• Journal of the Korean Chemical Society
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• v.28 no.2
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• pp.79-85
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• 1984

The ionic association constant(K) of 2,4,6, N-tetramethyl pyridinium iodide (TeMPI) in 95 volume percentage ethanol-water mixture were determined by a modified UV and conductance method at $25^{\circ}C$ to $50^{\circ}C$ under 1 to 2,000 bars. The K values increase with increasing pressure and have maximum value at $40^{\circ}C$. The partial molar volume hange (${\Delta}V$) has relatively small negative value and the absolute values of ${\Delta}$ are minimum at $40^{\circ}C$. The ion size parameter(a) of TeMPI have maximum value at $40^{\circ}C$. {\Delta}H^{\circ}$ values are zero, positive and negative at 40^{\circ}C$, $25^{\circ}C$ and $50^{\circ}C$ respectively. Other thermodynamic parameters such as the changes of standard entropy ({\Delta}S^{\circ}$) and free energy {\Delta}G^{\circ}$ were evaluated. From these experimental results, we came to conclusion that TeMPI is stabilized by the elevation of pressure and that of temperature below $40^{\circ}C$ but weakly dimerized at $40^{\circ}C$ because of the intermolecular hydrophobic interaction of eight methyl groups of two molecules. And it thermally decomposed above $50^{\circ}C$.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.4
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• pp.661-669
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• 2000

This research was carried out to evaluate effect of metallic release and change of water corrosive indices by the pH and alkalinity adjustment using the SDLS (Simulated Distribution Loop System) which consist of six types of pipe loop with DCIP, PVC, PE, STS304, CP, GSP, respectively, and its effects on water quality changes which were microbes quality(SPC), residual chlorine. THMs and other parameters. And it was to propose optimal criteria of water quality control for the field application. According to the results, water control system by pH and alkalinity adjustment showed the changing of corrosive water and reducing of metallic release rate and it was not affects of THMs formation, microbes regrowth and variation of other parameters. Water quality stability and corrosion control were due to calcium carbonate precipitation film formation of pipe inner by water quality control. Therefore, corrosive water control system by pH and alkalinity adjustment can be attributed to effective water quality management in water distribution system according to water quality stability of pH and TIC(Total Inorganic Carbonate concentration) that affect the precipitation and dissolution of solids.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.299-299
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• 2008

초전도 응용기기 개발을 위해 필수적인 초전도 박막선재는 길이방향으로 임계전류밀도가 균일한 것이 요구되고 있다. 전체 길이에 대해 가장 임계전류 밀도가 낮은 지점에서 선재의 특성이 제한되기 때문이다. 한편 초전도 박막선재의 경우 높은 임계전류 밀도와 함께 과전류 등의 사고발생시를 고려하여 안정화재를 반드시 초전도층 위에 구성하여야 한다. 고가의 은(Ag)을 두껍게 증착할 수 없으므로 보통은 구리도금 또는 솔더링으로 안정화재를 덧댄다. 본 연구에서는 초전도 박막선재의 대전류화와 길이방향의 전류 균일성 향상, 안정화 특성 항상 등의 목적으로 초전도 박막선재간 확산 접합을 시도하였다. 초전도 박막선재 제조 후 안정화재인 은을 증착 후 따로 구리도금이나 솔더링 없이 선재 2가닥을 서로 포개어서 열처리를 하였다. 이때 선재간의 충분한 확산접합을 위하여 선재를 둥근 SUS 디스크에 감고 외부에 다시 SUS판재로 감아서 열처리 도중 압력을 가하였다. 아울러 포개는 방법도 초전도층의 위치에 따라 3 가지로 하였으며 열처리 후 임계전류를 측정하였다. 각 선재한 가닥에 대한 임계전류는 77K에서 50~60 A 정도의 임계전류를 나타내었으며 선재를 접합한 경우 90~120A의 특성을 나타내었으며 특히 초전도층이 설마주보는 형태에서 가장 높은 임계전류 특성을 나타내었다.

• Korean Journal of Agricultural Science
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• v.30 no.2
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• pp.148-153
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• 2003

Vegetable soybeans were blanched at 80, 90 and $100^{\circ}C$ for 30, 20 and 10min, respectively. NaCl(3%) was also used to measure the protective effect of soybean color. The color of vegetable soybeans was measured by colorimeter, -a value (greenness) was highest at $100^{\circ}C$-10min. However, the chlorophyll contents was highest at $80^{\circ}C$-30min. NaCl (3%) decreased the loss of chlorophyll in blanched vegetable soybeans. The reaction rate constant for the thermal degradation of chlorophyll and greenness doubled per $10^{\circ}C$. The activation energy chlorophyll a of pod for thermal degradation of chlorophyll a in pods were 138.02 (unsalted), 146.63 (salted) Kcal/mol, respectively.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.22 no.1
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• pp.11-14
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• 2012

The AlGaN layer has direct wide bandgaps ranging from 3.4 to 6.2 eV. Nowadays, it is becoming more important to fabricate optical devices in an UV region for the many applications. The high quality AlGaN layer is necessary to establish the UV optical devices. However, the growth of AlGaN layer on GaN layer is difficult due to the lattice mismatch and difference thermal expansion coefficient between GaN layer and AlGaN layer. In this paper, we attempted to grow the LED structure on GaN template by mixed-source HVPE method with multi-sliding boat system. We tried to find the optical and lattice transition of active layer by control the Al content in mixed-source. For the growth of epi layer, the HCl and $NH_3$ gas were flowed over the mixed-source and the carrier gas was $N_2$. The temperature of source zone and growth zone was stabled at 900 and $1090^{\circ}C$, respectively. After the growth, we performed the x-ray diffraction (XRD) and electro luminescence (EL) measurement.

• PNF and Movement
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• v.16 no.2
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• pp.195-205
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• 2018

Purpose: The purpose of this study was to demonstrate the effects of proprioceptive neuromuscular facilitation (PNF) stability techniques on walking speed, trunk stability, and balance in stroke patients. Methods: Ten stroke patients volunteered to participate in the study, and each of subjects was randomly assigned to either the stability technique (ST) group (n=5) or to the treadmill (TM) group (n=5). Each therapeutic exercise program was provided for 30 minutes a day, 5 days per week for 4 weeks. The ST group performed a PNF pattern combined with stabilizing reversal and rhythmic stabilization of the PNF stability technique. Walking speed (measured using a 10-meter walking test), trunk stability (TIS), and balance (BBS, FRT) were evaluated before and after training. All data were analyzed using SPSS version 18.0. The significance level for statistical inspection was set at 0.05. Results: Both groups showed improvements on the 10-meter walking test, the trunk impairment scale, the Berg balance scale, and the functional reaching test. Conclusion: PNF stability techniques are effective for improving trunk stability, balance, and walking speed in stroke patients. For stroke patients, PNF stability techniques are very useful and effective, including in clinical practice.

• Applied Biological Chemistry
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• v.47 no.1
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• pp.33-40
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• 2004

Thermodynamic properties of ubiquitin transient folding intermediate were studied by measuring folding kinetics in varying temperatures and denaturant concentrations. Through quantitative kinetic modeling, the equilibrium constant, hence folding free energy, between unfolded state and intermediate state in several different temperatures were calculated. Using these values, the thermodynamic parameters were estimated. The heat capacity change $({\Delta}C_p)$ upon formation of folding intermediate from unfolded state were estimated to be around 80% of the overall folding reaction, indicating that ubiquitin folding intermediate is highly compact. At room temperature, the changes of enthalpy and entropy upon formation of the intermediate state were observed to be positive. The positive enthalpy change suggests that the breaking up of the highly ordered solvent structure surrounding hydrophobic side-chain upon formation of intermediate state. This positive enthalpy was compensated for by the positive entropy change of whole system so that formation of transient intermediate has negative free energy.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.6 no.1
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• pp.40-50
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• 1994

For an accurate prediction of the temperature field induced by heated water discharged into a shallow crossflow, a two-dimensional near-field numerical model is developed. It is based on a 4-equation turbulence model in which the transport equations for mean of the temperature fluctuation squared and its dissipation rate are added to those of a 2-equation turbulence model which cannot give the information of the thermal time scale ratio. Vertical diffusion is also considered by including buoyancy production and turbulence heat flux terms. The developed model is applied to a steady flow in an open channel with simple geometry and the results are compared with existing experimental data and those of the already established 2-equation turbulence model. Numerical results of the model agree with the experimental data better than those of the 2-equation model. The present model also simulates quite adequately the physical characteristics of thermal discharge in the jet entrainment and stable regions.

• Journal of the Korean Vacuum Society
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• v.5 no.4
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• pp.284-291
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• 1996

We have implemented a fast pressure control system for the transport chamber of a high vacuum cluster tool for advance semiconductor fabrication and evaluated its performance. To overcome the typically slow response of mass flow controllers, the modified experimental method is used very effectively to optimize the pressure control procedure. We successfully obtained quite fast pressure control by adjusting the starting time and eht tuning constants by the Ziegler-Nichols method. In the transport pressure $10\times 10^{-5}$ torr, actual pressure control starts from 4 sec after an initial gas load of 2.1 sccm. As a result, optimum conditions for the tuning constants are the rise rate of 0.02 torr/sec, the lag time of 0.15 sec, and the sampling period of 0.5 sec. Then the settling time is about 9 sec within about $\pm$0.5% for the referenced value. This settling time is enhanced above 75 percents in comparison with conventional experimental method. To account for the experimental effects observed, a theoretical model was developed. This experimental result has a tendency to fit with the theoretical result of $\omega$=-1.0.

• Journal of the Korean Chemical Society
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• v.31 no.5
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• pp.419-424
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• 1987

Kinetic studies on the solvolysis of para-methyl benzyl nitrate and benzyl nitrate were carried out in aqueous methanol, ethanol, acetonitrile, acetone, tetrahydrofuran and dioxane mixtures at 60$^{\circ}$C. The rates were faster in protic solvent mixtures than in aprotic solvent mixtures. This was considered in the light of transition state stabilization by hydrogen bonding solvation of protic solvent mixtures. Grunwald-Winstein equation, extended Grunwald-Winstein equation and correlation between E$_T$(30) and rate constant were applied in order to discuss the transition state variations caused by changing benzyl substituents and solvents. The results showed that strong electrophilic assistance of solvent is operative in the the water-rich solvents.