• Title/Summary/Keyword: 알칼리-실리카 반응

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Physical Characteristics of Cement Mortar Prepared Using Waste Glass and Graphene Oxide (폐유리와 산화 그래핀을 사용한 시멘트 모르타르의 물성 연구)

  • Kim, Kyoungseok;Chu, Yongsik
    • Resources Recycling
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    • v.28 no.6
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    • pp.54-63
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    • 2019
  • This study investigated on the compressive strength and the length change test with using the waste glass and graphene oxide for recycling the waste glass as the aggregate. Curing on 3-day and 7-day, the compressive strength was enhanced as the usage of waste glass was increased. Especially, the huge difference in the compressive strength was observed when the amount of substituting on the waste glass was used on 10~50%. With 50% of waste glass condition, the compressive strength was portionally enhanced as the usage of graphene oxide was increased and its value was 42.6 N/㎟ with 0.2% of graphene oxide. In terms of the length change test, the use of high content of waste glass led length change value to increase, but it was dropped down as the portion of waste glass was above 50%. Furthermore, in the case of using 50% of waste glass, the use of high amount of graphene oxide tended to decrease the length change value. That is, graphene oxide may contribute on boosting the cement hydration reaction and blocking the ion's movement.

Comparison of Alkali-Silica Reactivity for Mortar Bar and Concrete Prism Specimens Using Crushed Aggregates in Korea (국내 쇄석골재를 사용한 모르타르 봉 및 콘크리트 각주 시험편의 알칼리-실리카 반응성 비교)

  • Kim, Seong-Kwon;Yun, Kyong-Ku;Hur, In
    • International Journal of Highway Engineering
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    • v.14 no.5
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    • pp.93-99
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    • 2012
  • PURPOSES: The purpose of this study is to compare the alkali-silica reactivity for mortar bar and concrete prism specimens using crushed aggregates of 5 types in Korea. And the alkali-silica reactivity for those aggregates are measured by chemical test method. METHODS: The alkali-silica reactivity for those aggregates was measured by chemical test method of KS F 2545, mortar-bar test of KS F 2546, accelerated mortar-bar test method of ASTM C 1260 and concrete prism test method of ASTM C 1293, relatively. RESULTS: The alkali-silica reactivity for those aggregates was verified by chemical test of KS F 2546 and accelerated mortar-bar test of ASTM C 1260. However, it was not by mortar-bar test of KS F 2546 and concrete prism test of ASTM C 1293. CONCLUSIONS: The above results showed that relationship among the four test methods were very low. The results from 3 types of test methods using cement-aggregate combinations appeared to be different. Because the environmental conditions of test methods for measuring the alkali-silica reactivity such as equivalent alkali content(external source), humidity, temperature, and times were different though the aggregates were same. Moreover, alkali-silica reactivity showed the biggest impact when alkalis were supplied form outside and exposed to environmental conditions. The accelerated mortar-bar test method seems to be most appropriate test method for concrete structures exposed to alkali environment.

Properties of Self-hardened Inorganic Coating in the System Alumina-Silica-Calcium Oxide by the Reaction with Alkalies (알칼리 반응에 의한 알루미나-실리카-산화칼슘계 무기질 자기경화 코팅의 특성)

  • Jeon, Chang-Seob;Song, Tea-Woong
    • Journal of the Korean Ceramic Society
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    • v.47 no.5
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    • pp.381-386
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    • 2010
  • Some basic properties of inorganic coatings hardened by the room temperature reaction with alkalies were examined. The coating paste was prepared from the powders in the system $Al_2O_3-SiO_2$-CaO using blast furnace slag, fly ash and amorphous ceramic fiber after mixing with a solution of sodium hydroxide and water glass. The mineralogical and morphological examinations were performed for the coatings prepared at room temperature and after heating to $1200^{\circ}C$ respectively. The binding force of the coating hardened at room temperature was caused by the formation of fairly dense matrix mainly composed of oyelite-containing amorphous phase formed by the reaction between blast furnace slag and alkali solution. At the temperature, fly ash and ceramic fiber was not reacted but imbedded in the binding phase, giving the fluidity to the paste and reinforcing the coating respectively. During heating up to $1200^{\circ}C$, instead of a break in the coating, anorthite and gehlenite was crystallized out by the reaction among the binding phase and unreacted components in ternary system. The crystallization of these minerals revealed to be a reason that the coating maintains dense morphology after heating. The maintenance of binding force after heat treatment is seemed to be also caused by the formation of welldispersed fiber-like mineral phase which is originated from the shape of the amorphous ceramic fiber used as a raw materials.

Hydrochemical Characteristics of Natural Mineral Water in the Daebo and Bulguksa Granites (대보화강암과 불국사화강암지역 먹는샘물의 수리화학적 특성)

  • 조병욱;성익환;추창오;이병대;김통권
    • The Journal of Engineering Geology
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    • v.8 no.3
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    • pp.247-259
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    • 1998
  • Groundwater quality of the natural mineral water was investigated in hydrochemical aspects in order to ensure that mineral water meets stringent health standards. There exist 20 mineral water plants in the Daebo granite and 4 mineral water plants in the Bulguksa granite, respectively. Both granite areas show some differences in water chemistry. The pH, EC, hardness, total ionic contents in groundwater of the Daebo granite area are higher relative to those of the Bulguksa granite area. The content of major cations is in the order of Ca>Na>Mg>K, while that of major anions shows the order of $HCO_3>SO_4$>Cl>F. The fact that the $Ca-Na-HCO_3$ type is most predominant among water types may reflect that the dissolution of plagioclase that is most abundant in granitic rocks plays a most important role in groundwater chemistry. Representative correlation coefficients between chemical species are variable depending on geology. In the Daebo granite area, $Ca-HCO_3(0.84),{\;}Mg-HCO_3(0.81),{\;}SiO_2-Cl(0.74),{\;}Na-HCO_3(0.70)$ show relatively good correlationships. In the Bulguksa granite area, fairly good correlationships are found among some components such as K-Mg(0.93), $K-HCO_3(0.92)$, Mg-Cl(0.92), $Cl-HCO_3(0.91)$, and K-F(0.90). According to saturation index, most chemical species are undersaturated with respect to major minerals, except for some silica phases. Groundwater is slightly undersaturated with respect to calcite, whereas it is still greatly undersaturated with respect to dolomite, gypsum and fluorite. Based on the phase equilibrium it is clear that groundwater is mostly in equilibrium with kaolinite and becomes undersaturated with respect to feldspars, evolved from the stability area of gibbsite during water-rock interaction. While the activity of silica increases, there is no remarkable increase in the acivities of alkali ions and pH, which indicates that some amounts of silicic acid dissolved from silica phases as well as feldspars were provided to groundwater. It is concluded that chemical evolution of groundwater in granite aquifers may continue to proceed with increasing pH.

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Evaluation on Applicability of Copper and Steelmaking Slags for Use of Heavy Weight Aggregates in Marine Concrete Structure (동슬래그 및 제강슬래그의 해양 콘크리트용 중량 골재 사용성 평가)

  • Moon, Hoon;Jang, Bo-Kil;Kim, Ji-Hyun;Chung, Chul-Woo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.4
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    • pp.345-352
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    • 2017
  • Heavy weight concrete can be used in marine concrete structure to improve resistance against high wave energy. However, heavy weight aggregate, which is an indispensable material for heavy weight concrete, is difficult to be supplied in large quantities because its use is limited due to its high cost. In this work, the applicability of heavy weight by-products, copper and 3 month aged steelmaking slags, were evaluated as sources of heavy weight aggregate for marine concrete structures. Experimental results showed that copper slag was found to be a stable material for marine concrete structure. However, 3 month aged steelmaking slag showed significant expansion by $80^{\circ}$ water immersion test and ASTM C 1260 test. In addition, depth of chloride ion penetration in concrete was higher at which steelmaking slags were located. It was associated with porosity of steelmaking slag, and for this reason, steelmaking slag was not found to be suitable for marine concrete structure.

A Experimental Study on the Ready-mixed Shotcrete Using Granulated Blast Furnace Slag (고로슬래그 미분말을 혼입한 레디믹스트 숏크리트의 현장적용성에 관한 실험적 연구)

  • Choi, Hee-Sup;Kim, Dong-Min;Jang, Pil-Sung;Seo, Sin-Seuk
    • Journal of the Korean Geotechnical Society
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    • v.25 no.6
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    • pp.31-45
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    • 2009
  • The aim of this study is to evaluate the applicability of Granulated Blast Furnace Slag to the development of the Powdered Ready-mixed Shotcrete. First of all, after accomplishing SEM analysis and Leaching Test, the laboratory and field experiments for evaluating the utility of Granulated Blast Furnace Slag were performed. As a result of SEM and Leaching test, the environmental stability was confirmed. That is, non-detection of harmful lists and dense shotcrete structure result from mixing Granulated Blast Furnace Slag. As a result of lab. and field test, Blast Furnace Slag is superior to Plain Batch in improving strength and durability. And it will be able to improve to some extent the problem caused by the delayed reaction of existing Granulated Blast Furnace Slag with alkali activated material. Also the proper amount of Granulated Blast Furnace Slag is estimated to be under 30%. Finally, it is possible that Granulated Blast Furnace Slag can apply to economical recycling and development of the Ready-mixed Shotcrete for its price is only about 5% of Silica-finne's price.

Implicit Distinction of the Race Underlying the Perception of Faces by Event-Related fMRI (Event-related 기능적 MRI 영상을 통한 얼굴인식과정에서 수반되는 무의식적인 인종구별)

  • Kim Jeong-Seok;Kim Bum-Soo;Jeun Sin-Soo;Jung So-Lyung;Choe Bo-Young
    • Investigative Magnetic Resonance Imaging
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    • v.9 no.1
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    • pp.43-49
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    • 2005
  • A few studies have shown that the function of fusiform face area is selectively involved in the perception of faces including a race difference. We investigated the neural substrates of the face-selective region called fusiform face area in the ventral occipital-temporal cortex and same-race memory superiority in the fusiform face area by the event-related fMRI. In our fMRI study, subjects (Oriental-Korean) performed the implicit distinction of the race while they consciously made familiar-judgments, regardless of whether they considered a face as Oriental-Korean or European-American. For race distinction as an implicit task, the fusiform face areas (FFA) and the right parahippocampal gyrus had a greater response to the presentation of Oriental-Korean faces than for the European-American faces, but in the conscious race distinction between Oriental-Korean and European-American faces, there was no significant difference observed in the FFA. These results suggest that different activation in the fusiform regions and right parahippocampal gyrus resulting from superiority of same-race memory could have implicitly taken place by the physiological processes of face recognition.

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