• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.3
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• pp.229-235
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• 2011

This research aims todevelopa compression/absorption hybrid heat pump system using an $NH_3/H_2O$ as working fluid.The heatpump cycle is based on a combination of compression and absorption cycles. The cycle consists of two-stage compressors, absorbers, a desorber, a desuperheater, solution heat exchangers, a solution pump, a rectifier, and a liquid/vapor separator. The compression/absorption hybrid heat pump was designed to produce hot water above $90^{\circ}C$ using high-temperature glide during a two-phase heat transfer. Distinct characteristics of the nonlinear temperature profile should be considered to maximize the performance of the absorber. In this study, the performance of the absorber was investigated depending on the capacity, shape, and arrangementof the plate heat exchangers with regard tothe concentration and distribution at the inlet of the absorber.

• Proceedings of the KSME Conference
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• 2001.06d
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• pp.304-310
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• 2001

A numerical model which simulates the heat and mass transfer processes within a counter-current plate type generator for ammonia/water absorption refrigerators was developed. Ammonia/water solution flows downward under gravity and ammonia/water vapor generated by flow boiling flows upward. The flow pattern within the generator was assumed to be a bubbly flow, and the liquid and vapor phase were assumed to be saturated. It was shown that the boiling of ammonia occurred mainly in the upper part of the generator. The effects of the generator length, the wall temperature and the mass flow rate of ammonia/water solution into the generator on the generation of ammonia/water vapor were investigated.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.13 no.10
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• pp.1034-1041
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• 2001

A numerical model which simulates the flow boiling process of the ammonia/water solution within a plate type generator for ammonia/water absorption refrigerators was developed. The ammonia/water solution flows downward under gravity and the ammonia/water vapor generated by flow boiling flows upward. The heating medium flows counter to the ammonia/water solution. The flow pattern within the generator was assumed to be a bubbly flow, and the liquid and vapor phases were assumed to be saturated. It was shown that the boiling of ammonia occurred mainly in the upper part of the generator. The effects of the heating medium inlet temperature, the mass flow rate of the heating medium and the mass flow rate of ammonia/water solution into the generator on the generation of ammonia/water vapor were investigated.

• Proceedings of the SAREK Conference
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• 2005.06a
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• pp.188-188
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• 2005

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.16 no.1
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• pp.16-25
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• 2004

The flow and heat/mass transfer in the falling-film of a heat exchanger can be influenced by the motion of the surrounding refrigerant vapor. In this study, the effect of the vapor flow direction on the absorption heat transfer has been investigated for a falling-film helical coil which is frequently used as the absorber of ammonia/water absorption refrigerators. The experiments were carried out for different solution concentration. The heat and mass transfer performance was measured for both parallel and counter-current flow. The effect of vapor flow on the heat and mass transfer is found to be increased with decreasing solution concentration. In the experiments with low solution concentration, whose vapor specific volume is great, the counter-current flow of vapor resulted in uneven distribution of falling-film and reduced the heat transfer performance of the absorber. The direction of the vapor flow hardly affected the thermal performance as the solution concentration became stronger since the specific volume of the ammonia/water vapor was much smaller than that of the water vapor.

• Korean Chemical Engineering Research
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• v.47 no.2
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• pp.185-189
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• 2009

Absorption rate of carbon dioxide into aqueous ammonia absorbent(10 wt%) was measured in the temperature range from 293 K to 337 K using a stirred-cell reactor. The reaction rate constant was correlated with the Arrehnius equation and the activation energy was 50.42 kJ/mol. $CO_2$ absorption rate into modified ammonia absorbent was also investigated. For the modified ammonia absorbent, 1 wt% sterically hindered amines of 2-amino-2-methyl-1-propanol(AMP), 2-amino-2-methyl-1,3-propandiol(AMPD) and 2-amino-2-ethyl-1,3-propandiol(AEPD) were used as additives. The $CO_2$ absorption rate increased by adding 1 wt% of the amine additive, in the case of AMP additive, the absorption rate enhanced by about 53%.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2003.11a
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• pp.271-276
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• 2003

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.13 no.7
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• pp.557-563
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• 2001

Small capacity gas absorption systems for cooling and heating have been favorably considered to reduce the seasonal imbalance of electrical loads and LNG consumption recently. A multifunctional plate-fin heat exchanger was adopted as an absorber and the performance was tested and analyzed to reduce the size and weight of the absorption heat pump. The test was performed using breadboard type ammonia absorption machine. The performance was compared with the plate type absorber and there was little difference in heat and mass transfer characteristics. The heat and mass transfer performance was a function of poor solution and vapor flow rates and the mass transfer was dependent on vapor flow rate more than heat transfer.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.28 no.4
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• pp.391-418
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• 1983

Urea and ammonium sulfate without and with sulfur group, respectively, were compared with respect to their nutritive effects on the rice plants, Suweon 264 and Jinheung, under the nursery trial on the protected upland and lowland seedbed, the pot trials with their various combination ratios and with added sodium sulfate to urea and the trials on the paddy fields which have undergone urea and ammonium sulfate application for many years. The rice seedlings fertilized with ammonium sulfate surpassed those with urea in growth performance and nutrients absorption of the rice seedlings at nursery period. Such stimulating effect of ammonium sulfate on the growth and nutrients uptake was more remarkable under the upland nursery than under the lowland one. The pot trial with the various combination ratios of urea and ammonium sulfate revealed that the chlorophyll content in leaf blade increased with the increment of sulfate ratio in the combination and the sole application of urea caused the chlorosis of leaf which was more conspicuous in Suweon 264 than in Jinheung. Fertilized with the same active ingradient amount of nitrogen, the rice plants supplied with ammonium sulfate surpassed those with urea in the chlorophyll content consistently under the nursery, the pot and the paddy field trials. The photosynthesis of flag leaf at heading stage increased with the combination rate of ammonium sulfate in the pot trial. The sulfur applicated as supplementary element of nitrogen in the nursery, the pot and the field trials were observed to be in positive relationship to the nitrogen and potassium content, but to be in negative correlation to the calcium content. The sulfur content in the rice plants was higher at early growth stage and decreased with the advance in growth stage. The nitrogen content also showed a similiar tendency to the sulfur content, and the N/S ratio was higher at early growth stage than at later one. The N/S ratio was negatively correlated with the chlorophyll content. In the field experiment, ammonium sulfate surpassed urea in the number of productive tiller, dry matter production and unhulled rice yields, but much stimulating effect of ammonium sulfate on the grain production was shown to be less effective than that on the straw production. The nitrogen and major nutrients content in the rice straw at harvest were higher in the paddy field with long-term ammonium sulfate application than in that with long-term urea application, suggesting that the former might have greater potentiality in nutrients supply than the latter.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.1
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• pp.102-111
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• 2000

A numerical model which simulates the simultaneous heat and mass transfer within a vertical tube GAX absorber was developed. The ammonia vapor and the solution liquid are in counter-current flow, and the hydronic fluid flows counter to the solution liquid. The film thickness and the velocity distribution of the liquid film were obtained by matching the shear stress at the liquid-vapor interface. Two-dimensional diffusion and energy equations were solved in the liquid film to give the temperature and concentration, and a modified Colburn-Drew analysis was used for the vapor phase to determine the heat and mass fluxes at the liquid-vapor interface. The model was applied to a GAX absorber to investigate the absorption rates, temperature and concentration profiles, and mass flow rates of liquid and vapor phases. It was shown that the mass flux of water was negligible compared with that of ammonia except the region near the liquid inlet. Ammonia absorption rate increases rapidly near the liquid inlet and decrease slowly. Both the absorption rate of ammonia vapor and the desorption rate of water near the liquid inlet increase as the vapor mass flow rate increases, but the mass fluxes of the ammonia and the water near the liquid outlet decrease as the mass flow rate of the vapor increases.