• Korean Chemical Engineering Research
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• v.49 no.5
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• pp.560-564
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• 2011

The objective of this study is to propose a mathematical model for a pervaporation process for concentrating hydrogen peroxide. The process was developed by NASA, which consists of a shell and membrane tubes, where a liquid hydrogen peroxide solution flows in the shell, and a sweep gas flows in the tubes countercurrent to each other. The liquid retentate is concentrated as more water molecules permeate and evaporate through the membrane than hydrogen peroxide. For this process, a mathematical model has been developed in the form of a system of nonlinear partial differential algebraic equations based on a sorption-diffusion mechanism for permeation, an Arrhenius relationship for the temperature dependency of the permeate flux, and mass and momentum balances for the liquid concentrations and flows in the membrane module. The dynamic behavior of the concentration of hydrogen peroxide in the retentate side has been simulated by solving a simplified version of the proposed model, and the result is compared with the experimental data reported in the NASA patent.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.12
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• pp.8637-8642
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• 2015

Typical aging for the rubber using the current military adhesive combat boots was spread with a regular aging caused by heat stress. In this study, the aging test of the rubber for combat boots was carried out and the reaction rate constant, k was calculated at aging temperature $60^{\circ}C$, $80^{\circ}C$ and $100^{\circ}C$, using the Arrhenius equation. The lifetime limit was assumed that the tensile strength of the product is reduced to 30%, the elongation is reduced to 50% and abrasion resistance ratio is 380%. ln($P/P_0$) and the lifetime was predicted with the consideration of the activation energy constant. According to the above, the lifetime of the rubber for combat boots with influenced by aging temperature was predicted. As the result, the estimate lifetime at $20^{\circ}C$ was confirmed more than 10 years.

• Journal of Power System Engineering
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• v.16 no.2
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• pp.43-48
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• 2012

Generally accelerated life test is well known as one method to reduce reliability qualification test period. This test is conducted under the higher stress condition than normal condition. So it can save the test time by calculating the acceleration factor from the relationship between the worst stress condition and normal condition. This paper investigates the worst stress condition for the accelerated life test to increase the acceleration factor. Especially, we focused on the method to obtain effective acceleration factors under the worst stress condition. Moreover, we considered how to decide the worst stress condition by looking for the operating limit of this system. The acceleration factor can be estimated from the ratio of the kinematic viscosity in the normal condition and the worst stress condition, the lowest temperature, by using Arrhenius relationship. Through some experiments for a refrigerator's compressor, we were able to confirm how to increase acceleration factors and how to reduce the reliability qualification test period with minimum samples.

• Journal of the Microelectronics and Packaging Society
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• v.24 no.1
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• pp.67-73
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• 2017

An analysis of thermal degradation of epoxy based adhesive performed by thermogravimetry tests are presented in this study. Six different heating rates were employed for the weight change measurements. Based on the data, an Arrhenius type modeling equation was developed by calculating activation energies and proportional constants, and $n^{th}$ polynomial function was adopted to predict the weight change rates. The prediction results by the modeling was compared with the data using the average activation energy. It was found that the activation energy at the each heating rate was not same due to the different degradation kinetics, especially at the high heating rate. To overcome this pitfall, a new approach using exponential function series was introduced and employed. The calculation results showed very good agreements with the test data regardless of the heating rates.

• Korean Journal of Food Science and Technology
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• v.18 no.4
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• pp.278-282
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• 1986

Rheological properties of naked barley (Songhak and Youngsan) starches were compared. The gelatinized starches at $3{\sim}9%$ concentration showed a Bingham pseudoplastic behavior. Songhak starch had higher values of consistency index and yield stress than those of Youngsan starch. The dependence of consistency index on concentration was mere pronounced in Songhak starch. Consistency index of both starches was exponentially dependent on concentration, but the slopes at $3{\sim}5%\;and\;5{\sim}9%$ starch concentration were different. The activation energies of 7% for Songhak and Youngsan starches were 4.10 and 3.71 Kcal/mole, respectively.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.35 no.10
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• pp.1193-1198
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• 2011

The solenoid valve used in fuel cell system need to have good sealing performance because the work fluid can explode in the system. Moreover, the temperature of the work fluid is extremely high in order to maintain the properties of the rubber ring that seals the solenoid valve. This study deals with the rubber ring which is made from a fluoro-elastomer. The life cycle of the rubber ring was estimated by the relational expression of Arrhenius, and the solenoid valve was tested to confirm the sealing characteristics.

• Elastomers and Composites
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• v.47 no.3
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• pp.254-258
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• 2012

Material characteristics and the prediction of life time of polyacrylic rubber (ACM) for automotive engine gasket were studied. Two kinds of ACM rubber compounds, having chlorine cure-site and carboxyl cure-site, were made with optimum formulations and the properties of each materials were examined. As a test results for the thermal properties and compression set, which are very important in the application for the automotive engine gasket, the compound using ACM with carboxyl cure-site was evaluated as having a better characteristics than that of ACM with chlorine cure-site. Arrhenius relationship based on time-temperature superposition principle (TTSP) was obtained through the accelerated heat aging test to predict the useful life-time for the compound using ACM with carboxyl cure-site.

• Korean Journal of Food Science and Technology
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• v.16 no.3
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• pp.314-318
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• 1984

Rheological properties of gelatinized chestnut starch solution were investigated with a narrow gap rotational viscometer. The starch solutions at 1.2-1.8% concentration showed pseudoplastic behaviour with yield stress. At higher concentrations (1.65 and 1.8%), the starch solution showed more pseudoplastic tendency and time-dependent characteristics. Values of yield stress were small and independent of concentrations 1.2, 1.35 and 1.5%. Significant increase of yield stress was observed at 1.65% concentration. Consistency index was exponentially dependent on concentration and temperature. The activation energy for 1.65% starch solution was about 5 Kcal/g.mol.

• Polymer(Korea)
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• v.32 no.5
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• pp.440-445
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• 2008

The failure mechanism and failure morphology of linear low density polyethylene (LLDPE) tubing under hydrostatic pressure were investigated. Microscopic observations using video microscope and scanning electron microscope indicate that the failure mode is a brittle fracture including cracks propagated from inner wall to outer wall. In addition, oxidation induction time and Fourier transform infrared spectroscopy results show the presence of exothermic peak and the increase in carbonyl index on the surface of fractured LLDPE tubing, due to thermal-degradation. An accelerated life test methodology and testing system for LLDPE tubing are developed using the relationship between stresses and life characteristics by means of thermal acceleration. Statistical approaches using the Arrhenius model and Weibull distribution are implemented to estimate the long-term life time of LLDPE tubing under hydrostatic pressure. Consequently, the long-term life time of LLDPE tubing at the operating temperature of $25^{\circ}C$ could be predicted and also be analyzed.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.33 no.3
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• pp.197-201
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• 2007

Oil soluble licorice extract(licorice extract) is an officially approved cosmetic component as a whitening ingredient in Korea. The durability of licorice, during which the whitening effect can be maintained in optimum condition, must be accurately defined. Since the cosmetics durability under real condition is relatively longer than its development time. It is needed to predict the real durability interval from the experimental measurement under simulated operating conditions. We analyzed the relationship between the licorice lifetime and the high temperature condition by using Arrhenius equation. We have established the constant stress test with temperature of $50^{\circ}C$, $55^{\circ}C$, and $60^{\circ}C$ condition, within which no formulation change of licorice products is expected for the accelerated stress test. In this paper, the lifetime of licorice in cosmetics was defined as time period for its 10% contents reduction. We observed that the lifetime of licorice is 580 h at $50^{\circ}C$, 319 h at $55^{\circ}C$ and 166 h at $60^{\circ}C$. Using the above experimental data, we obtained the equation for the relationship between the licorice lifetime and temperature as follows; log(lifetime)=-35.0243 + 1.15322$\times$(11604.83/temperature). From this equation, the lifetime of licorice at $25^{\circ}C$ can be estimated as 26 months. The estimated result was verified by measuring full lifetime of licorice. In fact, there was no significant difference between the estimated lifetime and real measurement within 95 % significance level. This study can be applied to other useful cosmetic components for the fast estimation of the exact durability.