• Title/Summary/Keyword: 아레니우스 관계

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Influence of Temperature on Chloride Ion Diffusion of Concrete (콘크리트의 염화물이온 확산성상에 미치는 온도의 영향)

  • So, Hyoung-Seok;Choi, Seung-Hoon;Seo, Chung-Seok;Seo, Ki-Seog;So, Seung-Young
    • Journal of the Korea Concrete Institute
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    • v.26 no.1
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    • pp.71-78
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    • 2014
  • The long term integrity of concrete cask is very important for spent nuclear fuel dry storage system. However, there are serious concerns about early deterioration of concrete cask from creaking and corrosion of reinforcing steel by chloride ion because the cask is usually located in seaside, expecially by combined deterioration such as chloride ion and heat, carbonation. This study is to investigate the relation between temperature and chloride ion diffusion of concrete. Immersion tests using 3.5% NaCl solution that were controlled in four level of temperature, i.e. 20, 40, 65, and $90^{\circ}C$, were conducted for four months. The chloride ion diffusion coefficient of concrete was predicted based on the results of profiles of Cl- ion concentration with the depth direction of concrete specimens using the method of potentiometric titration by $AgNO_3$. Test results indicate that the diffusion coefficient of chloride ion increases remarkably with increasing temperature, and there was a linear relation between the natural logarithm values of the diffusion coefficients and the reciprocal of the temperature from the Arrhenius plots. Activation energy of concrete in this study was about 46.6 (W/C = 40%), 41.7 (W/C = 50%), 30.7 (W/C = 60%) kJ/mol under a temperature of up to $90^{\circ}C$, and concrete with lower water-cement ratio has a tendency towards having higher temperature dependency.

Rheological Properties of Gelatinized Millet Starch Dispersions (국내산 조전분 호화액의 유동특성)

  • Kim, Nam-Soo;Nam, Young-Jung
    • Korean Journal of Food Science and Technology
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    • v.21 no.6
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    • pp.742-748
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    • 1989
  • Rheological properties of gelatinized millet starch dispersions were evaluated. Gelatinized nonwaxy and waxy millet starch dispersion were typical pseudoplastic fluids. At constant shear rate, gelatinized waxy millet starch dispersion showed higher shear stress than nonwaxy millet starch dispersion. Flow behaviours of gelatinized nonwaxy and waxy millet starch dispersion were well fitted to Herschel-Bulkley equation and flow behaviour index (n) and consistency index (K) were strongly concentration dependent. There was a linear relationship between concentration of gelatinized starch dispersion and square root of yield stress. The concentrations of gelatinized nonwaxy and waxy millet starch dispersion where yield stresses become zero were estimated as 2.19 and 1.69%, respectively. Pseudoplastic constant (m) approaches to a constant value in each type of millet starch when the concentration of gelatinized starch dispersion was increased. As the measuring temperatures increase, n value was increased, whereas, K value was decreased. The activation energies of gelatinized nonwaxy and waxy millet starch dispersion were 2.89 and 3.18kcal/mol, respectively.

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Life assessment of monitoring piezoelectric sensor under high temperature at high-level nuclear waste repository (고준위방사성폐기물 처분장 고온 환경 조건에 대한 모니터링용 피에조 센서의 수명 평가)

  • Changhee Park;Hyun-Joong Hwang;Chang-Ho Hong;Jin-Seop Kim;Gye-Chun Cho
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.25 no.6
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    • pp.509-523
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    • 2023
  • The high-level nuclear waste (HLW) repository is exposed to complex environmental conditions consisting of high temperature, high humidity, and radiation, resulting in structural deterioration. Therefore, structural health monitoring is essential, and piezo sensors are used to detect cracks and estimate strength. However, since the monitoring sensors installed in the disposal tunnel and disposal container cannot be replaced or removed, the quantitative life of the monitoring sensor and its suitability must be assessed. In this study, the life of a piezo sensor for monitoring was assessed using an accelerated life test (ALT). The failure mode and mechanism of the piezo sensor under high temperature conditions were determined, and temperature stress's influence on the piezo sensor's life was analyzed. ALT was conducted on temperature stress and the relationship between temperature stress and piezo sensor life was suggested. The life of the piezo sensor was assessed using the Weibull probability distribution and the Arrhenius acceleration model. The suggested relationship can be used in multiple stress ALT designs for more precise life assessment.