50% of floated scum was returned, coagulator Al included in scum assisted the injected coagulator and maximized the coagulation efficiency of pollutant. In such treatment, the T-P concentration was measured as 0.18 mg/L and satisfied the outflow water quality standard, which is 0.2 mg/L or less.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.7
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• pp.521-530
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• 2009

This study has been made to execute a research in order to lead the improvement of indoor air quality, examining the indoor ventilation characteristics by using a numerical analysis method. To this end an extensive parametric investigation are made according to various external flow variables such as main wind direction and wind speed by season, building layout design, and location of ventilators, etc. in Daedeok Techno Valley, one of large-scaled apartment in Daejeon. It is observed there was a significant difference of main wind direction between summer and winter. The main wind direction in summer was a south wind, and on the contrary the direction in winter is northnorthwest, which is similar to the average main wind direction for 10 years. One of the important calculation results is that the change of wind direction causes a significant effect on the apartment ventilation by the change of pressure difference around each complex of apartment. In case of favorable area of ventilation, the indoor ventilation rate can meet 0.7 ACH from the standard value only with natural ventilation. On the contrary, in other area the value was much lower than the standard value. If the calculation result applies to the design of layout apartment or placement of ventilators, it will be greatly helpful to the energy saving because it can be parallel with the natural ventilation to help securing ventilation rate, not much depending on the mechanical ventilation.

• Tunnel and Underground Space
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• v.27 no.3
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• pp.132-145
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• 2017

Shock loss was not applied for the tunnel ventilation of road tunnel in the past. However, pressure losses due to the shock loss can be significant in network double-deck road tunnel in which combining and separating road structures exist. For the optimum ventilation design of network double-deck road tunnel, this study conducted 3D CFD numerical analysis for the shock loss at the combining and separating flows. The CFD model was made with the real-scale model that was the standard section of double-deck road tunnel. The shock loss coefficient of various combining and separating angles and road width was obtained and compared to the existing design values. As a result of the comparison, the shock loss coefficient of the $30^{\circ}$ separating flow model was higher and that of the two-lane combining flow model was lower. Since the combining and separating angles and road width can be important for the design of shock loss estimation, it is considered that this study can provide the accurate design factors for the calculation of ventilation system capacity. In addition, this study conducted 3D CFD analysis in order to calculate the shock loss coefficient of both combining and separating flows at flared intersection, and the result was compared with the design values of ASHRAE. The model that was not widened at the intersection showed three times higher at the most, and the other model that was widened at the intersection resulted two times higher shock loss coefficients.

• Journal of the Korean Wood Science and Technology
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• v.42 no.3
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• pp.258-265
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• 2014

By replacing the previous metal connector on the joints of timber structure, the GFRP reinforced laminated wooden pin was produced using a wooden material and Glass fiber reinforced plastic(GFRP) composite laminate. In addition, using the reinforced wooden pin, the tensile type shear strength test was conducted. Based on the result of the bending strength test of the reinforced laminated wooden pin according to the GFRP arrangement, a specimen(Type-A) with a single insertion of GFRP for each layer have shown the most favorable performance. Also, it was verified that densified specimen hot pressed for an hour at the temperature of $150^{\circ}C$ and with the oppression pressure $1.96N/mm^2$ have shown the improved performance of 1.57 times than the specimen without the densification. And in the bending strength test considering the load direction, edgewise have shown a higher performance of 3.51 times than the flatwise. A shear strength test was conducted using the Type-A reinforced laminated wooden pin which have shown a moderate performance on the test. Based on the test conducted by differentiating the type of the joint plate and the connector, compared to the specimen(Type-DS) applied with the drift pin and steel plate, the specimen( Type-WL) applied with the GFRP reinforced laminated wooden pin and GFRP reinforced wooden laminated plate have shown 1.12 times higher shear strength and also have shown an excellent toughness even after the maximum load.

• Journal of the Korean Wood Science and Technology
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• v.42 no.3
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• pp.282-289
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• 2014

After being laminated with a combination of glass fiber reinforced plastic and plywood, the GFRP laminated plate was densificated for 1 hour at $150^{\circ}C$ with pressure of $1.96N/mm^2$. A partial reinforced beam was produced by attaching the 5 GFRP laminated plates to the joint of glulam and the column. In addition, the column to beam joint was produced by using reinforced laminated wooden pin which was made of GFRP sheet and plywood, fiber glass reinforced cylindrical-LVL column. The joint was made of round log, glulam and drift pin as the reference specimen, and its moment resistance was evaluated. As a result, the strength performance of specimens with partial reinforced beams were 1.8 times stronger than the reference specimen on average. Furthermore, rupture was neither occurred on partial reinforced beam nor column. Toughness and stiffness of joints were also fine. The GFRP sheet reinforced laminated plate showed better reinforcement effect than GFRP textile reinforced one. GFRP sheet was inserted into each layer of laminate, and it showed good condition in rotation-angle and strength, therefore it is the most appropriate to reinforce the part of the beam.

• Journal of the Institute of Electronics and Information Engineers
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• v.52 no.4
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• pp.156-163
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• 2015

In this paper, we propose an active water level and distance measurement algorithm using a light beam pattern. On behalf of conventional water level gauge types of pressure, float-well, ultrasonic, radar, and others, recently, extensive research for video analysis based water level measurement methods is gradually increasing as an importance of accurate measurement, monitoring convenience, and much more has been emphasized. By turning a reference light beam pattern on bridge or embankment actively, we suggest a new approach that analyzes and processes the projected light beam pattern image obtained from camera device, measures automatically water level and distance between a camera and a bridge or a levee. As contrasted with conventional methods that passively have to analyze captured video information for recognition of a watermark attached on a bridge or specific marker, we actively use the reference light beam pattern suited to the installed bridge environment. So, our method offers a robust water level measurement. The reasons are as follows. At first, our algorithm is effective against unfavorable visual field, pollution or damage of watermark, and so on, and in the next, this is possible to monitor in real-time the portable-based local situation by day and night. Furthermore, our method is not need additional floodlight. Tests are simulated under indoor environment conditions from distance measurement over 0.4-1.4m and height measurement over 13.5-32.5cm.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.32 no.5
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• pp.287-296
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• 2019

In this study, the effect of ground boundary conditions on the evaluation of blast resistance performance of precast arch structures was evaluated by a numerical analysis method. Two types of boundary conditions, namely, fixed boundary conditions and a perfectly matched layer (PML) were applied to numerical models. Blast loads that were much higher than the design load of the target structure were applied to compare the effects of the boundary conditions. The distribution and path of the ground explosion pressure, structural displacement, fracture of concrete, stress of concrete, and reinforcing bars were compared according to the ground boundary condition settings. As a result, the reflecting pressure shock wave at the ground boundaries could be effectively eliminated using PML elements; furthermore, the displacement of the foundation was reduced. However, no distinct difference could be observed in the overall structural behavior including the fracture and stress of the concrete and rebar. Therefore, when blast simulations are performed in the design of protective structures, it is rational to apply the fixed boundary condition on the ground boundaries as conservative design results can be achieved with relatively short computation times.

• Korean Chemical Engineering Research
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• v.59 no.3
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• pp.417-428
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• 2021

The combustion characteristics of anthracite, which follow a complex process with low reactivity, must be considered through the dynamic behavior of circulating fluidized bed (CFB) boilers. In this study, computational fluid dynamics (CFD) simulation was performed to analyze the combustion characteristics of anthracite in a pilot scale 0.1 MW_th Oxy-fuel circulating fluidized bed (Oxy-CFB) boiler. The 0.1MW_th Oxy-CFB boiler is composed of combustor (0.15 m l.D., 10 m High), cyclone, return leg, and so on. To perform CFD analysis, a 3D simulation model reactor was designed and used. The anthracite used in the experiment has an average particle size of 1,070 ㎛ and a density of 2,326 kg/m³. The flow pattern of gas-solids inside the reactor according to the change of combustion environment from air combustion to oxygen combustion was investigated. At this time, it was found that the temperature distribution in air combustion and oxygen combustion showed a similar pattern, but the pressure distribution was lower in oxygen combustion. addition, since it has a higher CO₂ concentration in oxygen combustion than in air combustion, it can be expected that carbon dioxide capture will take place actively. As a result, it was confirmed that this study can contribute to the optimized design and operation of a circulating fluidized bed reactor using anthracite.

• Korean Chemical Engineering Research
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• v.57 no.1
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• pp.51-57
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• 2019

A plant layout problem has a large impact on the overall construction cost of a plant. When determining a plant layout, various constraints associating with safety, environment, sufficient maintenance area, passages for workers, etc have to be considered together. In general plant layout problems, the main goal is to minimize the length of piping connecting equipments as satisfying various constraints. Since the process may suffer from the heat and friction loss, the piping length between equipments should be shorter. This problem can be represented by the mathematical formulation and the optimal solutions can be investigated by an optimization solver. General researches have overlooked many constraints such as maintenance spaces and safety distances between equipments. And, previous researches have tested benchmark processes. What the lack of general researches is that there is no realistic comparison. In this study, the plant layout of a real industrial C3MR (Propane precooling Mixed Refrigerant) process is studied. A MILP (Mixed Integer Linear Programming) including various constraints is developed. To avoid the violation of constraints, penalty functions are introduced. However, conventional optimization solvers handling the derivatives of an objective functions can not solve this problem due to the complexities of equations. Therefore, the PSO (Particle Swarm Optimization), which investigate an optimal solutions without differential equations, is selected to solve this problem. The results show that a proposed method contributes to saving the capital expenditures.