• Title/Summary/Keyword: 알만딘

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Gemological Studies on Garnet from Madagascar, Africa (아프리카 마다가스카르산 석류석에 대한 보석광물학적 연구)

  • Kim, Su-Hyun;Jang, Yun-Deuk;Kim, Jong-Rang;Kim, Jeong-Jin;Kim, Jong-Gun
    • Journal of the Mineralogical Society of Korea
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    • v.21 no.1
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    • pp.17-26
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    • 2008
  • The Madagascar garnets wear mainly found as a porphyroblast in gneiss and classified into rhodolite, purple almandine, and brown almandine based on compositional characteristics and color. UV-visible analysis strong absorption bands, 400, 428, 504, 521, and 572 nm, were observed for rhodolite and purple almandine, and main absorption bands of 433 and 502 nm observed for brown almandine. For FT-IR analysis a strong absorption band of $640\;cm^{-1}$ was observed for rhodolite, two strong bands of 628 and $651\;cm^{-1}$ observed for brown almandine, and two weak absorption bands of 635 and $653\;cm^{-1}$ observed for purple almandine. Single distinct absorption band, $3552\;cm^{-1}$, was observed only for rhodolite. It is possible to distinguish rhodolite from purple or brown almandine by considering overall characteristics of the rhodolite such as color, RI, UV-visible absorption, FTIR absorption etc.

Gemological and Minearlogical Properties of the Red Garnet Stones (적색 석류석 보석의 보석.광물학적 특징)

  • 김금조;김진섭;김원사;최진범
    • Journal of the Mineralogical Society of Korea
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    • v.16 no.1
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    • pp.19-31
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    • 2003
  • Chemical composition, crystal structure, refractive index, specific gravity, color, and luster were studied fur pyrope-almandine series garnets. The main coloring agents determining the reddish or brownish garnets were also investigated. It was also examined if there is any relationship between mineralogical properties with respect to the various chemical compositions in the solid solution, in the hope to figure out the existing classification values of R.I. and S.G. using gem- testing facilities to distinguish pyrope from almadine. It was found that 17 out of the 24 specimens belong to pyrope and the rest almandine. R.I. of pyrope goes up to 1.77 and that of almandine is higher than the value.5.5. of pyrope reaches to 3.88 and that of almandine is greater than the value of pyrope. X-ray diffraction data revealed that pyrope-almandine garnets are isometric with space group Ia3d, and also show that the variation of cell parameters are not significant enough to parallel with the chemical compositions of the series. R.I. and S.G. increase with FeO content. Fe and Mn are most responsible to the red-purple and orange coloration of the specimens, respectively. Both zircon and rutile crystals are most common inclusions in the reddish stones.

A Study of Compressibility on a Natural Almandine Using Synchrotron Radiation (방사광을 이용한 천연산 알만딘의 압축성 연구)

  • Hwang Gil Chan;Kim Young-Ho
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.4 s.46
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    • pp.249-257
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    • 2005
  • Garnet is one of the major minerals down to the top of lower mantle approximately 660 km with spinel and pyroxenes. Garnet transforms into perovskite and corundum in the lower mantle, however its sequence is still in controversy. We measured the compressibility of a natural almandine at high-pressure up to 62 CPa using Mao-Bell type diamond anvil cell (DAC) at room temperature. Chemical formula of the specimen is ($Fe_{2.52}Ca_{0.21}Mg_{0.18}Mn_{0.12})Al_{2.23}Si_{2.97}O_{12}$. Results of this compression study are as follows: a : $10.175\;{\AA}$, V : $1251.16\;{\AA}^{3}$, $D_{x}$ : $5.265\;g/cm^{3}$ at 62 GPa; bulk modulus is 156 GPa using Birch-Murnaghan equation of state (EoS) with a fixed $K_{0}\;'$ of 4. This study would be the first time attempt accomplished with the high pressure DAC using synchrotron radiation at the Pohang Light Source (PLS) in Korea.

Granulite xenoliths in porphyroblastic gneiss from Mt. Jiri area, SW Sobaegsan massif, Korea (소백산육괴 서남부 지리산지역의 반상변정질 편마암에서 산출되는 백립암질 포획암)

    • The Journal of the Petrological Society of Korea
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    • v.8 no.1
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    • pp.34-45
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    • 1999
  • Mafic granulite xenoliths are found in precambrian porphyroblastic gneiss of the Mt. Jiri area, SW Sobaegsan massif, Korea. The xenoliths are rounded to ellipsoidal in shape, 50-100 cm in length and coarse-grained with granoblastic and foliated texture. The xenoliths consist of orthopyroxene, garnet, biotite, plagioclase, quartz, ilmenite and secondary orthoamphibole. Orthopyroxene is mostly resorbed and rimmed by coronitic orthoamphiboles. Garnets occur as porphyblasts and are zoned with higher pyrope content in cores than in rims. Geothermo-barometry results yield conditions of about $800-850^{\circ}C$, 6 kb and $500^{\circ}C$, 4 kb for early and retrograde stages of equilibration, respectively. According to available geochronological data, it is suggested that the granulite facies metamorphism occurred prior to 2.1-1.9Ga and that the area was superimposed by the high-grade (over $600-700^{\circ}C$) metamorphism between 1.9-1.7Ga, followed by cooling during uplift.

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Petrological and geochemical study of the Precambrian granitic gneiss in the Danyang- Yecheon area (단양-예천사이에 분포하는 선캠브리아 화강암질 편마암류의 암석학적 및 지구화학적 연구)

  • Yun Hyon Soo
    • The Journal of the Petrological Society of Korea
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    • v.1 no.1
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    • pp.34-41
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    • 1992
  • The Precambrian granitic gneisses are widely distributed in the Danyang-Yecheon area, eastern part of Korea, where the Ryeongnam massif borders the Ogcheon fold belt. They are composed of migmatitic, biotite granitic, garnet-bearing and granoblastic granitic gneisses. The common joint sets of the granitic gneiss are NE and NS directions, which are probably related to the effects of Daebo orogeny and Bulgugsa disturbance, respectively. Mineral assemblages of the banded gneiss xenolith in the garnet-bearing granitic gneiss are quartz-plagioc1ase-biotite-mus-covite-orthoclase and quartz-plagioc1ase-biotite-garnet, belonging to the amphibolite facies. The granoblastic granitic gneiss is felsic, metaluminous, and granitic, and shows subalkaline trend. The garnet-biotite geothermometry of garnet-bearing granitic gneiss yields 640$^{\circ}$-708$^{\circ}C$ at pressure of 4 kb.

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Preliminary Study of Heavy Minerals in the Central Yellow Sea Mud (황해중앙이질대 퇴적물에 대한 중광물 예비 연구)

  • Lee, Bu Yeong;Cho, Hyen Goo;Kim, Soon-Oh;Yi, Hi Il
    • Journal of the Mineralogical Society of Korea
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    • v.29 no.1
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    • pp.1-10
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    • 2016
  • We studied the heavy minerals in 46 surface sediments collected from the Central Yellow Sea Mud (CYSM) to characterize the type, abundance, mineralogical properties and distribution pattern using the stereo-microscopy, field-Emission scanning electron microscopy (FE SEM) and chemical analysis through the energy dispersive spectrometer (EDS). Heavy mineral assemblages are primarily composed of epidote group, amphibole group, garnet group, zircon, rutile and sphene in descending order. Epidote group and amphibole group minerals account for more than 50% of total heavy minerals. The minerals in epidote group, amphibole group and garnet group in studied area are epidote, edenite and almandine, respectively. When we divided the CYSM into two regions by $124^{\circ}E$, the eastern region contain higher contents of epidote and (zircon + rutile), which are more resistant to weathering but lower of amphibole, which is less resistant to weathering than the western region. Based on this results, it is possible to estimate that the eastern region sediments are transported for a long distance while western region sediments are transported for a short distance from the source area. In the future, the additional study on the heavy minerals in river sediments flowing into the Yellow Sea and much more samples for marine sediments must be carried out to interpret exactly the provenance and sedimentation process.

Geochemistry and Metamorphism of the Gneisses in Gwangyang-Hadong Area (광양-하동지역에 분포하는 편마암류의 지구화학 및 변성작용)

  • Park, Bae-Young;Suh, Gu-Won
    • Journal of the Korean earth science society
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    • v.29 no.3
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    • pp.221-245
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    • 2008
  • The precambrian granitic gneiss and porphyroblastic gneiss are widely distributed in the Gwangyang-Hadong area of Korea. This study focuses on the geochemical properties and metamorphic P-T conditions of these gneisses. These gneisses are plotted according to granodiorite domain on an IUGS silica-alkali diagram. Geochemical properties of major elements suggest that these rocks are of the sub-alkalic rock series, and were farmed from S-type magmas which were generated in a syn-collision tectonic environment. The amounts of trace elements (Zn, Sc, Sr, V, etc.) decreased as $SiO_2$ concentrations increased. Almandine and spessartine mol%'s and XFe are higher in garnet rims, while pyrope mol%'s are higher in the garnet cores. This seems to be the result of garnet growth and retrogressive metamorphism. Metamorphic zones are divided into sillimanite-cordierite, sillimanite, garnet, and biotite zones. Metamorphic P-T conditions estimated from the gneisses indicate high temperature and low to medium pressure metamorphism (689-757$^{\circ}C$, 5.0-5.6 kbar), followed by medium temperature, low pressure retrorade metamorphism (579-628$^{\circ}C$, 3.1-4.5 kbar), and overprinted retrogade metamorphism (502-558$^{\circ}C$, 1.6-2.3 kbar).

Petrology of the Blastoporphyritic Granite Gneiss in the Southwestern Part of the Sobaegsan Massif (소백산육괴 서남부의 잔류반상 화강편마암의 암석학적 연구)

  • Lee, Choon-Hee;Lee, Sang-Won;Ock, Soo-Seck;Song, Young-Sun
    • Journal of the Korean earth science society
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    • v.22 no.6
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    • pp.528-547
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    • 2001
  • The blastoporphyritic granite gneiss (BPGN) including much alkali-feldspar megacrysts occurs in Jiri mountains area, southwestern part of Sobaegsan massif, Korea. The BPGN is formed gneiss complexes with other gneisses in Precambrian. The BPGN was named as porphyroblastic gneiss with porphyroblasts of alkali-feldspar megacrysts by other researchers, but the BPGN includes of euhedral alkali-feldspars (microcline), and the boundary with the granitic gneiss represents sharp contact as intrusive relationship. The BPGN mainly composes of alkali-feldspar megacrysts, quartz, plagioclase, K-feldspar and biotite some almandine and accessary minerals are muscovite, chlorite, apatite, zircon and opaques. The alkali-feldspar is microcline with perthitic texture. An content of plagioclases show 30 to 40. Biotites occur two type, one is Brown biotite which shows compositional ranges of Mg/Fe+Mg ratios from 0.38 to 0.52, the other is Green Bt. which is retrograde product. Camels to be various sizes and shapes have composition of almandine with 73 to 80 mole percent, but represent retrogressive zoning from core (X$_{pyr}$: 15.9${\sim}$20.8) to rim (X$_{pyr}$:13.7${\sim}$15.9) to be evidence of retrograde metamorphism. Megacrysts of alkali-feldspar in the BPGN show rectangular shape of euhedral and some become ellipsoidal or spheroidal in shape and the average size up to 20 cm long. The megacryst includes of biotite, plagioclase and quartz, and rarely euhedral apatite as inclusions. In petrochemistry the BPGN represents granodiorite composition, characteristics of peraluminous S-type granitoid and calc-alkaline features.

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Metamorphic Evolution of the central Ogcheon Metamorphic Belt in the Cheongju-Miwon area, Korea (청주-미원지역 중부 옥천변성대의 변성진화과정)

  • 오창환;권용완;김성원
    • The Journal of the Petrological Society of Korea
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    • v.8 no.2
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    • pp.106-124
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    • 1999
  • In the Cheongju-Minwon area which occupies the middle part of the Ogcheon Metamorphic Belt, three metamorphic events(M1, M2, M3) had occurred. Intermediate P/T type M2 regional metamorphism formed prevailing mineral assemblages in the study area. Low PIT type M3 contact metamorphism occurred due to the intrusion of granites after M2 metamorphism. M1 metamorphism is recognized by inclusions within garnet. During M2 metamorphism, the metamorphic grade increased from the biotite zone in the southeastern part to the garnet zone in the northwestern part of the study area. This result is similar to the metamorphic evolution of the southwestern part of the Ogcheon Metamorphic Belt. Garnets in the garnet zone are classified into two types; Type A garnet has inclusions whose trail is connected to the foliation in the matrix and Type B garnet has inclusion rich core and inclusion poor rim. Type A garnet formed in the mica rich part with crenulation cleavage whereas Type B garnet formed in the quartz rich part with weak crenulation cleavage. In some outcrops, two types garnets are found together. Compared to the rim of Type A garnet, the rim of Type B garnet is lower in grossular and spessartine contents but higher in almandine and pyrope contents. In some Type B garnets, the inclusion poor part is rimmed by muddy colored or protuberant new overgrowth. In the inclusion poor part and new overgrowth, a rapid increase in grossular and decrease in spessartine is observed. However, the compositional patterns of Type A and B are similar; Ca increases and Mn decreases from core to rim. Two types garnets formed mainly due to the difference of bulk chemistry instead of metamorphic and deformational differences. The metamorphic P-T conditions estimated from Type A garnets are 595-690 OC15.7-8.8 kb, which indicates M2 metamorphism is intermediate P/T type metamorphism. On the other hand, a wide range of P-T conditions is calculated from Type B garnets. The P-T conditions from most Type B garnet rims are 617-690 OC16.2-8.9 kb which also indicates an intermediate P/T type metamorphism. However, at the rim part with flat end or weak overgrowth, grossular content is low and 573-624OC14.7-5.8 kb are estimated. The P-T conditions calculated from plagioclase and biotite inclusions in garnet are 460-500 0C/1.9-3.0 kb. The P-T conditions from rim part with weak overgrowth and inclusions within garnet, indicate that low P/T type M1 regional metamorphism might have occurred before intermediate P/T type M2 regional metamorphism. The P-T conditions estimated from samples which had undergone low PIT type M3 metamorphism strongly, are 547-610 0C/2.1-5.0 kb.

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