• Title/Summary/Keyword: 알바이트

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Annealing Experiments of Albite Using Optical Microscope Heating Stage (광학현미경 가열실험대를 이용한 알바이트의 등온가열 실험 연구)

  • Park Byung-Kyu;Kim Yong-Jun;Kim Youn-Joong
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.4 s.46
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    • pp.289-299
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    • 2005
  • Annealing experiments on albite powders, thin sections, and TEM specimens have been performed utilizing an optical microscope heating stage. Sample orientations were determined by optical microscope and XRD, and then confirmed by TEM diffraction patterns. Partial melting of samples occurred at $1030^{\circ}C$-l2 hr for powder, but at $1060^{\circ}C$-12 hr for TEM specimen. It is difficult to get TEM images of albite microstructures above this temperature due to thickening and the amorphous phase of the melted part. Correlative studies between optical microscopy and TEM indicated that the $1050^{\circ}C$-12 hr annealing in ambient condition was most adequate to observe tweed microstructures in albite through TEM. In situ TEM heating experiments for direct observation of tweed microstructures in albite may require annealing at slightly higher temperatures than $1050^{\circ}C$ considering the high vacuum condition inside TEM.

Albitization of feldspar in the Cretaceous Kusandong Tuff, Korea (백악기 구산동응회암 내 장석의 알바이트화 작용)

  • Jeong, Jong-Ok;Sohn, Young-Kwan
    • The Journal of the Petrological Society of Korea
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    • v.14 no.4 s.42
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    • pp.195-211
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    • 2005
  • The Kusandong Tuff, known as a representative key bed in the Cretaceous Gyeongsang Basin, is a crystal-rich tuff of pyroclastic flow and surge origin. It is 1-4 m thick and laterally extends for more than 200 km intercalated in the upper part of the Hayang Croup. Observations and analyses of the feldspar crystals in the tuff, using polarizing microscopes, EPMA, and BSE images, reveal that the plagioclase crystals in the tuff were completely albitized (>$97\%$ Ab) whereas those in the southernmost localities where the tuff is rich in fine ash matrix are unaltered or partly albitized. K-feldspars are partly albitized at all localities, irrespective of the matrix content of the tuff, Perthitic textures, chessboard twinning, albitization along micro-fractures and cleavages, and the relationship between matrix content and the degree of albitization suggest that feldspars in the Kusandong Tuff were albitized by Na-rich fluid after burial. Albitization is interpreted to start preferentially along micro-fractures and cleavages and be hampered in matrix-rich tuffs with a low permeability. Original composition of the plagioclases in the Kusandong Tuff is also interpreted to have ranged between oligoclase and andesine ($Ab_{62.5}-Ab_{83.3}$) before the albitization.

XRD and TEM Investigations of Structures and Phase Transformations in Albite (XRD와 TEM을 이용한 알바이트의 구조 및 상전이 연구)

  • 김윤중;이영부
    • Journal of the Mineralogical Society of Korea
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    • v.16 no.1
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    • pp.91-106
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    • 2003
  • XRD results on annealing studies of Na-feldspars (Amelia albite) show rapid changes in the lattice parameters of the $1073^{\circ}C$-heated samples owing to disordering of Al and Si as well as lattice distortions upon quenching of the heated specimens. While a low albite transformed to a high albite by 7-days annealing at $1073^{\circ}C$, it remains as an early intermediate albite even by 140-days annealing at $924^{\circ}C$ due to the slower Al-Si disordering rate. From the heated samples tweed structures of $100∼200\AA$ were typically observed by TEM, which showed different ways of development between the $1073^{\circ}C$ -heated one and the $923 ^{\circ}C$ -heated one. The former locally trans-farmed to rnicrostructures similar to albite twin, while the latter transformed to domain structures containing albite twin plane in the wider area. The origin of tweed structures is suggested to be formation of incipient twins (albite twin and pericline twin) to reduce the lattice instability which is increased by disordering of Al and Si as well as quenching.

Application of CBED Techniques of Energy Filtering TEM for Si-Al Disordering Study of Albite (알바이트의 Si-Al 배열상태 연구를 위한 에너지여과 투과전자현미경의 CBED법 적용)

  • Lee Young Boo;Kim Youn Joong;Lee Joung Hoo
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.4
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    • pp.327-338
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    • 2004
  • XRD studies on annealed Na-feldspar (Amelia albite) at $1100^{\circ}C$ showed rapid structural changes due to Si-Al disordering, which resulted in phase transformations from low albite to high albite by 4-days annealing test. TEM SAED analyses on the annealed samples revealed a trend of structural changes, but estimation of the structural state was difficult due to a large deviation of the SAED data. Optimum conditions of CBED analyses on albite was established by employing a cooling specimen holder, 120 kV of acceleration voltage, 37 Jim of condenser aperture size and 25 nm of spot size. A proper orientation showing distinct changes of HOLZ lines corresponding to the structure changes of albite turned out to be close to the [418] direction with $-1.2^{\circ}$ tilting, where the width of two HOLZ lines in low albite was opposite to those in high albite.

Feldspar Diagenesis and Reseuoir History of the Miocene Temblor Formation, Kettleman North Dome, California, U.S.A. (미국 캘리포니아주 케틀만 노스돔의 마이오세 템블러층에서 장석의 속성작용과 저류암의 발달사)

  • Lee Yong Il;Boles James R.
    • The Korean Journal of Petroleum Geology
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    • v.3 no.1 s.4
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    • pp.16-27
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    • 1995
  • The Early Miocene Temblor Formation forms an important sandstone reservoir at Kettleman North Dome oil field, California. Sandstones are mostly arkosic in composition except deepest sandstones containing much volcanic rock fragments. Arranged in paragenetic sequence prior to feldspar alteration, the Temblor sandstones contain cements of early calcite, dolomite, quartz, albite, mixed-layer ohloriteismectite (C/S) and smectite, and anhydrite. Diagenetic changes associated with feldspar are albitization of plagioclase, late calcite and laumontite cementation and grain replacement, plagioclase dissolution, and kaolinite cementation. Plagioclase albitization and late calcite and laumontite cementation in Temblor sandstones occurred at the time of maximum burial with temperatures up to $130^{\circ}C$. Volcanic plagioclases were selectively albitized. Most diagenetic changes are interpreted to have occurred before the maior uplift which occurred within the last one million years ago. Since then to the time of hydrocarbon emplacement plagioclase dissolution and kaolinite cementation occurred. This reaction occurred in relatively closed system due to the occurrence of kaolinite next to the site of plagioclase dissolution. Unaltered part of volcanic plagioclase and plutonic plagioclase which escaped albitization during maximum burial were preferentially dissolved to make plagioclase porosity. Secondary porosity resulting from dissolution of plagioclase and carbonate and anhydrite cements was mainly produced by formation waters containing organic acids released during atagenesis of organic matter.

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Controls on Diagenetic Mineralogy of Sandstones and Mudrocks from the Lower Hayang Group (Cretaceous) in the Daegu Area, Korea (대구 부근 하부 하양층군(백악기) 사암과 이암의 속성 광물과 속성 작용의 규제 요인)

  • Shin, Young-Sik;Choo, Chang-Oh;Lee, Yoon-Jong;Lee, Yong-Tae;Koh, In-Seok
    • Journal of the Korean earth science society
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    • v.23 no.7
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    • pp.575-586
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    • 2002
  • Authigenic minerals found in sandstones and mudrocks of the Lower Hayang Group (Cretaceous) in the central part of the Kyungsang Basin are carbonate minerals (calcite, dolomite), clay minerals (illite, chlorite, C/S, I/S and kaolinite), albite, quartz and hematite. Characteristic diagenetic mineral assemblages are as follows: albite-chlorite (including C/S)-hematite in the Chilgog Formation, albite-illite-calcite in the Silla Conglomerate, illite-chlorite-hematite in the Haman Formation and albite-chlorite-dolomite in the Panyawol Formation, respectively. Among clay minerals reflecting the physical and chemical change of the diagenetic process, illite, the dominant clay mineral, occurs in every formation in the study area. Chlorite occurs mainly in green or gray sandstones and mudrocks, or in sandstones and mudrocks of the Chilogok Formation which contains a high content of volcanic materials. Based on the mineral assemblage, diagenetic minerals are strongly related with source rocks. Judging from the illite crystallinity, diagenesis of sandstones and mudrocks in the study area reached the late diagenetic stage or low grade metamorphisim. The diagenetic process was much influenced by intrusion of the Bulguksa granite, content of organic materials, grain size, and depositional environment rather than burial depth.

Occurrence of the Nb-Ta Ore Bodies in Pegmatites, Mujoo (무주 페그마타이트 내 Nb-Ta 광화대의 산출상태)

  • Kang, Min-Woo;Kim, Ji-Hyun;Choi, Jin-Beom
    • Journal of the Mineralogical Society of Korea
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    • v.24 no.2
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    • pp.133-143
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    • 2011
  • In Mujoo area, the granitic pegmatites are developed in the granitic gneiss complex with Jurassic gneissic granites, where Nb-Ta mineralization were reported. Pegmatites are mainly composed of large crystals of quartz, feldspars of end-member orthoclase and albite, and muscovite. Nb-Ta minerals in study area are columbite (Nb > Ta) in composition. Chemistry of muscovites shows post-magmatic in origin and they are closely related with columbite. Large columbite, in pegmatites occurred with quartz and feldspars, while microcrystalline columbite is associated with muscovite. The Nb contents in large columbite are relatively higher than those in microcrystalline ones. Two pegmatites, 4~15 m in width and 120 m, 250 m in extension respective1y, are developed. Five drilling cores with total 600 m in length are finally obtained and revealed no possible potential for economic rare metals of Na-Ta deposits.

A proposal on the framework of searching patterns for Hangul characters and Its relationship with Hangul code (한글 글자단위 검색 기능 구현에서의 검색 유형 정의 및 한글 부호계와의 연관성에 관한 연구)

  • Lee, Jung-Hwa;Kim, Kyong-Sok
    • Annual Conference on Human and Language Technology
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    • 1994.11a
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    • pp.282-287
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    • 1994
  • 본 논문에서는 글자 단위를 기본으로 하는 한글 검색 기능을 구현할 때 적용될 수 있는 검색유형 (search pattern) 들은 어떠한 것들이 존재할 수 있는지에 대해 먼저 살펴보고, 검색 알고리즘에 적용시켜 본다. 이 때 부호계와의 연관성과 효율성을 따져보기 위해서 두 바이트 상용조합형, 두 바이트 KS C 5601 완성형, n-바이트 (3 바이트) 부호계, 그리고 국제 표준 한글 부호계의 첫-가-끝 부호계 등 여러가지 부호계를 사용할 때를 서로 비교해 본다. 각 부호계를 사용할 때 알고리즘이 조금씩 바뀌게된다. 그 변형을 살펴보면 그 효율을 측정할 수 있는데, 한글 글자단위 검색 등의 유형의 작업에서는 조합방식의 부호계를 사용하면 더욱 편리하다는 것을 알 수 있다. 이는 단순히 한글 글자단위 검색 기능에서 유리하다고 하기보다는 한글의 특성을 더 잘 반영하고 있다고 할 수 있는 것이다. 또한 조합방식의 부호체계 중에서도 별도의 연산값이 소리마디에서 글자를 분리해 낼 수 있는 부호계 (3-바이트 부호계, 첫-가-끝 부호계) 의 경우는 글자를 기본 단위로 처리하고자 하는 응용 분야에서 더욱 편리하게 사용될 수 있다.

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A Minerlogical Study of Plagioclase in Volcanic Rocks from the Mt. Mudeung Area (무등산지역 화산암류에서 산출되는 사장석의 광물학적 연구)

  • Park Byung-Kyu;Kim Yong-Jun;Kim Youn-Joong
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.3 s.45
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    • pp.155-164
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    • 2005
  • Volcanic rocks from the Mt. Mudeung area which are composed of Hwasun andesite, Mudeungsan dacite and Togok rhyolite contain plagioclase phenocrysts in common. Majority of the repeated twins observed in optical microscopy are albite twin and some are pericline twin. EPMA studies of plagioclases from Hwansun andesite, Mudeungsan dacite and Togok rhyolte indicate calcic andesine, andesine-oligoclase, nearly pure albite, respectively Albite twin and pericline twin can be easily distinguished through TEM diffraction patterns, which is quite difficult by optical microscopy. Plagioclases in volcanic rocks from the Mt. Mudeung area do not show e-reflection in (100) electron diffraction patterns, probably because of their high cooling rate, which inhibited phase separations during cooling.

Geochemical Modeling on Water-caprock-gas Interactions within a CO2 Injected in the Yeongil Group, Pohang Basin, Korea (포항분지 영일층군 내 이산화탄소 주입에 의한 물-덮개암-가스 반응에 대한 지화학적 모델링)

  • Kim, Seon-ok;Wang, Sookyun;Lee, Minhee
    • Economic and Environmental Geology
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    • v.54 no.1
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    • pp.69-76
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    • 2021
  • This study is to identify the mineralogical properties of caprock samples from drilling cores of the Pohang basin, which is the research area for the demonstration-scale CO2 storage project in Korea. The interaction of water-rock-gas that can occur due to CO2 injection was identified using geochemical modeling. Results of mineralogical studies, together with petrographic data of caprock and data on the physicochemical parameters of pore water were used for geochemical modeling. Modelling was carried out using the The Geochemist's Workbench 14.0.1 geochemical simulator. Two steps of modeling enabled prediction of immediate changes in the caprocks impacted by the first stage of CO2 injection and the assessment of long-term effects of sequestration. Results of minerlaogical analysis showed that the caprock samples are mainly composed of quartz, K-feldspar, plagioclase and a small amount of pyrite, calcite, kaolinite and montmollonite. After the injection of carbon dioxide, the porosity of the caprock increased due to the dissolution of calcite, and dawsonite and chalcedony were precipitated as a result of the dissolution of albite and k-feldspar. In the second step after the injection was completed, the precipitation of dawsonite and chalcedony occurred as a result of dissolution of calcite and albite, and the pH was increased due to this reaction. Results of these studies are expected to be used as data to quantitatively evaluate the efficiency of mineral trapping capture in long-term storage of carbon dioxide.