• Title/Summary/Keyword: 알카리 활성 시멘트

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Strength Development and Hardening Mechanism of Alkali Activated Fly Ash Mortar (알카리 활성화에 의한 플라이애쉬 모르타르의 강도 발현 및 경화 메커니즘)

  • Jo, Byung-Wan;Park, Min-Seok;Park, Seung-Kook
    • Journal of the Korea Concrete Institute
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    • v.18 no.4 s.94
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    • pp.449-458
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    • 2006
  • The discharge of fly ash that is produced by coal-fired electric power plants is rapidly increasing in Korea. The utilization of fly ash in the raw materials would contribute to the elimination of an environmental problem and to the development of new high-performance materials. So it is needed to study the binder obtained by chemically activation of pozzolanic materials by means of a substitute for the cement. Fly ash consists of a glass phase. As it is produced from high temperature, it is a chemically stable material. Fly ash mostly consists of $SiO_2\;and\;Al_2O_3$, and it assumes the form of an oxide in the inside of fly ash. Because this reaction has not broken out by itself, it is need to supply it with additional $OH^-$ through alkali activators. Alkali activators were used for supplying it with additional $OH^-$. This paper concentrated on the strength development according to the kind of chemical activators, the curing temperature, the heat curing time. Also, according to scanning electron microscopy and X-Ray diffraction, the main reaction product in the alkali activated fly ash mortar is Zeolite of $Na_6-(AlO_2)_6-(SiO_2)_{10}-12H_2O$ type.

Quality Characteristics and Environmental Impact Assessment of Alkali-Activated Foamed Concrete (알카리활성 기포콘크리트의 품질특성 및 환경영향 평가)

  • Yang, Keun-Hyeok;Yoo, Sung-Won;Lee, Hyun-Ho;Kim, Sang-Chel
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.2
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    • pp.114-119
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    • 2013
  • The present study tested 5 concrete mixes to develop reliable mixing proportions for the sustainable alkali-activated(AA) foamed concrete as a thermal insulation material for the floor heating system of buildings. The AA binder used was composed of 73.5% ground granulated blast-furnace slag, 15% fly ash, 5% calcium hydroxide, and 6.5% sodium silicate. As a main variable, the unit binder content varied from $325kg/m^3$ to $425kg/m^3$ at a space of $25kg/m^3$. The test results revealed that AA foamed concrete has considerable potential for practical applications when the unit binder content is close to $375kg/m^3$, which achieves the minimum quality requirements specified in KS F 4039 and ensures economic efficiency. In addition, lifecycle assessment demonstrated the reduction in the environmental impact profiles of all specimens relative to typical ordinary portland cement foamed concrete as follows: 99% for photochemical oxidation potential, 87~89% for global warming potential, 78~82% for abiotic depletion, and 70~75% for both acidification potential and human toxicity.

Development of Application Block Using Geobond and Ash from Sewage Sludge Incinerator II (하수슬러지 소각재와 무기바인더를 이용한 응용 블록 개발 II)

  • Lee, Hyun-joo
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.7
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    • pp.412-417
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    • 2015
  • This study investigated to recycle geobond and ash produced in thesewage sludge incinerator using reduction/stabilization. Nonsintering process was performed by binding cement (High Early Strength Portland cement, Micro cement), geobond and sand mixed with sewage sludge ash (SSA). Chemical ingradients of the sewage sludge ash was mainly composed of $SiO_2$, $Al_2O_3$, $Fe_2O_3$, CaO and others, which were similar to those of the each binders consisting High Early Strength Portland cement, Micro cement and geobond. Results showed that unconfined the long term compressive strength could be obtained components of sewage sludge ash. It exceeded more than double score 64.6 MPa of the Korean standard ($22.54MPa=229.7kg/cm^2$). Microstructure of solidified block for the different admixture was related to the compressive strength according to SEM analysis. Optimum mixing range of the sewage sludge ash to each binders were found to be 10~40% which can widly safely regulate the confined a long term compressive strength. The best binder of long term compressive strengh was revealed Geobond more than High Early Strength Portland cement and Micro cement. This study revealed the sewage sludge ash can be partial replacement of the inorganic binder & application block for recycling.